Antibacterial and anti-flaming PA6 composite with metathetically prepared nano AgCl@BaSO4 co-precipitates

doi:10.1007/s11705-020-1942-9

Frontiers of Chemical Science and Engineering

2021, Vol. 15

Issue (2): 340-350 https://doi.org/10.1007/s11705-020-1942-9

本期目录

Antibacterial and anti-flaming PA6 composite with metathetically prepared nano AgCl@BaSO₄ co-precipitates

Wei Zhang¹, Boren Xu¹, Caihong Gong¹, Chunwang Yi^1,²(

), Shen Zhang¹

¹. Key Laboratory of Sustainable Resources Processing and Advanced Materials of Hunan Province, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China
². National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, China

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Abstract：

In this study, a facile and environmentally friendly method with low energy consumption for preparing nanoscale AgCl and BaSO₄ co-precipitates (AgCl@BaSO₄ co-precipitates) was developed based on the metathetical reaction. Then, the dried co-precipitates were melt-compounded with polyamide 6 (PA6) resins at a specified mass ratio in a twin-screw extruder. The results demonstrated that in the absence of any coating agent or carrier, the nanoparticles of AgCl@BaSO₄ co-precipitates were homogeneously dispersed in the PA6 matrix. Further analysis showed that after the addition of AgCl@BaSO₄ co-precipitates, the antibacterial performance, along with the flame-retardance and anti-dripping characteristics of PA6, was enhanced significantly. In addition, the PA6 composites possessed high spinnability in producing pre-oriented yarn.

Key words： nano AgCl@BaSO₄ co-precipitates antibacterial flame resistance PA6 composite PA6 yarn

收稿日期: 2019-12-15 出版日期: 2021-03-10

Corresponding Author(s): Chunwang Yi

引用本文:

. [J]. Frontiers of Chemical Science and Engineering, 2021, 15(2): 340-350.
Wei Zhang, Boren Xu, Caihong Gong, Chunwang Yi, Shen Zhang. Antibacterial and anti-flaming PA6 composite with metathetically prepared nano AgCl@BaSO₄ co-precipitates. Front. Chem. Sci. Eng., 2021, 15(2): 340-350.

链接本文:

https://academic.hep.com.cn/fcse/CN/10.1007/s11705-020-1942-9
https://academic.hep.com.cn/fcse/CN/Y2021/V15/I2/340

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1	G R Hatfield, J H Glans, W B Hammond. Characterization of structure and morphology in nylon 6 by solid-state carbon-13 and nitrogen-15 NMR. Macromolecules, 1990, 23(6): 1654–1658 https://doi.org/10.1021/ma00208a016
2	S M Peng, L Peng, C W Yi, W Zhang, X Wang. A novel synthetic strategy for preparing semi-aromatic components modified polyamide 6 polymer. Journal of Polymer Science. Part A, Polymer Chemistry, 2018, 56(9): 959–967 https://doi.org/10.1002/pola.28983
3	G Panthi, N A M Barakat, P Risal, A Yousef, B Pant, A R Unnithan, H Y Kim. Preparation and characterization of nylon-6/gelatin composite nanofibers via electrospinning for biomedical applications. Fibers and Polymers, 2013, 14(5): 718–723 https://doi.org/10.1007/s12221-013-0718-y
4	F F Qi, Y Cao, M Wang, F Rong, Q Xu. Nylon 6 electrospun nanofibers mat as effective sorbent for the removal of estrogens: Kinetic and thermodynamic studies. Nanoscale Research Letters, 2014, 9(1): 353–362 https://doi.org/10.1186/1556-276X-9-353
5	N J W Reuvers, H P Huinink, H R Fischer, O C G Adan. Quantitative water uptake study in thin nylon-6 films with NMR imaging. Macromolecules, 2012, 45(4): 1937–1945 https://doi.org/10.1021/ma202719x
6	T Liu, R Wang, Z F Dong, Z G Zhu, X Q Zhang, J G Liu. Role of caged bicyclic pentaerythritol phosphate alcohol in flame retardancy of PA6 and mechanism study. Journal of Applied Polymer Science, 2018, 135(19): 46236–46243 https://doi.org/10.1002/app.46236
7	T V Duncan. Applications of nanotechnology in food packaging and food safety: Barrier materials, antimicrobials and sensors. Journal of Colloid and Interface Science, 2011, 363(1): 1–24 https://doi.org/10.1016/j.jcis.2011.07.017
8	J W Wiechers, N Musee. Engineered inorganic nanoparticles and cosmetics: Facts, issues, knowledge gaps and challenges. Journal of Biomedical Nanotechnology, 2010, 6(5): 408–431 https://doi.org/10.1166/jbn.2010.1143
9	G Yuan, R Cranston. Recent advances in antimicrobial treatments of textiles. Textile Research Journal, 2008, 78(1): 60–72 https://doi.org/10.1177/0040517507082332
10	Y T Yang, C W Yi. Surface modification of TiO2 for the preparation of full-dull polyamide-6 polymers. Journal of Materials Science, 2019, 54(13): 9456–9465 https://doi.org/10.1007/s10853-019-03549-x
11	S Chernousova, M Epple. Silver as antibacterial agent: Ion, nanoparticle and metal. Angewandte Chemie International Edition, 2013, 52(6): 1636–1653 https://doi.org/10.1002/anie.201205923
12	Z Liu, W Guo, C Guo, S Liu. Fabrication of AgBr nanomaterials as excellent antibacterial agents. RSC Advances, 2015, 5(89): 72872–72880 https://doi.org/10.1039/C5RA12575H
13	R Kumar, H Münstedt. Silver ion release from antimicrobial polyamide/silver composites. Biomaterials, 2005, 26(14): 2081–2088 https://doi.org/10.1016/j.biomaterials.2004.05.030
14	O Choi, Z Q Hu. Size dependent and reactive oxygen species related nanosilver toxicity to nitrifying bacteria. Environmental Science & Technology, 2008, 42(12): 4583–4588 https://doi.org/10.1021/es703238h
15	Z M Davoudi, A E Kandjani, A I Bhatt, I L Kyratzis, A P O’Mullane, V Bansal. Hybrid antibacterial fabrics with extremely high aspect ratio Ag/AgTCNQ nanowires. Advanced Functional Materials, 2014, 24(8): 1047–1053 https://doi.org/10.1002/adfm.201302368
16	X Cao, H Zhang, M Chen, L Wang. Preparation, characterization, and properties of modified barium sulfate nanoparticles/polyethylene nanocomposites as T-shaped copper intrauterine devices. Journal of Applied Polymer Science, 2014, 131(12): 40393–40399 https://doi.org/10.1002/app.40393
17	J Tang, Q Chen, L G Xu, S Zhang, L Z Feng, L Cheng, H Xu, Z Liu, R Peng. Graphene oxide-silver nanocomposite as a highly effective antibacterial agent with species-specific mechanisms. ACS Applied Materials & Interfaces, 2013, 5(9): 3867–3874 https://doi.org/10.1021/am4005495
18	J R He, J Su, J L Wang, L Z Zhang. Synthesis of water-free PEDOT with polyvinylpyrrolidone stabilizer in organic dispersant system. Organic Electronics, 2018, 53: 117–126 https://doi.org/10.1016/j.orgel.2017.11.035
19	B Yoon, S H Lee, L Feng. Dispersion and densification of nano Si-(Al)-C powder with amorphous/nano-crystalline bi-modal microstructure. Journal of the American Ceramic Society, 2018, 101(7): 2760–2769 https://doi.org/10.1111/jace.15455
20	R Horrocks, A Sitpalan, C Zhou, B K Kandola. Flame retardant polyamide fibres: The challenge of minimising flame retardant additive contents with added nanoclays. Polymers, 2016, 8(8): 288–304 https://doi.org/10.3390/polym8080288
21	A Buczko, T Stelzig, L Bommer, D Rentsch, M Heneczkowski, S Gaan. Bridged DOPO derivatives as flame retardants for PA6. Polymer Degradation & Stability, 2014, 107: 158–165 https://doi.org/10.1016/j.polymdegradstab.2014.05.017
22	Z B Guo, C L Wang, J Li, Q Yao. Micro-intumescent flame retardant polyamide 6 based on cyclic phosphate grafting phenol formaldehyde. Polymers for Advanced Technologies, 2016, 27(7): 955–963 https://doi.org/10.1002/pat.3755
23	G J Si, D X Li, Y L You, X Hu. Investigation of the influence of red phosphorus, expansible graphite and zinc borate on flame retardancy and wear performance of glass fiber reinforced PA6 composites. Polymer Composites, 2017, 38(10): 2090–2097 https://doi.org/10.1002/pc.23781
24	H Peng, W C Tjiu, L Shen, S Huang, C He, T Liu. Preparation and mechanical properties of exfoliated CoAl layered double hydroxide/polyamide 6 nanocomposites by in situ polymerization. Composites Science and Technology, 2009, 69(7-8): 991–996 https://doi.org/10.1016/j.compscitech.2009.01.005
25	M Casetta, G Michaux, B Ohl, S Duquesne, S Bourbigot. Key role of magnesium hydroxide surface treatment in the flame retardancy of glass fiber reinforced polyamide 6. Polymer Degradation & Stability, 2018, 148: 95–103 https://doi.org/10.1016/j.polymdegradstab.2018.01.007
26	J Alongi, G Malucelli. Cotton fabrics treated with novel oxidic phases acting as effective smoke suppressants. Carbohydrate Polymers, 2012, 90(1): 251–260 https://doi.org/10.1016/j.carbpol.2012.05.032
27	H J Kim, Y Kwon, C K Kim. Mechanical property and thermal stability of polyurethane composites reinforced with polyhedral oligomeric silsesquioxanes and inorganic flame retardant filler. Journal of Nanoscience and Nanotechnology, 2014, 14(8): 6048–6052 https://doi.org/10.1166/jnn.2014.8808
28	Y Ding, Y Jiang, F Xu, J Yin, H Ren, Q Zhuo, Z Long, P Zhang. Preparation of nano-structured LiFePO4/graphene composites by co-precipitation method. Electrochemistry Communications, 2010, 12(1): 10–13 https://doi.org/10.1016/j.elecom.2009.10.023
29	Z L Jiang, C S Wang, S Y Fang, P Ji, H P Wang, C C Ji. Durable flame-retardant and antidroplet finishing of polyester fabrics with flexible polysiloxane and phytic acid through layer-by-layer assembly and sol-gel process. Journal of Applied Polymer Science, 2018, 135(27): 46414–46424 https://doi.org/10.1002/app.46414
30	Y J Chang, X X Yan, Q Wang, L L Ren, J Tong, J Zhou. High efficiency and low cost preparation of size controlled starch nanoparticles through ultrasonic treatment and precipitation. Food Chemistry, 2017, 227: 369–375 https://doi.org/10.1016/j.foodchem.2017.01.111
31	H Daupor, S Wongnawa. Flower-like Ag/AgCl microcrystals: Synthesis and photocatalytic activity. Materials Chemistry and Physics, 2015, 159: 71–82 https://doi.org/10.1016/j.matchemphys.2015.03.054
32	J N Yang, C Wang, K Y Shao, G X Ding, Y L Tao, J B Zhu. Morphologies, mechanical properties and thermal stability of poly(lactic acid) toughened by precipitated barium sulfate. Russian Journal of Physical Chemistry A. Focus on Chemistry, 2015, 89(11): 2092–2096 https://doi.org/10.1134/S0036024415110242
33	M Shahzamani, I Rezaeian, M S Loghmani, P Zahedi, A Rezaeian. Effects of BaSO4, CaCO3, kaolin and quartz fillers on mechanical, chemical and morphological properties of cast polyurethane. Plastics. Rubber and Composites: Macromolecular Engineering, 2012, 41(6): 263–269 https://doi.org/10.1179/1743289811Y.0000000035
34	R Damerchely, A S Rashidi, R Khajavi. Morphology and mechanical properties of antibacterial nylon 6/nano-silver nano-composite multifilament yarns. Textile Research Journal, 2011, 81(16): 1694–1701 https://doi.org/10.1177/0040517511410104
35	M Venkatram, H N R Narasimha Murthy, A Gaikwad, S A Mankunipoyil, S Ramakrishna, P Ayalasomayajula Ratna. Antibacterial and flame retardant properties of Ag-MgO/nylon 6 electrospun nanofibers for protective applications. Clothing & Textiles Research Journal, 2018, 36(4): 296–309 https://doi.org/10.1177/0887302X18783071
36	K Kawahara, K Tsuruda, M Morishita, M Uchida. Antibacterial effect of silver-zeolite on oral bacteria under anaerobic conditions. Dental Materials, 2000, 16(6): 452–455 https://doi.org/10.1016/S0109-5641(00)00050-6
37	B Pant, H R Pant, D R Pandeya, G Panthi, K T Nam, S T Hong, C S Kim, H Y Kim. Characterization and antibacterial properties of Ag NPs loaded nylon-6 nanocomposite prepared by one-step electrospinning process. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 2012, 395: 94–99 https://doi.org/10.1016/j.colsurfa.2011.12.011
38	G X Fei, Y Liu, Q Wang. Synergistic effects of novolac-based char former with magnesium hydroxide in flame retardant polyamide-6. Polymer Degradation & Stability, 2008, 93(7): 1351–1356 https://doi.org/10.1016/j.polymdegradstab.2008.03.031

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