Catalytic combustion of methane over a highly active and stable NiO/CeO2 catalyst
Xiuhui Huang1,2(), Junfeng Li3, Jun Wang1,2, Zeqiu Li1,2, Jiayin Xu1,2()
1. School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China 2. Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China 3. Shanghai MCC20 Construction Co. Ltd., Shanghai 201999, China
In the last decades, many reports dealing with technology for the catalytic combustion of methane (CH4) have been published. Recently, attention has increasingly focused on the synthesis and catalytic activity of nickel oxides. In this paper, a NiO/CeO2 catalyst with high catalytic performance in methane combustion was synthesized via a facile impregnation method, and its catalytic activity, stability, and water-resistance during CH4 combustion were investigated. X-ray diffraction, low-temperature N2 adsorption, thermogravimetric analysis, Fourier transform infrared spectroscopy, hydrogen temperature programmed reduction, methane temperature programmed surface reaction, Raman spectroscopy, electron paramagnetic resonance, and transmission electron microscope characterization of the catalyst were conducted to determine the origin of its high catalytic activity and stability in detail. The incorporation of NiO was found to enhance the concentration of oxygen vacancies, as well as the activity and amount of surface oxygen. As a result, the mobility of bulk oxygen in CeO2 was increased. The presence of CeO2 prevented the aggregation of NiO, enhanced reduction by NiO, and provided more oxygen species for the combustion of CH4. The results of a kinetics study indicated that the reaction order was about 1.07 for CH4 and about 0.10 for O2 over the NiO/CeO2 catalyst.
. [J]. Frontiers of Chemical Science and Engineering, 2020, 14(4): 534-545.
Xiuhui Huang, Junfeng Li, Jun Wang, Zeqiu Li, Jiayin Xu. Catalytic combustion of methane over a highly active and stable NiO/CeO2 catalyst. Front. Chem. Sci. Eng., 2020, 14(4): 534-545.
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