Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing and thermal properties of epoxy nanocomposites
1. School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China 2. School of Energy Resources and Safety, Anhui University of Science and Technology, Huainan 232001, China 3. School of Mechanical Engineering, Anhui University of Science and Technology, Huainan 232001, China
Poor interfacial adhesion and dispersity severely obstruct the continued development of carbon nanotube (CNT)-reinforced epoxy (EP) for potential applications. Herein, hierarchical CNT nanohybrids using nickel phyllosilicate (Ni-PS) as surface decorations (CNT@Ni-PS) were synthesized, and the nanocomposites derived from varied mass fractions of EP and CNT@Ni-PS were prepared. The morphological structures, tribological performances, curing behaviors and thermal properties of EP/CNT@Ni-PS nanocomposites were carefully investigated. Results show that hierarchical CNT nanohybrids with homogeneous dispersion and well-bonded interfacial adhesion in the matrix are successfully obtained, presenting significantly improved thermal and tribological properties. Moreover, analysis on cure kinetics proves the excellent promotion of CNT@Ni-PS on the non-isothermal curing process, lowering the curing energy barrier steadily.
. [J]. Frontiers of Chemical Science and Engineering, 2021, 15(5): 1281-1295.
Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li. Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing and thermal properties of epoxy nanocomposites. Front. Chem. Sci. Eng., 2021, 15(5): 1281-1295.
S Liu, V S Chevali, Z Xu, D Hui, H Wang. A review of extending performance of epoxy resins using carbon nanomaterials. Composites. Part B, Engineering, 2018, 136: 197–214
2
H Wang, L Sun, R Wang, L Yan, Y Zhu, C Wang, E Wang. Dopamine modification of multiwalled carbon nanotubes and its influences on the thermal, mechanical, and tribological properties of epoxy resin composites. Polymer Composites, 2017, 38(1): 116–125
3
L H Esposito, J A Ramos, G Kortaberria. Dispersion of carbon nanotubes in nanostructured epoxy systems for coating application. Progress in Organic Coatings, 2014, 77(9): 1452–1458
4
A Li, W Li, Y Ling, W Gan, M A Brady, C Wang. Effects of silica-coated carbon nanotubes on the curing behavior and properties of epoxy composites. RSC Advances, 2016, 6(28): 23318–23326
5
M R Zakaria, H M Akil, M H A Kudus, M B H Othman. Compressive properties and thermal stability of hybrid carbon nanotube-alumina filled epoxy nanocomposites. Composites. Part B, Engineering, 2016, 91: 235–242
6
X Li, B Chen, Y Jia, X Li, J Yang, C Li, F Yan. Enhanced tribological properties of epoxy-based lubricating coatings using carbon nanotubes-ZnS hybrid. Surface and Coatings Technology, 2018, 344: 154–162
7
K Zhou, J Liu, Y Shi, S Jiang, D Wang, Y Hu, Z Gui. MoS2 nanolayers grown on carbon nanotubes: an advanced reinforcement for epoxy composites. ACS Applied Materials & Interfaces, 2015, 7(11): 6070–6081
8
Y Hou, W Hu, L Liu, Z Gui, Y Hu. In-situ synthesized CNTs/Bi2Se3 nanocomposites by a facile wet chemical method and its application for enhancing fire safety of epoxy resin. Composites Science and Technology, 2018, 157: 185–194
9
Z Bian, S Kawi. Preparation, characterization and catalytic application of phyllosilicate: a review. Catalysis Today, 2020, 339: 3–23
10
S Nie, D Jin, Y Xu, C Han, X Dong, J Yang. Effect of a flower-like nickel phyllosilicate-containing iron on the thermal stability and flame retardancy of epoxy resin. Journal of Materials Research and Technology, 2020, 9(5): 10189–10197
11
J Yang, Y Liu, Y Xu, S Nie, Z Li. Property investigations of epoxy composites filled by nickel phyllosilicate-decorated graphene oxide. Journal of Materials Science, 2020, 55(24): 10593–10610
12
J Qu, W Li, C Y Cao, X J Yin, L Zhao, J Bai, Z Qin, W G Song. Metal silicate nanotubes with nanostructured walls as superb adsorbents for uranyl ions and lead ions in water. Journal of Materials Chemistry, 2012, 22(33): 17222–17226
13
G Grassi, A Scala, A Piperno, D Iannazzo, M Lanza, C Milone, A Pistone, S Galvagno. A facile and ecofriendly functionalization of multiwalled carbon nanotubes by an old mesoionic compound. Chemical Communications, 2012, 48(54): 6836–6838
14
P Burattin, M Che, C Louis. Characterization of the Ni(II) phase formed on silica upon deposition-precipitation. Journal of Physical Chemistry B, 1997, 101(36): 7060–7074
15
X Zhang, D Zhao, D Luan, C Bi. Fabrication and mechanical properties of multiwalled carbon nanotube/nanonickel reinforced epoxy resin composites. Applied Physics. A, Materials Science & Processing, 2016, 122(12): 1056
16
H B Li, M H Yu, F X Wang, P Liu, Y Liang, J Xiao, C X Wang, Y X Tong, G W Yang. Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials. Nature Communications, 2013, 4: 1894
17
M Kermarec, J Carriat, P Burattin, M Che, A Decarreau. FTIR identification of the supported phases produced in the preparation of silica-supported nickel catalysts. Journal of Physical Chemistry, 1994, 98(46): 12008–12017
18
Y Wu, G Chang, Y Zhao, Y Zhang. Preparation of hollow nickel silicate nanospheres for separation of His-tagged proteins. Dalton Transactions (Cambridge, England), 2014, 43(2): 779–783
19
M G Da Fonseca, C R Silva, J S Barone, C Airoldi. Layered hybrid nickel phyllosilicates and reactivity of the gallery space. Journal of Materials Chemistry, 2000, 10(3): 789–795
20
C Gui, S Hao, Y Liu, J Qu, C Yang, Y Yu, Q Wang, Z Yu. Carbon nanotube@layered nickel silicate coaxial nanocables as excellent anode materials for lithium and sodium storage. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2015, 3(32): 16551–16559
21
K Chabrol, M Gressier, N Pebere, M J Menu, F Martin, J P Bonino, C Marichal, J Brendle. Functionalization of synthetic talc-like phyllosilicates by alkoxyorganosilane grafting. Journal of Materials Chemistry, 2010, 20(43): 9695–9706
22
K Kim, Y Kim, J Nam, S H Baeck, D W Park, S E Shim. Mechanical properties of silica-coated multi-walled carbon nanotube/epoxy composites. Polymer (Korea), 2016, 40(1): 117–123
23
J Liu, R K K Yuen, N Hong, Y Hu. The influence of mesoporous SiO2-graphene hybrid improved the flame retardancy of epoxy resins. Polymers for Advanced Technologies, 2018, 29(5): 1478–1486
24
X Chen, L Wang, J Shi, H Shi, Y Liu. Effect of barium sulfate nanoparticles on mechanical properties and crystallization behaviour of HDPE. Polymers & Polymer Composites, 2010, 18(3): 145–152
25
R Baptista, A Mendao, F Rodrigues, C G Figueiredo-Pina, M Guedes, R Marat-Mendes. Effect of high graphite filler contents on the mechanical and tribological failure behavior of epoxy matrix composites. Theoretical and Applied Fracture Mechanics, 2016, 85: 113–124
26
H Yi, C Chen, F Zhong, Z Xu. Preparation of aluminum oxide-coated carbon nanotubes and the properties of composite epoxy coatings research. High Performance Polymers, 2014, 26(3): 255–264
27
J Yuan, Z Zhang, M Yang, F Guo, X Men, W Liu. Surface modification of hybrid-fabric composites with amino silane and polydopamine for enhanced mechanical and tribological behaviors. Tribology International, 2017, 107: 10–17
28
Q H Wang, X R Zhang, X Q Pei. Study on the friction and wear behavior of basalt fabric composites filled with graphite and nano-SiO2. Materials & Design, 2010, 31(3): 1403–1409
29
Z Pawlak, T Kaldonski, R Pai, E Bayraktare, A Oloyede. A comparative study on the tribological behaviour of hexagonal boron nitride (H-BN) as lubricating micro-particles—an additive in porous sliding bearings for a car clutch. Wear, 2009, 267(5): 1198–1202
30
J Yu, W Zhao, Y Wu, D Wang, R Feng. Tribological properties of epoxy composite coatings reinforced with functionalized C-BN and H-BN nanofillers. Applied Surface Science, 2018, 434: 1311–1320
31
Z Zhao, J Ji. Synthesis and tribological behaviors of epoxy/phosphazene-microspheres coatings under dry sliding condition. Advanced Engineering Materials, 2014, 16(8): 988–995
32
J H Choi, H J Song, J Jung, J W Yu, N You, M Goh. Effect of crosslink density on thermal conductivity of epoxy/carbon nanotube nanocomposites. Journal of Applied Polymer Science, 2017, 134(4): 44253
33
A Dasari, Z Z Yu, Y W Mai. Fundamental aspects and recent progress on wear/scratch damage in polymer nanocomposites. Materials Science and Engineering R Reports, 2009, 63(2): 31–80
34
T Zhou, X Wang, X Liu, D Xiong. Influence of multi-walled carbon nanotubes on the cure behavior of epoxy-imidazole system. Carbon, 2009, 47(4): 1112–1118
35
A K Singh, B P Panda, S Mohanty, S K Nayak, M K Gupta. Study on metal decorated oxidized multiwalled carbon nanotube (MWCNT)-epoxy adhesive for thermal conductivity applications. Journal of Materials Science Materials in Electronics, 2017, 28(12): 8908–8920
36
Y F Liu, M Zhao, S G Shen, J G Gao. Curing kinetics of tetrabromo-bisphenol—A epoxy resin with diaminodiphenyl methane. Acta Physico-Chimica Sinica, 1998, 14(10): 927–931
37
J K Gillham. Formation and properties of thermosetting and high Tg polymeric materials. Polymer Engineering and Science, 1986, 26(20): 1429–1433
38
E Yarahmadi, K Didehban, M G Sari, M R Saeb, M Shabanian, F Aryanasab, P Zarrintaj, S M R Paran, M Mozafari, M Rallini, et al. Development and curing potential of epoxy/starch-functionalized graphene oxide nanocomposite coatings. Progress in Organic Coatings, 2018, 119: 194–202
39
H E Kissinger. Reaction kinetics in differential thermal analysis. Analytical Chemistry, 1957, 29(11): 1702–1706
40
S Vyazovkin, A Mititelu, N Sbirrazzuoli. Kinetics of epoxy-amine curing accompanied by the formation of liquid crystalline structure. Macromolecular Rapid Communications, 2003, 24(18): 1060–1065
41
R Jain, V Choudhary, A Narula. Studies on the curing kinetics of epoxy resins using mixture of nadic/or maleic anhydride and 4, 4′-diaminodiphenyl sulfone. Journal of Thermal Analysis and Calorimetry, 2007, 90(2): 495–501
42
J Wan, B Gan, C Li, J Molina-Aldareguia, Z Li, X Wang, D Y Wang. A novel biobased epoxy resin with high mechanical stiffness and low flammability: synthesis, characterization and properties. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2015, 3(43): 21907–21921
43
H L Friedman. Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic. Journal of Polymer Science Part C: Polymer Symposia, 1964, 6(1): 183–195
44
M Starink. The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods. Thermochimica Acta, 2003, 404(1-2): 163–176
45
J Zhang, H Dong, L Tong, L Meng, Y Chen, G Yue. Investigation of curing kinetics of sodium carboxymethyl cellulose/epoxy resin system by differential scanning calorimetry. Thermochimica Acta, 2012, 549: 63–68
46
L Lu, L Xia, H Zengheng, S Xingyue, Z Yi, L Pan. Investigation on cure kinetics of epoxy resin containing carbon nanotubes modified with hyper-branched polyester. RSC Advances, 2018, 8(52): 29830–29839
47
W Xu, X Wang, Y Liu, W Li, R Chen. Improving fire safety of epoxy filled with graphene hybrid incorporated with zeolitic imidazolate framework/layered double hydroxide. Polymer Degradation & Stability, 2018, 154: 27–36
48
Y Che, Z Sun, R Zhan, S Wang, S Zhou, J Huang. Effects of graphene oxide sheets-zirconia spheres nanohybrids on mechanical, thermal and tribological performances of epoxy composites. Ceramics International, 2018, 44(15): 18067–18077
49
H Kim, A A Abdala, C W Macosko. Graphene/polymer nanocomposites. Macromolecules, 2010, 43(16): 6515–6530
