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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2018, Vol. 12 Issue (2): 209-225   https://doi.org/10.1007/s11705-017-1688-1
  本期目录
Study of the robustness of a low-temperature dual-pressure process for removal of CO2 from natural gas
Stefania Moioli1(), Laura A. Pellegrini1, Paolo Vergani2, Fabio Brignoli2
1. Department of Chemistry, Materials and Chemical Engineering “G. Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, I-20133 Milano, Italy
2. Maire Tecnimont S.p.A. Via Gaetano De Castillia 6/A, I-20124 Milano, Italy
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Abstract

The growing use of energy by most of world population and the consequent increasing demand for energy are making unexploited low quality gas reserves interesting from an industrial point of view. To meet the required specifications for a natural gas grid, some compounds need to be removed from the sour stream. Because of the high content of undesired compounds (i.e., CO2) in the stream to be treated, traditional purification processes may be too energy intensive and the overall system may result unprofitable, therefore new technologies are under study. In this work, a new process for the purification of natural gas based on a low temperature distillation has been studied, focusing on the dynamics of the system. The robustness of the process has been studied by dynamic simulation of an industrial-scale plant, with particular regard to the performances when operating conditions are changed. The results show that the process can obtain the methane product with a high purity and avoid the solidification of carbon dioxide.

Key wordsCO2 capture    innovative process    cryogenic distillation    dynamic simulation    solid-liquid-vapor equilibrium
收稿日期: 2017-05-08      出版日期: 2018-05-09
Corresponding Author(s): Stefania Moioli   
 引用本文:   
. [J]. Frontiers of Chemical Science and Engineering, 2018, 12(2): 209-225.
Stefania Moioli, Laura A. Pellegrini, Paolo Vergani, Fabio Brignoli. Study of the robustness of a low-temperature dual-pressure process for removal of CO2 from natural gas. Front. Chem. Sci. Eng., 2018, 12(2): 209-225.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-017-1688-1
https://academic.hep.com.cn/fcse/CN/Y2018/V12/I2/209
Fig.1  
Unit Section P/bar
High pressure column top 46
Low pressure column top 40
Tab.1  
Parameter Value
Temperature /°C 27.64
Pressure /bar 62.01
Vapor fraction 1
Molar flow /(kmol?h?1) 10000
Composition (molar fraction)
Methane 0.6300
Carbon dioxide 0.2500
Nitrogen 0.0090
Ethane 0.0210
Hydrogen sulfide 0.0700
Propane 0.0126
n-Butane 0.0074
Tab.2  
Fig.2  
Parameter Top product Bottom product
Temperature /°C −88.11 15.31
Pressure /bar 40 47.03
Vapor fraction 1 0
Molar flow /(kmol?h?1) 6390 3611
Composition (molar fraction)
Methane 0.98584715 1.09E−04
Carbon dioxide 6.65E−05 0.692448
Nitrogen 0.01409 ?
Ethane ? 0.05815
Hydrogen sulfide ? 0.19390
Propane ? 0.03490
n-Butane ? 0.02050
Tab.3  
Controller Kc tI /min tD /min
FC-309 0.4 0.5 0
PC-C301 10 1 0
PC-V301 10 1 0
TC-320 3 0.2 0
TC-322 5 0.1 0
LC-E301 2 2 0
LC-V301 3 2 0
LC-C301 2 2 0
LC-C302 2 2 0
RefluxC-C301 0.05 1 0
BoilupC-C301 0.1 1 0
Tab.4  
Fig.3  
Stream/holdup T /°C Tfreeze /°C DTfreeze = T-Tfreeze /°C
C-301 (tray 1) −75.40 −111.8 36.41
C-301 (tray 2) −70.45 −111.8 41.36
C-301 (tray 3) −61.97 −111.8 49.83
321 −83.54 −94.6 11.06
322 −84.55 −94.32 9.769
C-302 (tray 30) −82.83 −87.83 5.001
C-302 (tray 29) −84.06 −111.8 27.76
323 −82.74 −87.88 5.139
Tab.5  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
Fig.9  
Fig.10  
Fig.11  
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