New ferrocenyl derivative with controllable aggregation-induced
emission (AIE) characteristics

doi:10.1007/s11458-010-0110-z

Front. Chem. China

2010, Vol. 5

Issue (2): 241-246 https://doi.org/10.1007/s11458-010-0110-z

Research articles

本期目录

New ferrocenyl derivative with controllable aggregation-induced emission (AIE) characteristics

Dong ZHANG,Liangliang ZHU,Hong LI,Jianhua SU,

Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China;

全文: PDF(273 KB)

Abstract：A novel molecular switch, 7-(N,N-diethylamino)-2-oxo-2H-chromen-4-yl ferrocene carboxylate (FCC), was synthesized and fully characterized by ¹H NMR, ¹³C NMR, and HRMS. Taking advantage of the properties of ferrocene as an electron donor active unit and the coumarin as a fluorescent unit, the dyad FCC shows a fast and reversible redox-switchable fluorescence emission. In sharp contrast to most photoluminescent chromophores, FCC has a unique enhanced emission through aggregation. The change of electrochemical signals (CV and DPV) indicated that the ferrocene (F_c) unit of FCC could form inclusion complex with Me-b-cyclodextrin (CD). This inclusion complex could further weaken the aggregation-induced emission (AIE) effect remarkably. This advance paves the way to introduce AIE property into molecular devices applications.

Key words： ferrocene cyclodextrin molecular switch fluorescence aggregation-induced emission (AIE)

出版日期: 2010-06-05

引用本文:

. New ferrocenyl derivative with controllable aggregation-induced emission (AIE) characteristics[J]. Front. Chem. China, 2010, 5(2): 241-246.
Dong ZHANG, Liangliang ZHU, Hong LI, Jianhua SU, . New ferrocenyl derivative with controllable aggregation-induced emission (AIE) characteristics. Front. Chem. China, 2010, 5(2): 241-246.

链接本文:

https://academic.hep.com.cn/fcc/CN/10.1007/s11458-010-0110-z
https://academic.hep.com.cn/fcc/CN/Y2010/V5/I2/241

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