Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

doi:10.1007/s11705-017-1669-4

Front. Chem. Sci. Eng.

2018, Vol. 12

Issue (1) : 24-31 https://doi.org/10.1007/s11705-017-1669-4

RESEARCH ARTICLE

Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

Dongxu Han, Zhiguo Zhang(

), Zongbi Bao, Huabin Xing, Qilong Ren(

)

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

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Abstract

We have successfully prepared a series of Pd-Ni/TiO₂ catalysts by a one-step impregnation-reduction method. Among these catalysts with different compositions of Ni and Pd, the one with the Ni:Pd ratio of 2.95 showed the best activity. Small monodispersed Pd-Ni bimetallic nanoparticles were loaded on the surface of titanium oxide nanopowder as confirmed with TEM and EDS mapping. The XPS analysis demonstrated that Pd exists as 31% Pd(II) species and 69% Pd(0) species and all nickel is Ni(II). The prepared Pd-Ni/TiO₂ exhibited enhanced catalytic activity compared to an equal amount of Pd/TiO₂ for Suzuki-Miyaura reactions together with excellent applicability and reusability.

Keywords Pd-Ni bimetallic nanoparticles nanocatalysis Suzuki-Miyaura reaction titanium oxide

Corresponding Author(s): Zhiguo Zhang,Qilong Ren

Just Accepted Date: 19 June 2017 Online First Date: 26 September 2017 Issue Date: 26 February 2018

Cite this article:

Dongxu Han,Zhiguo Zhang,Zongbi Bao, et al. Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions[J]. Front. Chem. Sci. Eng., 2018, 12(1): 24-31.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-017-1669-4
https://academic.hep.com.cn/fcse/EN/Y2018/V12/I1/24

Tab.1 ICP-OES data of the Pd-Ni/TiO₂ catalysts

Fig.1 XRD patterns of the Pd-Ni/TiO₂ catalysts, Pd/TiO₂, Ni/TiO₂, and TiO₂ P25

Fig.2 (a) TEM image, (b) particle size distribution, (c) HR-TEM image of the Pd-Ni NPs, (d) HAADF-STEM image of one single Pd-Ni NP, and EDS mapping of (e) Pd and (f) Ni of the Pd-Ni/TiO₂ IV catalyst

Fig.3 XPS results of (a) Pd 3d, (b) Ni 2p, (c) Ti 2p, and (d) O1s of the Pd-Ni/TiO₂ IV catalyst

Tab.2 Catalyst survey for the Suzuki-Miyaura coupling reaction of iodobenzene and 4-methylbenzeneboronic acid ^a)

Fig.4 Recyclability of the Pd-Ni/TiO₂ IV catalyst in the Suzuki-Miyaura coupling reaction of iodobenzene with 4-methylbenzeneboronic acid. Yields were determined by HPLC on the basis of 4-methylbiphenyl

Fig.5 (a) TEM image, (b) particle size distribution, (c) HR-TEM image of the Pd-Ni NPs, (d) HAADF-STEM image of one single Pd-Ni NP, and EDS mapping of (e) Pd and (f) Ni of the Pd-Ni/TiO₂ IV catalyst after four cycles

Fig.6 XPS results of (a) Pd 3d, (b) Ni 2p of the Pd-Ni/TiO₂ IV catalyst after four cycles, (c) and (d)

Tab.3 Substrate scope of the Suzuki-Miyaura coupling reaction catalyzed by Pd-Ni/TiO₂ IV^a)

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