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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2021, Vol. 15 Issue (5): 1050-1074   https://doi.org/10.1007/s11705-020-2025-7
  本期目录
Dehydration of natural gas and biogas streams using solid desiccants: a review
Soheil Bahraminia, Mansoor Anbia(), Esmat Koohsaryan
Research Laboratory of Nanoporous Materials, Faculty of Chemistry, Iran University of Science and Technology, 16846-13114 Tehran, Iran
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Abstract

Natural gas and biogas are two mixtures that consist of methane as their main component. These two gas mixtures are usually saturated with water vapor, which cause many problems, such as damaging the gas processing equipment by increasing the gas’s corrosion potential or clogging the pipelines due to gas hydrate formation. Thus, removing water vapor from these gas streams is mandatory. In this review paper, the main dehydration methods have been overviewed, and scrutiny of the adsorption dehydration has been carried out. Furthermore, the most important solid desiccants and their improvements have been reviewed.

Key wordsnatural gas    biogas    dehydration    adsorption    solid desiccant
收稿日期: 2020-07-09      出版日期: 2021-08-30
Corresponding Author(s): Mansoor Anbia   
 引用本文:   
. [J]. Frontiers of Chemical Science and Engineering, 2021, 15(5): 1050-1074.
Soheil Bahraminia, Mansoor Anbia, Esmat Koohsaryan. Dehydration of natural gas and biogas streams using solid desiccants: a review. Front. Chem. Sci. Eng., 2021, 15(5): 1050-1074.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-020-2025-7
https://academic.hep.com.cn/fcse/CN/Y2021/V15/I5/1050
Fig.1  
Constituents Composition/vol-%
Wet Dry
Hydrocarbons
CH4 84.6 96.00
C2H6 6.4 2.00
C3H8 5.3 0.60
Isobutene 1.2 0.18
n-Butene 1.4 0.12
Isopentane 0.4 0.14
n-Pentane 0.2 0.06
Hexanes 0.4 0.10
Heptane 0.1 0.80
Non-hydrocarbons
CO2 ≤5
He ≤0.5
H2S ≤5
N2 ≤10
Ar ≤0.05
Rn, Kr, Xe Traces
Tab.1  
Component CO2/vol-% H2S/vol-% NH3/vol-% H2O/vol-% Dust/mm N2/vol-% Siloxanes
/(mg·m–3)
Content 25–50 0–0.5 0–0.5 1–5 ? 5 0–5 0–50
Tab.2  
Application Components
H2S CO2 H2O Traces
Gas heater (boiler) ? 1394 mg·m−3 No No Yes (e.g., siloxanes)
CHP ? 1394 mg·m−3 No Avoid condensation Yes (e.g., siloxanes)
Vehicle fuel Yes Yes Yes Yes
Gas grid Yes Yes Yes Yes
Tab.3  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
Fig.9  
Fig.10  
Fig.11  
Phase Steps Time/h
Adsorption 12
Regeneration 12
Heating Gradual heating (0.5 h)
Ramp up heating (0.5 h)
Heating (4.5 h heating+ 0.5 h spare heating)
Cooling Cooling (2 h)
Stand by Hot stand (1 h)
Cooling stand by (3 h)
Tab.4  
Fig.12  
Fig.13  
Fig.14  
Adsorbent a) Adsorption capacity/(g·g–1) Refs.
SG 127 B 0.11 [63]
SG (Solvay) 0.18 [64]
Silica aerogel 1.35 [65]
SG type A 0.40 [66]
SG type RD 0.45 [66]
SG/CaCl2 0.80 [67]
SG/CaCl2 0.60 [68]
SG type C 0.09 [53,69]
SG/Li10 0.47 [53,69]
SG/Li20 0.72 [53,69]
SG/Li30 0.90 [53,69]
SG/Li40 1.20 [53,69]
SG wheel 0.23 [70]
SG/LiCl 0.67 [53,70]
SG/Ca (NO3)2 0.21 [53,57]
SG/LiNO3 0.22 [53,71]
SG-Meso-A/50 CaCl2 0.42 [59]
Mesoporous SG 0.06 [53,72]
SG/LiBr-17% 0.22 [53,72]
SG/MgCl2-17% 0.20 [53,72]
SG/CaCl2-17% 0.33 [53,72]
SG/CaCl2-26% 0.31 [53,72]
SG/CaCl2-33% 0.28 [53,72]
SG/Na2SO4 0.85 [53,62]
SG/CaCl2-33.7% 0.42 [73]
SG type A 0.25 [74]
Mesoporous SG 0.35 [53,75]
SG-Meso-B/50 CaCl2 0.47 [75]
SG/Meso/50 CaCl2 0.28 [75]
SG/MgSO4 0.40 [60]
SG/LiBr 0.93 [76]
SG/CaCl2 1.2 [61]
SG/CaCl2 1.1 [61]
SG/Na2SO4 0.85 [77]
Tab.5  
Fig.15  
Fig.16  
Fig.17  
Fig.18  
Fig.19  
Adsorbent Adsorption capacity
/(g·g–1)
Ref. Adsorbent Adsorption capacity/(g·g–1) Ref.
CaNaA 0.16 [110] NaA 0.29 [111]
MgA 0.42 [111] NaA 0.09 [63]
LiA 0.10 [63] 3A 0.21 [53]
3A 0.25 [91] 4A 0.25 [91]
5A 0.25 [91] LTASS 0.26 [91]
3A 0.24 [89] 3A 0.08 [112]
5A 0.25 [113] 13X 0.26 [114]
13X 0.34 [89] 13X 0.18 [90]
13X 0.26 [113] 13X 0.23 [115]
NaX 0.33 [116] KX 0.26 [116]
RbX 0.20 [116] CsX (5) 0.27 [116]
CsX (30) 0.22 [116] CsX (45) 0.19 [116]
NaX 0.34 [111] MgX 0.45 [111]
LiNaX 0.38 [117] 13X 0.33 [118]
13X 0.20 [74] NaX 0.32 [91]
Sr-ex 13X 0.25 [90] Zn-ex 13X 0.25 [90]
Cd-ex 13X 0.21 [90] Zeolite X/activated carbon composite 0.21 [114]
Alumina/zeolite 13X composite 0.38 [119] Dealuminated Y 0.22 [89]
CaY 0.34 [110] HY 0.20 [110]
KY 0.29 [110] LiY 0.36 [110]
RbY 0.34 [110] NaY 0.34 [111]
MgY 0.42 [111] PbY 0.15 [63]
NiY 0.15 [63] NaY 0.15 [63]
NaY 0.33 [91] LiY 0.19 [63]
LaNaY 0.19 [63] KP 0.12 [110]
NaP 0.24 [110] CaP 0.22 [110]
P1 0.34 [91] P2 0.42 [91]
P3 0.43 [91] P4 0.97 [91]
P5 0.64 [91] P6 1.30 [91]
P7 1.39 [91] A1-6.7 0.55 [75]
A2-7.7 0.53 [75] A3-8.7 0.46 [75]
Clinoptilolite 0.05 [90] Sr-ex clinoptilolite 0.10 [90]
Zn-ex clinoptilolite 0.11 [90] Cd-ex clinoptilolite 0.10 [90]
Tab.6  
Fig.20  
Fig.21  
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