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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2022, Vol. 16 Issue (5): 661-680   https://doi.org/10.1007/s11705-021-2084-4
  本期目录
A review on the forward osmosis applications and fouling control strategies for wastewater treatment
Linwei Zhu1, Chun Ding1, Tengyang Zhu1, Yan Wang1,2()
1. Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Wuhan 430074, China
2. Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
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Abstract

During the last decades, the utilization of osmotic pressure-driven forward osmosis technology for wastewater treatment has drawn great interest, due to its high separation efficiency, low membrane fouling propensity, high water recovery and relatively low energy consumption. This review paper summarizes the implementation of forward osmosis technology for various wastewater treatment including municipal sewage, landfill leachate, oil/gas exploitation wastewater, textile wastewater, mine wastewater, and radioactive wastewater. However, membrane fouling is still a critical issue, which affects water flux stability, membrane life and operating cost. Different membrane fouling types and corresponding fouling mechanisms, including organic fouling, inorganic fouling, biofouling and combined fouling are therefore further discussed. The fouling control strategies including feed pre-treatment, operation condition optimization, membrane selection and modification, membrane cleaning and tailoring the chemistry of draw solution are also reviewed comprehensively. At the end of paper, some recommendations are proposed.

Key wordsforward osmosis    wastewater treatment    membrane fouling    fouling control
收稿日期: 2021-04-14      出版日期: 2022-03-28
Corresponding Author(s): Yan Wang   
 引用本文:   
. [J]. Frontiers of Chemical Science and Engineering, 2022, 16(5): 661-680.
Linwei Zhu, Chun Ding, Tengyang Zhu, Yan Wang. A review on the forward osmosis applications and fouling control strategies for wastewater treatment. Front. Chem. Sci. Eng., 2022, 16(5): 661-680.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-021-2084-4
https://academic.hep.com.cn/fcse/CN/Y2022/V16/I5/661
Fig.1  
Fig.2  
Membrane Type Manufacturer
CTA, PA-TFC Flat sheet HTI, presently fluid technology
solutions, USA [33,34]
CTA Hollow fiber Toyobo, Japan [37]
PA-TFC Flat sheet Oasys Water, USA [38,39]
PA-TFC Flat sheet Porifera, USA [40]
Aquaporin TFC Flat sheet, hollow fiber Aquaporin A/S, Denmark [41]
Tab.1  
Type Draw solute Recovery method
Sugar Glucose [57], fructose [58], sucrose [59] Direct use for drinking with no recovery
Volatile gas NH3-CO2 [60,61] Heating, air stripping
Inorganic salt NaCl, MgCl2, Na2SO4, MgSO4, CaCl2 [62] NF, RO
Fertilizer (NH4)2HPO4, KNO3, NH4HCO3, NH4H2PO4, (NH4)2SO4 [63,64] Direct use for fertilization with no recovery
Polyelectrolyte Sodium polyacrylate [65], poly(4-styrenesulfonic acid-co-maleic acid) sodium salt [66], poly(amidoamine) [67] UF, membrane distillation (MD)
Small organic acid salt Ethylenediaminetetraacetic acid disodium (EDTA-2Na) [68], sodium tetraethylenepentamine heptaacetate [69], tetraethylenepentamine heptakis-(methylphosphonic) sodium salt [12], triethylenetetramine hexapropionic acid sodium [70], phytic acid salt [71] NF, RO
Responsive draw agent Functional magnetic nanoparticle [72,73], thermo/electric-responsive hydrogel [74,75], pH/thermo-responsive polyelectrolyte [76,77] Magnetic/pH/thermo/electric stimulation
Hydroacid complexes Citric acid-Fe complex [78], oxalic acid-Cr-tetramethylammonium salt [30], oxalic acid-Cr complex [79] NF, MD
Tab.2  
Case System Feed solution Draw solution FO membrane Pre-treatment Initial water flux/(L?·m−2?h−1) Final water flux/(L??·m−2?h−1) Operation time Membrane cleaning Ref.
A FO-
AnMBR
Simulating municipal wastewater 0.5 mol·L–1 NaCl (constant) HTI-CTA No 9.5 3.5 22 d per cycle, 4 cycles No [113]
B FO-MBR Synthetic domestic wastewater 0.5 mol·L–1 NaCl (constant) HTI-CTA No 5 3 14 d per cycle, 3 cycles Osmotic backwashing [85]
C MF-FOMBR Raw municipal wastewater 29 g·L–1 NaCl (constant) HTI-CTA, No 98 d No [114]
D FO-MD Landfill leachate 4.82 mol·L–1 NaCl HTI-TFC No 6.29 250 min No [91]
E FO-Fenton’s oxidation Landfill leachate 5 mol·L–1 NaCl Aquaporin-TFC No 5.23 2.46 10 h No [19]
F Calcium pretreatment-FO Landfill leachate 5 mol·L–1 NaCl HTI-CTA No 2.9 0.1 60 h No [115]
G FO Drilling waste 260 g·L–1 NaCl HTI-CTA No 14 2 6 h Osmotic backwashing [16]
H FO Produced water 70 g·L–1 NaCl TFC
(constant)
Organosilica adsorbent, MF, activated carbon 13.5 12.4 1.8 h No [116]
I FO-RO Produced water 1 mol·L–1 NaCl HTI-CTA 3.1 1.0 28 d Chemical cleaning [20]
J MF-FO-MD Fracking wastewater 4 mol·L–1 NaCl,
4.6 mol·L–1 NaP
Nanocomposite TFC,
HTI-TFC
MF 18.6 (NaCl), 22 (NaP); 13.4 (NaCl),
22.2 (NaP)
8.4 (NaCl),
13.6 (NaP); 4.1 (NaCl),
9.5 (NaP)
6 h Physical cleaning [21]
K FO Real textile wastewater 1 mol·L–1 NaCl, 2 mol·L–1
MgCl2, blue dye mixture, and green dye mixture
Aquaporin-TFC No 13 (2 mol·L–1 MgCl2) 9 20 h Chemical cleaning [104]
L FO-coagulation/flocculation Synthetic textile wastewater 2 mol·L–1 NaCl Laboratory-made TFC No 36 11 167 h Physically flushing [105]
M FO Acid mine drainage NH4HCO3 Porifera-TFC No [107]
N FO-NF Coalmine water 0.5 mol·L–1 (NH4)2SO4 HTI-CTA No 8 1 180 h per cycle, 6 cycles Physically flushing [108]
O FO-RO/NF Mine brackish groundwater 1 mol·L–1 Na2SO4 Toray-TFC No 7.02 [109]
P FO Radioactive wastewater (Cs(I)) 0.5–2 mol·L–1 NaCl CTA-NW, CTA-ES, TFC-ES (HTI) No CTA-NW (5.4–9.8), CTA-ES (9.7–19.3), TFC-ES (7.7–22.0) 3 h No [111]
Tab.3  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
Fig.9  
Fig.10  
Fig.11  
Fig.12  
Fig.13  
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