Please wait a minute...
Frontiers of Environmental Science & Engineering

ISSN 2095-2201

ISSN 2095-221X(Online)

CN 10-1013/X

Postal Subscription Code 80-973

2018 Impact Factor: 3.883

Front.Environ.Sci.Eng.    2014, Vol. 8 Issue (3) : 411-416    https://doi.org/10.1007/s11783-013-0577-1
RESEARCH ARTICLE
Occurrence of odor problems in drinking water of major cities across China
SUN Daolin,YU Jianwei1,(),YANG Min,AN Wei,ZHAO Yunyun,LU Ning2,YUAN Shengguang,ZHANG Dongqing
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
Shanghai National Engineering Research Center of Urban Water Resources Co., Ltd., Shanghai 200082, China
 Download: PDF(115 KB)   HTML
 Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract

A comprehensive investigation into the occurrence of odor problem at 111 drinking water treatment plants (DWTPs) in major cities across China was undertaken using both flavor profile analysis (FPA) and gas chromatography–mass spectrometry (GC-MS). Eighty percent of source water samples exhibited odor problems, characterized by earthy/musty (41%) and swampy/septic (36%) odors, while the occurrence rate was lower (45%) in the finished water. Source water from rivers exhibited more pollution-origin odors, such as the swampy/septic odor, while that from lakes and reservoirs exhibited more algae-origin odors, such as earthy/musty odors. The occurrence rate of 2-methylisoborneol (2-MIB) in the surface source water samples was 75%, with 7% of samples containing 2-MIB concentrations of over 10 ng·L-1. The earthy/musty odor in the lake/reservoir water samples was mainly caused by 2-MIB (linear regression coefficient, R2=0.69), while the correlation between 2-MIB concentration and the earthy/musty odor intensity in the river-source water samples was weak (R2=0.35). These results will be useful for the management of odor-quality problems in drinking water of China.

Keywords flavor profile analysis      2-methylisoborneol      swampy/septic odor      earthy/musty odor      drinking water quality     
Corresponding Author(s): YU Jianwei   
Issue Date: 19 May 2014
 Cite this article:   
SUN Daolin,YU Jianwei,YANG Min, et al. Occurrence of odor problems in drinking water of major cities across China[J]. Front.Environ.Sci.Eng., 2014, 8(3): 411-416.
 URL:  
https://academic.hep.com.cn/fese/EN/10.1007/s11783-013-0577-1
https://academic.hep.com.cn/fese/EN/Y2014/V8/I3/411
sampling citysampling DWTP numberssampling citysampling DWTP numberssampling citysampling DWTP numbers
Haikou2Lanzhou3Dalian4
Kunming2Nanjing3Fuzhou4
Nanchang2Ningbo3Guangzhou4
Qingdao2Shenyang3Huhehaote4
Yinchuan2Shijiazhuang3Nanning4
Beijing3Taiyuan3Shanghai4
Changchun3Tianjin3Shenzhen4
Changsha3Xiamen3Xi an4
Chengdu3Xining3Chongqing5
Haerbin3Wuhan3Guiyang5
Hangzhou3Zhengzhou3Jinan5
Hefei3
Tab.1  
Fig.1  Comparison of odor descriptors detected in source and finished waters
odor characteristicssource waterfinished water
occurrence /%average intensity b)occurrence /%average intensity
riverearthy/musty403.1172.7
swampy/septic544.3292.1
fishy114.853.8
odorless9-50-
lake/ reservoirearthy/musty503.4403.0
swampy/septic304.8152.6
grassy33.6--
odorless30-45-
groundwaterearthy/musty332.7152.0
odorless67-85-
Tab.2  
compoundssource waterfinished water
occu./% a)>5 ng·L-1/%max.b)med.c)occu./%>5 ng·L-1/%max.med.
river2-MIB802625.84.0521312.21.6
geosmin5766.11.64456.21.1
lake/res-ervoir2-MIB694565.05.8674032.55.3
geosmin3369.11.23059.01.0
Tab.3  
Fig.2  Relationship between 2-MIB levels and intensity of earthy/musty odors in the source waters
1 World Health Organization. Guidelines for drinking-water quality. World Health Organization, Geneva, Switzerland, 2011
2 Suffet I H, Corado A, Chou D, McGuire M J, Butterworth S. AWWA taste and odor survey. Journal- American Water Works Association, 1996, 88(4): 168-180
3 Yang M, Yu J, Li Z, Guo Z, Burch M, Lin T F. Taihu lake not to blame for Wuxi’s woes. Science, 2008, 319(5860): 158
doi: 10.1126/science.319.5860.158a
4 Zuo Y, Li L, Zhang T, Zheng L, Dai G, Liu L, Song L. Contribution of Streptomyces in sediment to earthy odor in the overlying water in Xionghe Reservoir, China. Water Research, 2010, 44(20): 6085-94
doi: 10.1016/j.watres.2010.08.001
5 Yu J W, Zhao Y M, Yang M, Lin T F, Guo Z H, Gu J N, Li S, Han W. Occurrence of odour-causing compounds in different source waters of China. Journal of Water Supply: Research and Technology- Aqua, 2009, 58(8): 587-594
doi: 10.2166/aqua.2009.023
6 SEPA. Secondary drinking water regulations: guidance for nuisance chemicals. 816-F-10-079, 2011 Available at: water.epa.gov/drink/contaminants/secondarystandards.cfm (access May 31, 2013)
7 McGuire M J. Off-flavor as the consumer’s measure of drinking water safety. Water Science & Technology, 1995, 31(11): 1-8
doi: 10.1016/0273-1223(95)00448-V
8 Krasner S W, McGuire M J, Ferguson V B. Tastes and odors: the flavor profile method. Journal- American Water Works Association, 1985, 77(3): 34-39
9 Suffet I H, Schweitze L, Khiari D. Olfactory and chemical analysis of taste and odor episodes in drinking water supplies. Reviews in Environmental Science and Biotechnology, 2004, 3(1): 3-13
doi: 10.1023/B:RESB.0000040012.94870.48
10 APHA,AWWA, WEF. Standard Methods for the Examination of Water and Wastewater. 20th ed. Washington, D C: American Public Health Association, 2000
11 Omür-Ozbek P, Dietrich A M. Developing hexanal as an odor reference standard for sensory analysis of drinking water. Water Research, 2008, 42(10-11): 2598-2604
doi: 10.1016/j.watres.2008.01.010
12 Suffet I H, Khiari D, Bruchet A. The drinking water taste and odor wheel for the millennium: beyond geosmin and 2-methylisoborneol. Water Science & Technology, 1999, 40(6): 1-13
doi: 10.1016/S0273-1223(99)00531-4
13 Lin T F, Wong J Y, Kao H P. Correlation of musty odor and 2-MIB in two drinking water treatment plants in South Taiwan. The Science of the Total Environment, 2002, 289(1-3): 225-235
doi: 10.1016/S0048-9697(01)01049-X pmid: 12049398
14 Watson S B. Cyanobacterial and eukaryotic algal odour compounds: signals or by-products? A review of their biological activity. Phycologia, 2003, 42(4): 332-350
doi: 10.2216/i0031-8884-42-4-332.1
15 Zaitlin B, Watson S B. Actinomycetes in relation to taste and odour in drinking water: myths, tenets and truths. Water Research, 2006, 40(9): 1741-1753
doi: 10.1016/j.watres.2006.02.024 pmid: 16600325
16 Khiari D, Barrett S E, Suffet I H. Determination of organic compounds causing decaying vegetation and septic odors in drinking water by sensory GC. Journal- American Water Works Association, 1997, 89(4): 150-161
17 Herrmann V, Jüttner F. Excretion products of algae: Identification of biogenic amines by gas-liquid chromatography and mass spectrometry of their trifluoroacetamides. Analytical Biochemistry, 1977, 78(2): 365-373
doi: 10.1016/0003-2697(77)90098-7 pmid: 851212
18 Peter A, Köster O, Schildknecht A, von Gunten U. Occurrence of dissolved and particle-bound taste and odor compounds in Swiss lake waters. Water Research, 2009, 43(8): 2191-2200
doi: 10.1016/j.watres.2009.02.016 pmid: 19303129
19 Tung S C, Lin T F, Yang F C, Liu C L. Seasonal change and correlation with environmental parameters for 2-MIB in Feng-Shen Reservoir, Taiwan. Environmental Monitoring and Assessment, 2008, 145(1-3): 407-416
doi: 10.1007/s10661-007-0049-9 pmid: 18080211
20 Westerhoff P, Rodriguez-Hernandez M, Baker L, Sommerfeld M. Seasonal occurrence and degradation of 2-methylisoborneol in water supply reservoirs. Water Research, 2005, 39(20): 4899-4912
doi: 10.1016/j.watres.2005.06.038 pmid: 16289672
21 Li Z L, Yu J W, Yang M, Zhang J, Burch M D, Han W. Cyanobacteial population and harmful metabolites dynamics during a bloom in Yanghe Reservoir, North China. Harmful Algae, 2010, 9(5): 481-488
doi: 10.1016/j.hal.2010.03.003
22 Bruchet A, Duguet J P. Role of oxidants and disinfectants on the removal, masking and generation of tastes and odours. Water Science & Technology, 2004, 49(9): 297-306
pmid: 15237638
23 Nerenberg R, Rittmann B E, Soucie W J. Ozone/biofiltration for removing MIB and geosmin. Journal- American Water Works Association, 2000, 92(12): 85-95
24 Jung S W, Baek K H, Yu M J. Treatment of taste and odor material by oxidation and adsorption. Water Science & Technology, 2004, 49(9): 289-295
pmid: 15237637
25 Thiemer E T. Fragrance Chemistry: the Science of the Sense of Smell. New York: Academic Press, 1982
[1] Rongfang YUAN, Beihai ZHOU, Chunhong SHI, Liying YU, Chunlei ZHANG, Junnong GU. Biodegradation of 2-methylisoborneol by bacteria enriched from biological activated carbon[J]. Front Envir Sci Eng, 2012, 6(5): 701-710.
[2] QU Jiuhui, YIN Chengqing, YANG Min, LIU Huijuan. Development and application of innovative technologies for drinking water quality assurance in China[J]. Front.Environ.Sci.Eng., 2007, 1(3): 257-269.
[3] MA Xiaoyan, CHEN Beibei, LI Qingsong, ZHANG Qiaoli, GU Guofen. Detection of geosmin and 2-methylisoborneol by liquid-liquid extraction-gas chromatograph mass spectrum (LLE-GCMS) and solid phase extraction-gas chromatograph mass spectrum (SPE-GCMS)[J]. Front.Environ.Sci.Eng., 2007, 1(3): 286-291.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed