Carbon dioxide: a renewable feedstock for the
synthesis of fine and bulk chemicals

doi:10.1007/s11705-009-0227-0

Front. Chem. Sci. Eng.

2010, Vol. 4

Issue (2) : 213-235 https://doi.org/10.1007/s11705-009-0227-0

Research articles

Carbon dioxide: a renewable feedstock for the synthesis of fine and bulk chemicals

Yogesh P. PATIL,Pawan J. TAMBADE,Sachin R. JAGTAP,Bhalchandra M. BHANAGE,

Institute of Chemical Technology (Autonomous), N. Parekh Marg, Matunga, Mumbai- 400019, India;

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Abstract The syntheses of carbon dioxide (CO₂) based industrially important chemicals have gained considerable interest in view of the sustainable chemistry and “green chemistry” concepts. In this review, recent developments in the chemical fixation of CO₂ to valuable chemicals are discussed. The synthesis of five-member cyclic carbonates via, cycloaddition of CO₂ to epoxides is one of the promising reactions replacing the existing poisonous phosgene-based synthetic route. This review focuses on the synthesis of cyclic carbonates, vinyl carbamates, and quinazoline-2,4(1H,3H)-diones via reaction of CO₂ and epoxide, amines/phenyl acetylene, 2-aminobenzinitrile and other chemicals. Direct synthesis of dimethyl carbonate, 1,3-disubstituted urea and 2-oxazolidinones/2-imidazolidinones have limitations at present because of the reaction equilibrium and chemical inertness of CO₂. The preferred alternatives for their synthesis like transesterification of ethylene carbonate with methanol, transamination of ethylene carbonate with primary amine and transamination reaction of ethylene carbonate with diamines/β-aminoalcohols are discussed. These methodologies offer marked improvements for greener chemical fixation of CO₂ in to industrially important chemicals.

Issue Date: 05 June 2010

Cite this article:

Pawan J. TAMBADE,Yogesh P. PATIL,Sachin R. JAGTAP, et al. Carbon dioxide: a renewable feedstock for the synthesis of fine and bulk chemicals[J]. Front. Chem. Sci. Eng., 2010, 4(2): 213-235.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-009-0227-0
https://academic.hep.com.cn/fcse/EN/Y2010/V4/I2/213

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