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Electric field driven phase transition and possible twining quasi-tetragonal phase in compressively strained BiFeO3 thin films |
Cheng-Liang Lu(陆成亮)1( ), Jun-Ming Liu(刘俊明)2,3( ), Tao Wu(吴韬)4 |
| 1. School of Physics, Huazhong University of Science and Technology, Wuhan 430074, China; 2. Laboratory of Solid State Microstructure, Nanjing University, Nanjing 210093, China; 3. International Center for Materials Physics, Chinese Academy of Sciences, Shenyang 110016, China; 4. Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore |
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Abstract Highly compressively strained BiFeO3 thin films with different thickness are epitaxially grown on (001) LaAlO3 substrates and characterized using various techniques. The quasi-tetragonal phase with a giant axial ratio of ~1.25 and its thickness-dependent evolution are investigated. An interesting twining structure of the quasi-tetragonal phase is evidenced in thicker films through detailed reciprocal space mapping, which becomes more pronounced with increasing film thickness. Moreover, an interesting electric-field driven phase transition was evidenced in the film with a thickness of 38 nm, in which the quasi-tetragonal and rhombohedral phases are close to each other in energy landscape.
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| Keywords
ferroelectricity
antiferromagnetic
phase transition
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Corresponding Author(s):
Cheng-Liang Lu(陆成亮),Email:cllu@mail.hust.edu.cn; Jun-Ming Liu(刘俊明),Email:liujm@nju.edu.cn
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Issue Date: 01 August 2012
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