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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2011, Vol. 5 Issue (1): 35-42   https://doi.org/10.1007/s11705-010-0551-4
  RESEARCH ARTICLE 本期目录
Outdoor aging of road asphalt and SBS modified asphalt
Outdoor aging of road asphalt and SBS modified asphalt
Li XIANG1, Juan TU2, Jian CHENG3,4(), Guohe QUE1
1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266555, China; 2. Hubei Guochuang Advanced Material Ltd.Co., Wuhan 430073, China; 3. Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073, China; 4. Hubei Key Lab of Novel Reactor & Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430073, China
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Abstract

The process of performance degradation of road asphalt (RA) is regarded as aging. At present, better understanding of the thermal-oxidative aging of asphalt is achieved and the corresponding method to evaluate this process is developed; meanwhile, photo-oxidative aging (aging in an atmospheric environment, which is referred to as “outdoor aging” in this paper) of asphalt remains at the initial stages of scientific exploration. The outdoor natural ultraviolet (UV) aging of RA and SBS modified asphalt (SBSMA) are investigated in this study. The experimental results show that the basic performances of RA and SBSMA present similar change tendencies. The softening point increased, while the penetration and ductility decreased as the outdoor aging time passed by, and the 5°C ductility (ductility measured at 5°C) of SBSMA decreased very quickly. The group components of RA and SBSMA also change during UV aging. The content of asphaltene rose and that of aromatics and saturates decreased, while the content of resins changed insignificantly. Moreover, the Fourier transform infrared (FTIR) graphs show that the content of sulfoxide and carbonyl groups in RA and SBSMA increased significantly during the outdoor aging process.

Key wordsasphalt    SBS    modified road asphalt    outdoor aging    ultraviolet
收稿日期: 2010-03-25      出版日期: 2011-03-05
Corresponding Author(s): CHENG Jian,Email:wuhancengjian@163.com   
 引用本文:   
. Outdoor aging of road asphalt and SBS modified asphalt[J]. Frontiers of Chemical Science and Engineering, 2011, 5(1): 35-42.
Li XIANG, Juan TU, Jian CHENG, Guohe QUE. Outdoor aging of road asphalt and SBS modified asphalt. Front Chem Sci Eng, 2011, 5(1): 35-42.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-010-0551-4
https://academic.hep.com.cn/fcse/CN/Y2011/V5/I1/35
itemsRASBSMA
penetration (25°C, 100 g, 5 s, 0.l mm)67.359.9
ductility (5°C, 5 cm/min, cm)4.846.2
ductility (15°C, 5 cm/min, cm)>15085.2
softening point (ring and ball, °C)50.862.9
elastic recovery (25°C, 10 cm, 60 min, %)--93
TFOT residuum
?mass loss (%)0.070.06
?penetration (25°C, 100 g, 5 s, 0.l mm)46.250.9
?ductility (5°C, 5 cm/min, cm)--25.7
?ductility (15°C, 5 cm/min, cm)10150.8
?softening point (ring and ball, °C)53.365.4
?5°C ductility ratio (%)--55.6
?25°C penetration ratio (%)68.685.0
Tab.1  
samples25°C penetration /(0.1 mm)ratio of penetration a) /%15°C ductility /cmratio of ductility a) /%softening point /°C
RA66.2-->150--50.8
TFOT46.2100.0101.0100.053.3
3 months outdoor aging27.860.26.26.159.3
6 months outdoor aging21.245.93.73.764.4
9 months outdoor aging15.734.00.30.365.7
12 months outdoor aging12.026.00--65.8
Tab.2  
samples25°C penetration / (0.1 mm)ratio of penetration a) /%5°C ductility /cm15°C ductility /cmratio of 15°C ductility a) /%softening point /°C
SBSMA59.9--46.285.2--62.9
TFOT50.9100.025.750.8100.065.4
3 months outdoor aging31.361.5016.432.366.5
6 months outdoor aging25.750.509.819.370.0
9 months outdoor aging21.642.409.819.370.6
12 months outdoor aging19.137.508.917.571.6
3 months simulated agingb)40.078.616.3----65.2
Tab.3  
Fig.1  
samplesasphaltenes /%saturates /%aromatics /%resins /%Ic
RA9.0813.3749.2728.280.2895
TFOT10.9313.4646.5329.080.3226
3 months outdoor aging14.0311.7341.9930.790.3539
6 months outdoor aging16.2411.5838.8730.230.4026
9 months outdoor aging16.4311.6837.8830.770.4095
3 months simulated aging a)12.9412.3344.8129.920.3382
SBSMA14.0612.6846.3626.900.3650
TFOT15.9912.4944.9826.540.3982
3 months outdoor aging17.6711.2139.9128.090.4247
6 months outdoor aging19.2110.4738.9728.070.4427
9 months outdoor aging19.4311.3737.7328.330.4662
3 months simulated aging a)16.0012.6044.3925.490.4093
Tab.4  
Fig.2  
Fig.3  
Fig.4  
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