Photocatalytic reduction of carbon dioxide by titanium oxide-based semiconductors to produce fuels

doi:10.1007/s11708-019-0628-9

Front. Energy

2019, Vol. 13

Issue (2) : 207-220 https://doi.org/10.1007/s11708-019-0628-9

REVIEW ARTICLE

Photocatalytic reduction of carbon dioxide by titanium oxide-based semiconductors to produce fuels

Xi CHEN¹, Fangming JIN²(

)

¹. China-UK Low Carbon College, Shanghai Jiao Tong University, Shanghai 201306, China
². China-UK Low Carbon College, Shanghai Jiao Tong University, Shanghai 201306, China; School of Environmental Science and Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

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Abstract

To tackle the crisis of global warming, it is imperative to control and mitigate the atmospheric carbon dioxide level. Photocatalytic reduction of carbon dioxide into solar fuels furnishes a gratifying solution to utilize and reduce carbon dioxide emission and simultaneously generate renewable energy to sustain the societies. So far, titanium oxide-based semiconductors have been the most prevalently adopted catalysts in carbon dioxide photoreduction. This mini-review provides a general summary of the recent progresses in titanium oxide-catalyzed photocatalytic reduction of carbon dioxide. It first illustrates the use of structural engineering as a strategy to adjust and improve the catalytic performances. Then, it describes the introduction of one/two exogenous elements to modify the photocatalytic activity and/or selectivity. Lastly, it discusses multi-component hybrid titanium oxide composites.

Keywords photocatalysis carbon dioxide reduction semiconductors titanium oxide renewable fuels

Corresponding Author(s): Fangming JIN

Online First Date: 15 May 2019 Issue Date: 04 July 2019

Cite this article:

Xi CHEN,Fangming JIN. Photocatalytic reduction of carbon dioxide by titanium oxide-based semiconductors to produce fuels[J]. Front. Energy, 2019, 13(2): 207-220.

URL:

https://academic.hep.com.cn/fie/EN/10.1007/s11708-019-0628-9
https://academic.hep.com.cn/fie/EN/Y2019/V13/I2/207

Fig.1 Devised utilization of CO₂ as an ample, low-cost, and readily available C1 platform resource

Fig.2 SEM and HRTEM images of TiO₂ nanocrystals with different crystal facets (adapted with permission from Ref. [³⁵])

Fig.3 SEM and bright-field TEM images of TiO₂ nanobelts (reprinted with permission from Ref. [³⁶]). Copyright 2010, American Chemical Society) (a) SEM image of the anatase TiO₂ nanobelts; (b) bright-field TEM images with SAED patterns of the nanobelt, and the diagram to show the relationship between the incident beam and the nanobelt

Tab.1 Summary of reviewed papers using co-catalysts to modify TiO₂

Fig.5 Proposed reaction pathways for the selective photoreduction of CO₂ into different products in gas and liquid phase respectively (adapted with permission from Ref. [⁴⁴]. Copyright 2016, Royal Society of Chemistry)

Fig.8 Proposal mechanism to explain the different product distribution under different types of light sources using AuCu/TiO₂ catalyst for photoreduction of CO₂ by water (reprinted with permission from Ref. [⁵⁰]. Copyright 2014, American Chemical Society)

Fig.9 Optimization, recycling tests and XRD analysis of Ag-Pd/TiO₂ nanosheets

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