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Development of solid base catalyst X/Y/MgO/-AlO for optimization of preparation of biodiesel from L.seed oil |
WANG Rui1, YANG Song2, YIN Shitao2, SONG Baoan2, BHADURY Pinaki S.2, XUE Wei2, TAO Shuwei2, JIA Zhaohui2, LIU Da2, GAO Liang2 |
1.Center for Research and Development of Fine Chemicals, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University;Department of Biology and Environment Engineering, Guiyang College; 2.Center for Research and Development of Fine Chemicals, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University |
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Abstract The preparation and regeneration conditions of the identified catalyst X/Y/MgO/?-Al2O3 with high catalytic activity were studied and optimized. The biodiesel was prepared by transesterification of Jatropha curcas seed oil produced in Guizhou with methanol at its reflux temoerature in the presence of X/Y/MgO/?-Al2O3 . The pilot plant tests were carried out in a 100 L reaction vessel. Both average yield and fatty acid methyl esters (FAME) content reached more than 96.50% under the optimum reaction conditions of the pilot plant tests designed with an oil/methanol molar ratio of 1 : 10, catalyst concentration of 1.00%, and reaction time of 3 h at reflux temperature. In addition, analysis shows that the quality of biodiesel meets the standard EN 14214.
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Issue Date: 05 December 2008
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1 |
Dunn R O, Knothe G . Alternativediesel fuels from vegetable oils and animal fats. Oleo Sci, 2001, 50: 415–426
|
2 |
Ma F, Hanna M A . Biodieselproduction: a review. Bioresour Technol, 1999, 70: 1–15. doi:10.1016/S0960-8524(99)00025-5
|
3 |
Ramadhas A S, Jayaraj S, Muraleedharan C, Biodiesel production fromhigh FFA rubber seed oil. Fuel, 2005, 84: 335–340. doi:10.1016/j.fuel.2004.09.016
|
4 |
Knothe G, Sharp C A, Ryan T W . Exhaust emissions of biodiesel, petrodiesel,neat methyl esters, and alkanes in a new technology engine. Energy & Fuels, 2006, 20: 403–408. doi:10.1021/ef0502711
|
5 |
Lin C Y, Lin H A, Hung L B . Fuel structure and properties of biodieselproduced by the peroxidation process. Fuel, 2006, 85: 1743–1749. doi:10.1016/j.fuel.2006.03.010
|
6 |
Meher L C, Sagar D V, Naik S N . Technical aspects of biodiesel productionby transesterification-a review. RenewSustain Energ Rev, 2006 10: 248–268. doi:10.1016/j.rser.2004.09.002
|
7 |
Vicente G, Martinez M, Aracil J . Integrated biodiesel production:a comparison of different homogeneous catalysts systems. Bioresour Technol, 2004, 92: 297–305. doi:10.1016/j.biortech.2003.08.014
|
8 |
Marchetti J M, MiguelaV U, Errazua A F . Possible methods for biodieselproduction. Renew Sustain Energ Rev, 2007, 11: 1300–1311. doi:10.1016/j.rser.2005.08.006
|
9 |
Formo M W . Ester reactions of fatty materials. J Am Oil Chem Soc, 1954, 31: 548–559. doi:10.1007/BF02638571
|
10 |
Kim H J, Kang B S, Kim M J, Park Y M, Kim D K, Lee J S, Lee K Y . Transesterificationof vegetable oil to biodiesel using heterogeneous base catalyst. Catal Today, 2004, 93–95: 315–320. doi:10.1016/j.cattod.2004.06.007
|
11 |
Suppes G J, Dasari M A, Doskocil E J, Mankidy P J, Goff M J . Transesterification of soybeanoil with zeolite and metal catalysts. ApplCatal A, 2004, 257: 213–223. doi:10.1016/j.apcata.2003.07.010
|
12 |
Ebiura T, Echizen T, Ishikawa A, Murai K, Baba T . Selective transesterificationof triolein with methanol to methyl oleate and glycerol using aluminaloaded with alkali metal salt as a solid-base catalyst. Appl Catal A, 2005, 283: 111–116. doi:10.1016/j.apcata.2004.12.041
|
13 |
Xie W L, Li H T . Alumina-supportedpotassium iodide as a heterogeneous catalyst for biodiesel productionfrom soybean oil. J Mol Catal A, 2006, 255: 1–9. doi:10.1016/j.molcata.2006.03.061
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