Kinetic model for hydroisomerization reaction
of C-aromatics

doi:10.1007/s11705-008-0015-2

Front. Chem. Sci. Eng.

2008, Vol. 2

Issue (1) : 10-16 https://doi.org/10.1007/s11705-008-0015-2

Kinetic model for hydroisomerization reaction of C-aromatics

XU Ouguan¹, SU Hongye², JIN Xiaoming², CHU Jian²

1.Zhijiang College, Zhejiang University of Technology; National Key Laboratory of Industrial Control Technology, Institute of Advanced Process Control, Zhejiang University; 2.National Key Laboratory of Industrial Control Technology, Institute of Advanced Process Control, Zhejiang University

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Abstract Based on the reported reaction networks, a novel six-component hydroisomerization reaction network with a new lumped species including C₈-naphthenes and C₈-paraffins is proposed and a kinetic model for a commercial unit is also developed. An empirical catalyst deactivation function is incorporated into the model accounting for the loss in activity because of coke formation on the catalyst surface during the long-term operation. The Runge-Kutta method is used to solve the ordinary differential equations of the model. The reaction kinetic parameters are benchmarked with several sets of balanced plant data and estimated by the differential variable metric optimization method (BFGS). The kinetic model is validated by an industrial unit with sets of plant data under different operating conditions and simulation results show a good agreement between the model predictions and the plant observations.

Issue Date: 05 March 2008

Cite this article:

SU Hongye,XU Ouguan,JIN Xiaoming, et al. Kinetic model for hydroisomerization reaction of C-aromatics[J]. Front. Chem. Sci. Eng., 2008, 2(1): 10-16.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-008-0015-2
https://academic.hep.com.cn/fcse/EN/Y2008/V2/I1/10

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