Bimetallic Ni–Mo nitride@C<sub>3</sub>N<sub>4</sub> for highly active and stable water catalysis

doi:10.1007/s11706-022-0613-9

Front. Mater. Sci.

2022, Vol. 16

Issue (3) : 220613 https://doi.org/10.1007/s11706-022-0613-9

RESEARCH ARTICLE

Bimetallic Ni–Mo nitride@C₃N₄ for highly active and stable water catalysis

Xinping LI¹, Min ZHOU¹, Zhuoxun YIN¹(

), Xinzhi MA²(

), Yang ZHOU³(

)

¹. College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China
². School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China
³. College of Science, Qiqihar University, Qiqihar 161006, China

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Abstract

Non-noble metal electrocatalysts for water cracking have excellent prospects for development of sustainable and clean energy. Highly efficient electrocatalysts for the oxygen evolution reaction (OER) are very important for various energy storage and conversion systems such as water splitting devices and metal‒air batteries. This study prepared a NiMo₄@C₃N₄ catalyst for OER and hydrogen evolution reaction (HER) by simple methods. The catalyst exhibited an excellent OER activity based on the response at a suitable temperature. To drive a current density of 10 mA·cm⁻² for OER and HER, the overpotentials required for NiMo₄@C₃N₄-800 (prepared at 800 °C) were 259 and 118 mV, respectively. A two-electrode system using NiMo₄@C₃N₄-800 needed a very low cell potential of 1.572 V to reach a current density of 10 mA·cm⁻². In addition, this catalyst showed excellent durability after long-term tests. It was seen to have good catalytic activity and broad application prospects.

Keywords stability oxygen reduction reaction water splitting electrocatalyst

Corresponding Author(s): Zhuoxun YIN,Xinzhi MA,Yang ZHOU

Issue Date: 28 July 2022

Cite this article:

Xinping LI,Min ZHOU,Zhuoxun YIN, et al. Bimetallic Ni–Mo nitride@C₃N₄ for highly active and stable water catalysis[J]. Front. Mater. Sci., 2022, 16(3): 220613.

URL:

https://academic.hep.com.cn/foms/EN/10.1007/s11706-022-0613-9
https://academic.hep.com.cn/foms/EN/Y2022/V16/I3/220613

Fig.1 XRD patterns of different NiMo₄@C₃N₄ catalysts.

Fig.2 (a) SEM image, (b) low-magnification TEM image, and (c)(d)(e)(f) high-resolution TEM (HRTEM) images of NiMo₄@C₃N₄-800 (where panels (d) and (f) are enlargements of panels (c) and (e), respectively).

Fig.3 Comparison of XPS spectra of NiMo₄@C₃N₄-800: (a) C 1s; (b) N 1s; (c) Ni 2p; (d) Mo 3d.

Fig.4 (a) Polarization curves of NiMo₄@C₃N₄-700, NiMo₄@C₃N₄-800, NiMo₄@C₃N₄-900, NiMo-800, and IO₂ toward the OER. (b) NiMo₄@C₃N₄-700, NiMo₄@C₃N₄-800, and NiMo₄@C₃N₄-900 Tafel slopes of the OER. (c) Nyquist curves of NiMo₄@C₃N₄-700, NiMo₄@C₃N₄-800, and NiMo₄@C₃N₄-900 catalysts at 259 mV. (d) Time-dependent current density curves for the catalysts under static overpotentials of 259 mV over 16 h.

Fig.5 (a) Polarization curves of NiMo₄@C₃N₄-700, NiMo₄@C₃N₄-800, NiMo₄@C₃N₄-900, and NiMo-800 toward the HER. (b) NiMo₄@C₃N₄-700, NiMo₄@C₃N₄-800, and NiMo₄@C₃N₄-900 Tafel slopes of the HER. (c) Nyquist curves of NiMo₄@C₃N₄-700, NiMo₄@C₃N₄-800, and NiMo₄@C₃N₄-900 catalysts at 118 mV. (d) Time-dependent current density curves for the catalysts under static overpotentials of 118 mV over 12 h.

Fig.6 (a) Polarization curves of NiMo₄@C₃N₄-800|NiMo₄@C₃N₄-800 in a two-electrode system for overall water splitting. (b) Durability of NiMo₄@C₃N₄-800|NiMo₄@C₃N₄-800 for overall water splitting in 1.0 mol·L^?1 KOH.

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