1. Key Laboratory of High Performance Fibers & Products (Ministry of Education), State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Science, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China 2. Hunan Changsha Aiwanting Home Texitle Products Co. Ltd, Changsha 410600, China
To enhance the solubility of polyanilines (PANI), polymeric ionic liquid (PIL) was introduced into the polymerization synthesis of PANI with various proportions. The structure and properties of the modified PANIs were characterized by 1H NMR, Fourier transform infrared spectroscopy, thermogravimetric analysis, ultraviolet-visible spectrum, etc. It was found that the obtained PANIs doped with PILs were soluble in various organic solvents such as N,N-dimethyl formamide and acetonitrile. Compared with the pure PANI, the PANIs doped by PILs showed remarkable solubility and their chemical structure and conductivity kept integrated.
S E Jacobo, J C Aphesteguy, R L Anton, N N Schegoleva, G V Kurlyandskaya. Influence of the preparation procedure on the properties of polyaniline based magnetic composites. European Polymer Journal, 2007, 43(4): 1333–1346 https://doi.org/10.1016/j.eurpolymj.2007.01.024
2
S L Bai, Y B Zhao, J H Sun, Y Tian, R X Luo, D Q Li, A F Chen. Ultrasensitive room temperature NH3 sensor based on a graphene-polyaniline hybrid loaded on PET thin film. Chemical Communications, 2015, 51(35): 7524–7527 https://doi.org/10.1039/C5CC01241D
3
L L Wang, H Huang, S H Xiao, D P Cai, Y Liu, B Liu, D D Wang, C X Wang, H Li, Y R Wang, Q Li, T Wang. Enhanced sensitivity and stability of room-temperature NH3 sensors using core-shell CeO2 nanoparticles@cross-linked PANI with p-n heterojunctions. ACS Applied Materials & Interfaces, 2014, 6(16): 14131–14140 https://doi.org/10.1021/am503286h
4
T Hino, T Namiki, N Kuramoto. Synthesis and characterization of novel conducting composites of polyaniline prepared in the presence of sodium dodecylsulfonate. Synthetic Metals, 2006, 156(21): 1327–1332 https://doi.org/10.1016/j.synthmet.2006.10.001
5
A Fahmy, W H Eisa, M Yosef, A Hassan. Ultra-thin films of poly(acrylic acid)/silver nanocomposite coatings for antimicrobial applications. Journal of Spectroscopy, 2016, 5: 1–11 https://doi.org/10.1155/2016/7489536
6
B S Anisha, R Biswas, K P Chennazhi, R Jayakumar. Chitosan-hyaluronic acid/nano silver composite sponges for drug resistant bacteria infected diabetic wounds. International Journal of Biological Macromolecules, 2013, 62(11): 310–320 https://doi.org/10.1016/j.ijbiomac.2013.09.011
A O Patil, A J Heeger, F Wudl. Optical properties of conducting polymers. Chemical Reviews, 1988, 88(1): 183–200 https://doi.org/10.1021/cr00083a009
10
S Bilal, S Gul, R Holze, A H A Shah. Shah. An impressive emulsion polymerization route for the synthesis of highly soluble and conducting polyaniline salts. Synthetic Metals, 2015, 206: 131–144 https://doi.org/10.1016/j.synthmet.2015.05.015
11
Z F Cao, Y Q Xia, C Chen. Fabrication of novel ionic liquids-doped polyaniline as lubricant additive for anti-corrosion and tribological properties. Tribology International, 2018, 120: 446–454 https://doi.org/10.1016/j.triboint.2018.01.009
12
B Urbach, N Korbakov, Y Bar-David, S Yitzchaik, A Sa’Ar. Composite structures of polyaniline and mesoporous silicon: Electrochemistry, optical and transport properties. Journal of Physical Chemistry C, 2007, 111(44): 16586–16592 https://doi.org/10.1021/jp073647f
13
E Harlev, T Gulakhmedova, I Rubinovich, G Aizenshtein. A new method for the preparation of conductive polyaniline solutions: Application to liquid crystal devices. Advanced Materials, 1996, 8(12): 994–997 https://doi.org/10.1002/adma.19960081211
14
J Q Dong, Q Shen. Enhancement in solubility and conductivity of polyaniline with lignosulfonate modified carbon nanotube. Journal of Polymer Science. Part B, Polymer Physics, 2010, 47(20): 2036–2046 https://doi.org/10.1002/polb.21802
15
M Ayad, G El-Hefnawy, S Zaghlol. Facile synthesis of polyaniline nanoparticles; its adsorption behavior. Chemical Engineering Journal, 2013, 217(2): 460–465 https://doi.org/10.1016/j.cej.2012.11.099
16
P J Kinlen, B G Frushour, Y Ding, V Menon. Synthesis and characterization of organically soluble polyaniline and polyaniline block copolymers. Synthetic Metals, 1999, 101(1): 758–761 https://doi.org/10.1016/S0379-6779(98)00280-X
17
Y Wang, K Chen, T Li, H M Li, R C Zeng, R L Zhang, Y J Gu, J X Ding, H Q Liu. Soluble polyaniline nanofibers prepared via surfactant-free emulsion polymerization. Synthetic Metals, 2014, 198: 293–299 https://doi.org/10.1016/j.synthmet.2014.10.038
18
L F Calheiros, B G Soares, G M O Barra, S Livi. Ionic liquid—assisted emulsion polymerization of aniline in organic medium. Materials Chemistry and Physics, 2016, 179: 194–203 https://doi.org/10.1016/j.matchemphys.2016.05.028
19
Y Cao, P Smith, A J Heeger. Counter-ion induced processibility of conducting polyaniline and of conducting polyblends of polyaniline in bulk polymers. Synthetic Metals, 1992, 48(1): 91–97 https://doi.org/10.1016/0379-6779(92)90053-L
K Deb, K Sarkar, A Bera, A Debnath, B Saha. Coupled polaron-electron charge transport in graphite functionalized polyaniline on cellulose: Metal free flexible p-type semiconductor. Synthetic Metals, 2018, 245: 96–101 https://doi.org/10.1016/j.synthmet.2018.08.011
R Marcilla, M L Curri, P D Cozzoli, M T Martínez, I Loinaz, H Grande, J A Pomposo, D Mecerreyes. Nano-objects on a round trip from water to organics in a polymeric ionic liquid vehicle. Small, 2006, 2(4): 507–512 https://doi.org/10.1002/smll.200500373
26
D Schüler, B Kerscher, F Beckert, R Thomann, R Mülhaupt. Hyperbranched polymeric ionic liquids with onion-like topology as transporters and compartmentalized systems. Angewandte Chemie International Edition, 2013, 52(1): 455–458 https://doi.org/10.1002/anie.201205130
27
S Bellayer, J W Gilman, N Eidelman, S Bourbigot, X Flambard, D M Fox, H C Long, P C Trulove. Preparation of homogeneously dispersed multiwalled carbon nanotube/polystyrene nanocomposites via melt extrusion using trialkyl imidazolium compatibilizer. Advanced Functional Materials, 2010, 15(6): 910–916 https://doi.org/10.1002/adfm.200400441
28
T Y Kim, H W Lee, J E Kim, K S Suh. Synthesis of phase transferable graphene sheets using ionic liquid polymers. ACS Nano, 2010, 4(3): 1612–1618 https://doi.org/10.1021/nn901525e
29
H L Zhao, Y T Yu, Z H Li, B Luo, X H Wang, Y P Wang, Y M Xia. Linear polymeric ionic liquids as phase-transporters for both cationic and anionic dyes with synergic effects. Polymer Chemistry, 2015, 6(39): 7060–7068 https://doi.org/10.1039/C5PY01123J
30
R Fabio, N G M Do, P S Santos. Dissolution and doping of polyaniline emeraldine base in imidazolium ionic liquids investigated by spectroscopic techniques. Macromolecular Rapid Communications, 2010, 28(5): 666–669
31
L F Calheiros, B G Soares, G M O Barra, S Livi. Ionic liquid-assisted emulsion polymerization of aniline in organic medium. Materials Chemistry and Physics, 2016, 179: 194–203 https://doi.org/10.1016/j.matchemphys.2016.05.028
32
K Zhang, L L Zhang, X S Zhao, J Wu. Graphene/polyaniline nanofiber composites as supercapacitor electrodes. Chemistry of Materials, 2010, 22(4): 1392–1401 https://doi.org/10.1021/cm902876u
33
J Pernak, M Smiglak, S T Griffin, W L Hough, T B Wilson, A Pernak, J Zabielska-Matejuk, A Fojutowski, K Kitad, R D Rogers. Long alkyl chain quaternary ammonium-based ionic liquids and potential applications. Green Chemistry, 2006, 8(9): 798–806 https://doi.org/10.1039/b604353d
34
S G Vaidya, S Rastogi, A Aguirre. Surfactant assisted processable organic nanocomposite dispersions of polyaniline-single wall carbon nanotubes. Synthetic Metals, 2010, 160(1): 134–138 https://doi.org/10.1016/j.synthmet.2009.10.020
35
J P Pouget, M E Jozefowicz, A J Epstein, X Tang, A G MacDiarmid. X-ray structure of polyaniline. Macromolecules, 1991, 24(3): 779–789 https://doi.org/10.1021/ma00003a022
36
Z Zhang, M Wan, Y Wei. Highly crystalline polyaniline nanostructures doped with dicarboxylic acids. Advanced Functional Materials, 2010, 16(8): 1100–1104 https://doi.org/10.1002/adfm.200500636
37
X Z Fu, Y Liang, R T Wu, J H Shen, Z D Chen, Y W Chen, Y P Wang, Y M Xia. Conductive core-sheath calcium alginate/graphene composite fibers with polymeric ionic liquids as an intermediate. Carbohydrate Polymers, 2019, 206: 328–335 https://doi.org/10.1016/j.carbpol.2018.11.021