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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2011, Vol. 5 Issue (3): 362-371   https://doi.org/10.1007/s11705-011-1106-z
  RESEARCH ARTICLE 本期目录
An investigation of reaction furnace temperatures and sulfur recovery
An investigation of reaction furnace temperatures and sulfur recovery
S. ASADI(), M. PAKIZEH, M. POURAFSHARI CHENAR
Chemical Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad P.O. Box 91775-1111, Iran
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Abstract

In a modern day sulfur recovery unit (SRU), hydrogen sulfide (H2S) is converted to elemental sulfur using a modified Claus unit. A process simulator called TSWEET has been used to consider the Claus process. The effect of the H2S concentration, the H2S/CO2 ratio, the input air flow rate, the acid gas flow of the acid gas (AG) splitter and the temperature of the acid gas feed at three different oxygen concentrations (in the air input) on the main burner temperature have been studied. Also the effects of the tail gas ratio and the catalytic bed type on the sulfur recovery were studied. The bed temperatures were optimized in order to enhance the sulfur recovery for a given acid gas feed and air input. Initially when the fraction of AG splitter flow to the main burner was increased, the temperature of the main burner increased to a maximum but then decreased sharply when the flow fraction was further increased; this was true for all three concentrations of oxygen. However, if three other parameters (the concentration of H2S, the ratio H2S/CO2 and the flow rate of air) were increased, the temperature of the main burner increased monotonically. This increase had different slopes depending on the oxygen concentration in the input air. But, by increasing the temperature of the acid gas feed, the temperature of the main burner decreased. In general, the concentration of oxygen in the input air into the Claus unit had little effect on the temperature of the main burner (This is true for all parameters). The optimal catalytic bed temperature, tail gas ratio and type of catalytic bed were also determined and these conditions are a minimum temperature of 300°C, a ratio of 2.0 and a hydrolysing Claus bed.

Key wordsClaus unit    concentration of H2S    tail gas ratio    sulfur recovery    catalytic bed
收稿日期: 2011-01-20      出版日期: 2011-09-05
Corresponding Author(s): ASADI S.,Email:samerasadi@yahoo.com   
 引用本文:   
. An investigation of reaction furnace temperatures and sulfur recovery[J]. Frontiers of Chemical Science and Engineering, 2011, 5(3): 362-371.
S. ASADI, M. PAKIZEH, M. POURAFSHARI CHENAR. An investigation of reaction furnace temperatures and sulfur recovery. Front Chem Sci Eng, 2011, 5(3): 362-371.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-011-1106-z
https://academic.hep.com.cn/fcse/CN/Y2011/V5/I3/362
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Composition /mol-%Acid gas+ fuel gasInput air
Ar00.96
O2021.77
H200
N2077.24
CO267.730.03
H2S31.260
CH41.010
Total100.00100.00
Temperature /°C12070
Pressure /psia3014.7
Tab.1  
Fig.7  
Type of second catalytic bedType of third catalytic bed
Claus bedHydrolyzing Claus bedSub dew point
Claus bed96.67%98.04%96.68%
Hydrolyzing Claus bed98.28%98.35%98.28%
Sub dew point Claus bed96.68%98.04%96.68%
Tab.2  
Type of second catalytic bedType of third catalytic bed
Claus bedHydrolyzing Claus bedSub dew point
Claus bed98.26%98.38%98.26%
Hydrolyzing Claus bed98.40%98.40%98.40%
Sub dew point Claus bed98.26%98.38%98.26%
Tab.3  
Type of second catalytic bedType of third catalytic bed
Claus bedHydrolyzing Claus bedSub dew point
Claus bed96.68%98.04%96.68%
Hydrolyzing Claus bed98.28%98.35%98.28%
Sub dew point Claus bed96.68%98.04%96.68%
Tab.4  
Fig.8  
1 Elbishtawi R, Haimour N. Claus recycles with double combustion process. Fuel Processing Technology , 2004, 86(3): 245–260
doi: 10.1016/j.fuproc.2004.04.001
2 ZareNezhad B. An investigation on the most important influencing parameters regarding the selection of the proper catalysts for Claus SRU converts. Journal of Industrial and Engineering Chemistry , 2009, 15(2): 143–147
doi: 10.1016/j.jiec.2008.08.020
3 Monnery W D, Svrcek W Y, Behie L A. Modeling the modified Claus process reaction furnace and the implications on plant design and recovery. Canadian Journal of Chemical Engineering , 1993, 71(5): 711–724
doi: 10.1002/cjce.5450710509
4 Nasato L V, Karan K, Mehrotra A K, Behie L A. Modeling reaction quench times in the waste heat boiler of a Claus plant. Industrial & Engineering Chemistry Research , 1994, 33(1): 7–13
doi: 10.1021/ie00025a002
5 Kamyshny A Jr, Goifman A, Rizkov D, Lev O. Formation of carbonyl sulfide by the reaction of carbon monoxide and inorganic polysulfides. Environmental Science & Technology , 2003, 37(9): 1865–1872
doi: 10.1021/es0201911
6 Zarenezhad B, Hosseinpour N. Evaluation of different alternatives for increasing the reaction furnace temperature of Claus SRU by chemical equilibrium calculations. Applied Thermal Engineering , 2008, 28(7): 738–744
doi: 10.1016/j.applthermaleng.2007.06.014
7 Fisher H. Burner/fire box design improves sulphur recovery. Hydrocarbon Processing , 1974: 27–30
8 Covington K, Mclntyre G. Investigate your option. Hydrocarbon Engineering , 2002: 81–84
9 Mcintyre G, Lyddon L.Claus sulphur recovery options. Petroleum Technology Quarterly Spring , 1997: 57–61
10 Lins V F C, Guimaraes E M. Failure of a heat exchanger generated by an excess of SO2 and H2S in the sulphur recovery unit of a petroleum refinery. Journal of Loss Prevention in the Process Industries , 2007, 20(1): 91–97
doi: 10.1016/j.jlp.2006.10.007
11 Boussetta N, Lanoisellé J L, Bedel-Cloutour C, Vorobiev E. Extraction of soluble matter from grape pomace by high voltage electrical discharges for polyphenol recovery: effect of sulphur dioxide and thermal treatments. Journal of Food Engineering , 2009, 95(1): 192–198
doi: 10.1016/j.jfoodeng.2009.04.030
12 Zagoruiko A N, Matro Y S. Mathematical modelling of Claus reactors undergoing sulphur condensation and evaporation. Chemical Engineering Journal , 2002, 87(1): 73–88
doi: 10.1016/S1385-8947(01)00203-0
13 Mattssonboze K W, Lyddon L G. Using a process simulator to improve sulphur recovery. Sulphur (Jan/Feb) , 1997, 37–41
14 Maddox R N. Gas Conditioning and Processing: Gas and Liquid Sweetening. Campbell Petroleum Series Vol. 4, 4th Ed. Oklahoma: Norman, 1998
15 Roberge P R. Handbook of Corrosion Engineering. New York: McGraw Hill, 1999, 833–862
16 Chen Y Y, Liou Y M, Shih H C. Stress corrosion cracking of type 321 stainless steels in simulated petrochemical process environments containing hydrogen sulfide and chloride. Materials Science and Engineering A , 2005, 407(1-2): 114–126
doi: 10.1016/j.msea.2005.07.011
17 Ramos M A, Mainier F B, Pimenta G S. Corros?o por H2S e CO2 em sistema de produc?o de petróleo, Petrobrás, Rio de Janeiro, 1982
18 Vagapov R K, Frolova L V, Kuznetsov Y I. Inhibition effect of Schiff base on steel hydrogenation in H2S-containing media. Protection of Metals , 2002, 38(1): 27–31
doi: 10.1023/A:1013896516283
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