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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2021, Vol. 15 Issue (1): 118-126   https://doi.org/10.1007/s11705-020-1916-y
  本期目录
Polymeric ionic liquid—assisted polymerization for soluble polyaniline nanofibers
Jie Liu1, Jiahao Shen1, Jingjing Wang1, Yuan Liang1, Routeng Wu1, Wenwen Zhang1, Delin Shi2, Saixiang Shi2, Yanping Wang1, Yimin Wang1, Yumin Xia1()
1. Key Laboratory of High Performance Fibers & Products (Ministry of Education), State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Science, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
2. Hunan Changsha Aiwanting Home Texitle Products Co. Ltd, Changsha 410600, China
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Abstract

To enhance the solubility of polyanilines (PANI), polymeric ionic liquid (PIL) was introduced into the polymerization synthesis of PANI with various proportions. The structure and properties of the modified PANIs were characterized by 1H NMR, Fourier transform infrared spectroscopy, thermogravimetric analysis, ultraviolet-visible spectrum, etc. It was found that the obtained PANIs doped with PILs were soluble in various organic solvents such as N,N-dimethyl formamide and acetonitrile. Compared with the pure PANI, the PANIs doped by PILs showed remarkable solubility and their chemical structure and conductivity kept integrated.

Key wordspolyaniline    polymeric ionic liquid    doping    solubility
收稿日期: 2019-10-21      出版日期: 2021-01-12
Corresponding Author(s): Yumin Xia   
 引用本文:   
. [J]. Frontiers of Chemical Science and Engineering, 2021, 15(1): 118-126.
Jie Liu, Jiahao Shen, Jingjing Wang, Yuan Liang, Routeng Wu, Wenwen Zhang, Delin Shi, Saixiang Shi, Yanping Wang, Yimin Wang, Yumin Xia. Polymeric ionic liquid—assisted polymerization for soluble polyaniline nanofibers. Front. Chem. Sci. Eng., 2021, 15(1): 118-126.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-020-1916-y
https://academic.hep.com.cn/fcse/CN/Y2021/V15/I1/118
Sample Sample 1 Sample 2 Sample 3 Sample 4
Weight of PIL-Cl/g 0 0.93 1.24 1.86
Weight ratio of PIL-Cl to ANI 0 1:4 1:3 1:2
Tab.1  
Materials ratio Weight loss/% Complex ratio Sample name
PIL-Cl/% PANI/%
1:0 85.4 ? ? PIL-Cl
1:2 46.5 46.5 53.5 PANIPIL3
1:3 25.3 17.4 82.6 PANIPIL1
1:4 34.1 29.5 70.5 PANIPIL2
0:1 12.6 ? ? PANI
Tab.2  
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
Samples Resistivity/(W·mm)
PANI 134
PANIPIL1 136
PANIPIL2 697
PANIPIL3 3002
Tab.3  
Fig.9  
Samples Resistivity/(W·mm)
PANI 134
PANIPIL1 136
PANIPIL-G 17
Tab.4  
Fig.10  
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