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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Engineering in China  2010, Vol. 4 Issue (4): 385-393   https://doi.org/10.1007/s11705-010-0501-1
  RESEARCH ARTICLE 本期目录
Effect of pressure on gasification reactivity of three Chinese coals with different ranks
Effect of pressure on gasification reactivity of three Chinese coals with different ranks
Chunyu LI1,2, Jiantao ZHAO1(), Yitian FANG1(), Yang WANG1
1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China
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Abstract

The gasification reactivities of three kinds of different coal ranks (Huolinhe lignite, Shenmu bituminous coal, and Jincheng anthracite) with CO2 and H2O was carried out on a self-made pressurized fixed-bed reactor at increased pressures (up to 1.0 MPa). The physicochemical characteristics of the chars at various levels of carbon conversion were studied via scanning electron microscopy (SEM), X-ray diffraction (XRD), and BET surface area. Results show that the char gasification reactivity increases with increasing partial pressure. The gasification reaction is controlled by pore diffusion, the rate decreases with increasing total system pressure, and under chemical kinetic control there is no pressure dependence. In general, gasification rates decrease for coals of progressively higher rank. The experimental results could be well described by the shrinking core model for three chars during steam and CO2 gasification. The values of reaction order n with steam were 0.49, 0.46, 0.43, respectively. Meanwhile, the values of reaction order n with CO2 were 0.31, 0.28, 0.26, respectively. With the coal rank increasing, the pressure order m is higher, the activation energies increase slightly with steam, and the activation energy with CO2 increases noticeably. As the carbon conversion increases, the degree of graphitization is enhanced. The surface area of the gasified char increases rapidly with the progress of gasification and peaks at about 40% of char gasification.

Key wordscoal    gasification    pressure    reaction order    shrinking core model
收稿日期: 2009-11-02      出版日期: 2010-12-05
Corresponding Author(s): ZHAO Jiantao,Email:zhaojt@sxicc.ac.cn; FANG Yitian,Email:fyt@sxicc.ac.cn   
 引用本文:   
. Effect of pressure on gasification reactivity of three Chinese coals with different ranks[J]. Frontiers of Chemical Engineering in China, 2010, 4(4): 385-393.
Chunyu LI, Jiantao ZHAO, Yitian FANG, Yang WANG. Effect of pressure on gasification reactivity of three Chinese coals with different ranks. Front Chem Eng Chin, 2010, 4(4): 385-393.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-010-0501-1
https://academic.hep.com.cn/fcse/CN/Y2010/V4/I4/385
sampleproximate analysis W/wt-%ultimate analysis /wt-% ad
VMACHONSt
HLH coal28.8221.1819.8740.961.7314.330.861.07
HLH char1.380.4459.4036.540.771.090.501.26
SM coal27.537.1212.5663.364.1511.490.950.37
SM char0.850.3718.2876.391.062.370.880.65
JC coal7.440.8923.5266.932.633.680.821.53
JC char0.690.3621.6274.180.901.110.840.99
Tab.1  
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
reaction order nreaction order mactivation energy Ea/(kJ·mol-1)frequency factor A /(s-1·MPa)
HLHChar+ H2O0.493- 0.286114.394.68 × 103
Char+ CO20.312- 0.113120.464.41 × 103
SMChar+ H2O0.457- 0.199126.961.05 × 104
Char+ CO20.283- 0.055168.632.76 × 105
JCChar+ H2O0.428- 0.164138.721.90 × 104
Char+ CO20.264- 0.025209.366.05 × 106
Tab.2  
Fig.7  
Fig.8  
Fig.9  
Fig.10  
1 Kajitani S, Suzuki N, Ashizawa M, Hara S. CO2 gasification rate analysis of coal char in entrained flow coal gasifier. Fuel , 2006, 85(2): 163-169
doi: 10.1016/j.fuel.2005.07.024
2 Huang J J, Fang Y T, Chen H S, Wang Y. Coal gasification characteristic in a pressurized fluidized bed. Energy & Fuels , 2003, 17(6): 1474-1479
doi: 10.1021/ef030052k
3 Liu G, Tate A G, Bryant G W, Wall T F. Mathematical modeling of coal char reactivity with CO2 at high pressures and temperatures. Fuel , 2000, 79(10): 1145-1154
doi: 10.1016/S0016-2361(99)00274-4
4 Kajitani S, Hara S, Matsuda H. Gasification rate analysis of coal char with a pressurized drop tube furnace. Fuel , 2002, 81(5): 539-546
doi: 10.1016/S0016-2361(01)00149-1
5 Muhlen H J, van Heek K H, Juntgen H. Influence of pretreatment temperature and pressure on the char reactivity during hydrogasification. Fuel , 1986, 65(4): 591-593
doi: 10.1016/0016-2361(86)90054-2
6 Li S, Xiao X. Influence of pretreatment temperature and pressure on the char reactivity during hydrogasification. Fuel , 1993, 72: 1351-1353
7 Li S, Sun R. Kinetic studies of a lignite char pressurized gasification with CO2, H2 and steam. Fuel , 1994, 73(3): 413-416
doi: 10.1016/0016-2361(94)90095-7
8 Bhatia K S, Perlmutter S D. A random pore model for fluid-solid reactions. I. Isothermal kinetic control. American Institute of Chemical Engineers , 1980, 26(3): 379-386
9 Liu G S, Niksa S. Coal conversion submodels for design applications at elevated pressures. Part II. Char gasification. Progress in Energy and Combustion Science , 2004, 30(6): 679-717
doi: 10.1016/j.pecs.2004.08.001
10 Li C Y, Zhao J T, Fang Y T, Wang Y. Pressurized fast-pyrolysis characteristics of typical Chinese coals with different ranks. Energy & Fuels , 2009, 23(10): 5099-5105
doi: 10.1021/ef900437h
11 Zhang L X, Huang J J, Fang Y T, Wang Y. Gasification reactivity and kinetics of typical Chinese anthracite chars with steam and CO2. Energy & Fuels , 2006, 20(3): 1201-1210
doi: 10.1021/ef050343o
12 Ahn D H, Gibbs B M, Ko K H, Kim J J. Gasification kinetics of an Indonesian subbituminous coal char with CO2 at elevated pressure. Fuel , 2001, 80(11): 1651-1658
doi: 10.1016/S0016-2361(01)00024-2
13 Linares-Solano A, Mahajan O P, Walker P Jr. Reactivity of heat-treated coals in steam. Fuel , 1979, 58(5): 327-332
doi: 10.1016/0016-2361(79)90148-0
14 Liu T F, Fang Y T, Wang Y. An experimental investigation into the gasification reactivity of chars prepared at high temperatures. Fuel , 2008, 87(4-5): 460-466
doi: 10.1016/j.fuel.2007.06.019
15 Jüntgen H. Reactivities of carbon to steam and hydrogen and applications to technical gasification processes—A review. Carbon , 1981, 19(3): 167-173
doi: 10.1016/0008-6223(81)90039-7
16 Goyal A, Zabransky R F, Rehmat A. Gasification kinetics of Western Kentucky bituminous coal char. Industrial & Engineering Chemistry Research , 1989, 28(12): 1767-1778
doi: 10.1021/ie00096a006
17 Jones R B, Mccourt C B, Morley C, King K. Maceral and rank influences on the morphology of coal char. Fuel , 1985, 64(10): 1460-1467
doi: 10.1016/0016-2361(85)90351-5
18 Hurt R H, Davis K A, Yang N Y C, Headley T J, Mitchell G D. Residual carbon from pulverized-coal-fired boilers. 2. Morphology and physicochemical properties. Fuel , 1995, 74(9): 1297-1306
doi: 10.1016/0016-2361(95)00100-J
19 Sadhukhan A K, Gupta P, Saha R K. Characterization of porous structure of coal char from a single devolatilized coal particle: Coal combustion in a fluidized bed. Fuel Processing Technology , 2009, 90(5): 692-700
doi: 10.1016/j.fuproc.2008.12.010
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