Please wait a minute...
Frontiers of Physics

ISSN 2095-0462

ISSN 2095-0470(Online)

CN 11-5994/O4

邮发代号 80-965

2019 Impact Factor: 2.502

Frontiers of Physics in China  2010, Vol. 5 Issue (4): 340-346   https://doi.org/10.1007/s11467-010-0106-7
  MINI-REVIEW ARTICLE 本期目录
Intermediate structures in two-dimensional molecular self-assembly
Intermediate structures in two-dimensional molecular self-assembly
Karl-Heinz ERNST1,2()
1. Nanoscale Materials Science, Empa, Swiss Federal Laboratories for Materials Testing and Research, Ueberlandstr. 129, CH-8600 Dübendorf, Switzerland; 2. Fachbereich Chemie, Universit?t Zürich, CH-8057 Zürich, Switzerland
 全文: PDF(325 KB)   HTML
Abstract

We discuss the occurrence of transition structures observed in molecular self-assembly at surfaces. The increasing surface coverage transitions from low coverage structures to high coverage structures are a common phenomenon. However, often observed and not perfectly understood is the formation of intermediate structures, sometimes with lower lateral density than the initial phase. We will present different examples from our recent work and discuss the possible mechanisms of intermediate phase formation. In addition, we present intermediate structures occurring due to temperature-controlled reversible phase transitions.

Key wordsscanning tunnelling microscopy (STM)    polymorphism    corannulene    heptahelicene    chirality
收稿日期: 2010-05-28      出版日期: 2010-12-05
Corresponding Author(s): ERNST Karl-Heinz,Email:Karl-Heinz.Ernst@empa.ch   
 引用本文:   
. Intermediate structures in two-dimensional molecular self-assembly[J]. Frontiers of Physics in China, 2010, 5(4): 340-346.
Karl-Heinz ERNST. Intermediate structures in two-dimensional molecular self-assembly. Front Phys Chin, 2010, 5(4): 340-346.
 链接本文:  
https://academic.hep.com.cn/fop/CN/10.1007/s11467-010-0106-7
https://academic.hep.com.cn/fop/CN/Y2010/V5/I4/340
1 J. D. Dunitz and J. Bernstein, Acc. Chem. Res. , 1995, 28: 193
doi: 10.1021/ar00052a005
2 J. Bauer, S. Spanton, R. Henry, J. Quick, W. Dziki, W. Porter, and J. Morris, Pharm. Res. , 2001, 18: 859
doi: 10.1023/A:1011052932607
3 R. Hilfiker (Ed.), Polymorphism in the Pharmaceutical Industry, Weinheim: Wiley-VCH, 2006
4 I. Weissbuch, L. Addadi, M. Lahav, and L. Leiserowitz, Science 1991, 253: 637
doi: 10.1126/science.253.5020.637
5 L. Addadi and S. Weiner, Proc. Natl. Acad. Sci. , 1985, 82: 4110
doi: 10.1073/pnas.82.12.4110
6 G. Ertl, Angew. Chem. Int. Ed. , 2008, 47: 3524
doi: 10.1002/anie.200800480
7 K.-H. Ernst, Top. Curr. Chem. , 2006, 265: 209
doi: 10.1007/128_036
8 S. De Feyter and F. De Schryver, Chem. Soc. Rev. , 2003, 32: 139
doi: 10.1039/b206566p
9 M. J. Buerger, Elementary Crystallography: An Introduction to the Fundamental Geometrical Features of Crystals, New York: Wiley, 1956
10 D. Shechtmann, I. Blech, D. Cratias, and J.W. Cahn, Phys. Rev. Lett. , 1984, 53: 1951
doi: 10.1103/PhysRevLett.53.1951
11 D. R. Nelson, Phys. Rev. B , 1983, 28: 5515
doi: 10.1103/PhysRevB.28.5515
12 I. Hargittai (Ed.), Fivefold Symmetry, Singapore: World Scientific, 1992
13 R. Lück, Mater. Sci. Eng. A , 2000, 294-296: 263
doi: 10.1016/S0921-5093(00)01302-2
14 K. E. Plass, A. L. Grzesiak, and A. J. Matzger, Acc. Chem. Res. , 2007, 40: 287
doi: 10.1021/ar0500158
15 T. Bauert, L. Merz, D. Bandera, M. Parschau, J. S. Siegel, and K.-H. Ernst, J. Am. Chem. Soc. , 2009, 131: 3460
doi: 10.1021/ja8101083
16 M. Parschau, R. Fasel, K.-H. Ernst, O. Gr?ning, L. Brandenberger, R. Schillinger, T. Greber, A. P. Seitsonen, Y. T. Wu, and J. S. Siegel, Angew. Chem. Int. Ed ., 2007, 46: 8258
doi: 10.1002/anie.200700610
17 L. Merz, M. Parschau, L. Zoppi, K. K. Baldridge, J. S. Siegel, and K.-H. Ernst, Angew. Chem. Int. Ed. , 2009, 48: 1966
doi: 10.1002/anie.200804563
18 L. Merz, T. Bauert, M. Parschau, G. Koller, J. S. Siegel, and K.-H. Ernst, Chem. Commun. , 2009: 5871
doi: 10.1039/b911056a
19 L. Merz, M. Parschau, J. S. Siegel, and K.-H. Ernst, Chimia , 2009, 63: 214
doi: 10.2533/chimia.2009.214
20 Y. T. Wu and J. S. Siegel, Chem. Rev. , 2006, 106: 4843
doi: 10.1021/cr050554q
21 A. I. Kitajgorodskij, Acta. Cryst. , 1965, 18: 585
doi: 10.1107/S0365110X65001391
22 J. D. Dunitz and R. M. Ibberson, Angew. Chem. Int. Ed. , 2008, 47: 4208
doi: 10.1002/anie.200800063
23 L. Merz and K.-H. Ernst, Surface Sci. , 2010, 604: 1049
doi: 10.1016/j.susc.2010.03.023
24 K.-H. Ernst, M. B?hringer, C. F. McFadden, P. Hug, U. Müller, and U. Ellerbeck, Nanotechnology , 1999, 10: 355
doi: 10.1088/0957-4484/10/3/320
25 K.-H. Ernst, M. Neuber, M. Grunze, and U. Ellerbeck, J. Am. Chem. Soc. , 2001, 123: 493
doi: 10.1021/ja003262+
26 K.-H. Ernst, Y. Kuster, R. Fasel, C. F. McFadden, and U. Ellerbeck, Surf. Sci. , 2003, 530: 195
doi: 10.1016/S0039-6028(03)00489-8
27 R. Fasel, M. Parschau, and K.-H. Ernst, Angew. Chem. Int. Ed. , 2003, 42: 5178
doi: 10.1002/anie.200352232
28 M. Parschau, U. Ellerbeck, and K.-H. Ernst, Colloids and Surfaces A: Physicochem. Eng. Aspects , 2010, 354: 240
doi: 10.1016/j.colsurfa.2009.06.008
29 K.-H. Ernst, Y. Kuster, R. Fasel, M. Müller, and U. Ellerbeck, Chirality , 2001, 13: 675
doi: 10.1002/chir.10006
30 R. Fasel, M. Parschau, and K.-H. Ernst, Nature , 2006, 439-449
doi: 10.1038/nature04419
31 M. M. Green, M. P. Reidy, R. J. Johnson, G. Darling, D. J. O’Leary, and G. Wilson, J. Am. Chem. Soc. , 1989, 111: 6452
doi: 10.1021/ja00198a084
32 M. Parschau, S. Romer, and K.-H. Ernst, J. Am. Chem. Soc. , 2004, 124: 15398
doi: 10.1021/ja044136z
33 M. Parschau, T. Kampen, and K.-H. Ernst, Chem. Phys. Lett. , 2005, 407: 433
doi: 10.1016/j.cplett.2005.03.117
34 K.-H. Ernst, Curr. Opin. Colloid Interface Sci. , 2007, 13: 54
doi: 10.1016/j.cocis.2007.08.011
35 M. M. Green, B. A. Garetz, B. Munoz, H. Chang, S. Hoke, and R. G. Cooks, J. Am. Chem. Soc. , 1995, 117: 4181
doi: 10.1021/ja00119a039
36 S. Haq, N. Liu, V. Humblot, A. P. J. Jansen, and R. Raval, Nature Chem. , 2009, 1: 409
doi: 10.1038/nchem.295
37 M. Parschau, R. Fasel, and K.-H. Ernst, Cryst. Growth & Des. , 2008, 8: 1890
doi: 10.1021/cg701100r
38 H. Yanagi, D. Schlettwein, H. Nakayama, and T. Nishino, Phys. Rev. B , 2000, 61: 1959
doi: 10.1103/PhysRevB.61.1959
39 S. Berner, M. Brunner, L. Ramoino, H. Suzuki, H.-J. Güntherodt, and T. A. Jung, Chem. Phys. Lett. , 2001, 348: 175
doi: 10.1016/S0009-2614(01)01158-7
40 S. Berner, M. de Wild, L. Ramoino, S. Ivan, A. Baratoff, H.-J. Güntherodt, H. Suzuki, and T. A. Jung, Phys. Rev. B , 2003, 68: 115410
doi: 10.1103/PhysRevB.68.115410
41 H. Yanagi, K. Ikuta, H. Mukai, and T. Shibutani, Nano Lett. , 2002, 2: 951
doi: 10.1021/nl0256762
42 S. Mannsfeld, H. Reichhard, and T. Fritz, Surf. Sci. , 2003, 525: 215
doi: 10.1016/S0039-6028(02)02562-1
43 N. Jiang, Y. Wang, Q. Liu, Y. Zhang, K.-H. Ernst, and H. J. Gao, Phys. Chem. Chem. Phys. , 2010, 12: 1318
doi: 10.1039/b918278k
44 K.-H. Ernst, D. Schlatterbeck, and K. Christmann, Phys. Chem. Chem. Phys . 1999, 1: 4105
doi: 10.1039/a904169i
45 B. Behzadi, D. Ferri, A. Baiker, and K.-H. Ernst, Appl. Surf. Sci. , 2007, 253: 3480
doi: 10.1016/j.apsusc.2006.07.084
46 M. Parschau, B. Behzadi, S. Romer, and K.-H. Ernst, Surf. Interface Anal. , 2006, 38: 1607
doi: 10.1002/sia.2426
47 T. J. Seiders, E. L. Elliott, G. H. Grube, and J. S. Siegel, J. Am. Chem. Soc. , 1999, 121: 7804
doi: 10.1021/ja991310o
48 A. Sudharkar and T. J. Katz, Tetrahedron Lett. , 1986, 27: 2231
doi: 10.1016/S0040-4039(00)84494-9
49 T. Bürgi, A. Urakawa, B. Behzadi, K.-H. Ernst, and A. Baiker, New J. Chem. , 2004, 28: 332
doi: 10.1039/b312877f
50 R. Fasel, A. Cossy, K.-H. Ernst, F. Baumberger, T. Greber, and J. Osterwalder, J. Chem. Phys. , 2001, 115: 1020
doi: 10.1063/1.1377886
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed