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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2014, Vol. 8 Issue (2): 197-202   https://doi.org/10.1007/s11705-014-1417-y
  本期目录
Enhanced hydrogen production from aqueous methanol solution using TiO2/Cu as photocatalysts
Paramasivan GOMATHISANKAR1,*(),Tomoko NODA1,Hideyuki KATSUMATA1,Tohru SUZUKI2,Satoshi KANECO1,*()
1. Department of Chemistry for Materials, Graduate School of Engineering, Mie University, Mie 514–8507, Japan
2. Environmental Preservation Center, Mie University, Mie 514-8507, Japan
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Abstract

The photocatalytic hydrogen production from aqueous methanol solution using titanium dioxide (TiO2) was investigated in the addition of metal particles including copper, lead, tin, and zinc. The results show that only the addition of copper particles enhances the hydrogen production. The copper usage and reaction temperature were further optimized for TiO2/Cu photocatalyts. Under the optimal conditions, the hydrogen production using TiO2/Cu as photocatalysts is approximately 68 times higher than that obtained with only TiO2.

Key wordsphotocatalytic hydrogen generation    methanol    copper particles    TiO2    metal-semiconductor interface
收稿日期: 2013-01-24      出版日期: 2014-05-22
Corresponding Author(s): Paramasivan GOMATHISANKAR   
 引用本文:   
. [J]. Frontiers of Chemical Science and Engineering, 2014, 8(2): 197-202.
Paramasivan GOMATHISANKAR,Tomoko NODA,Hideyuki KATSUMATA,Tohru SUZUKI,Satoshi KANECO. Enhanced hydrogen production from aqueous methanol solution using TiO2/Cu as photocatalysts. Front. Chem. Sci. Eng., 2014, 8(2): 197-202.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-014-1417-y
https://academic.hep.com.cn/fcse/CN/Y2014/V8/I2/197
Fig.1  
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Fig.6  
Fig.7  
MetalCrytal strurcture [33]Work function/eV [34]Electronegativity [33]Polarizability*
CuFcca)4.651.906.1-6.2
PbFcc4.251.806.8
SnFcc4.421.967.7
ZnHcpb)4.331.655.76-6.1
Tab.1  
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