Ultrasound-assisted co-precipitation synthesis of mesoporous Co3O4–CeO2 composite oxides for highly selective catalytic oxidation of cyclohexane

doi:10.1007/s11705-022-2145-3

Frontiers of Chemical Science and Engineering

2022, Vol. 16

Issue (8): 1211-1223 https://doi.org/10.1007/s11705-022-2145-3

本期目录

Ultrasound-assisted co-precipitation synthesis of mesoporous Co₃O₄–CeO₂ composite oxides for highly selective catalytic oxidation of cyclohexane

Shangjun Fu¹, Kuiyi You^1,²(

), Zhenpan Chen¹(

), Taobo Liu¹, Qiong Wang¹, Fangfang Zhao¹, Qiuhong Ai^1,², Pingle Liu^1,², He’an Luo^1,²

¹. School of Chemical Engineering, Xiangtan University, Xiangtan 411105, China
². National & Local United Engineering Research Center for Chemical Process Simulation and Intensification, Xiangtan University, Xiangtan 411105, China

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Abstract：

The one-step highly selective oxidation of cyclohexane into cyclohexanone and cyclohexanol as the essential intermediates of nylon-6 and nylon-66 is considerably challenging. Therefore, an efficient and low-cost catalyst must be urgently developed to improve the efficiency of this process. In this study, a Co₃O₄–CeO₂ composite oxide catalyst was successfully prepared through ultrasound-assisted co-precipitation. This catalyst exhibited a higher selectivity to KA-oil, which was benefited from the synergistic effects between Co³⁺/Co²⁺ and Ce⁴⁺/Ce³⁺ redox pairs, than bulk CeO₂ and/or Co₃O₄. Under the optimum reaction conditions, 89.6% selectivity to KA-oil with a cyclohexane conversion of 5.8% was achieved over Co₃O₄–CeO₂. Its catalytic performance remained unchanged after five runs. Using the synergistic effects between the redox pairs of different transition metals, this study provides a feasible strategy to design high-performance catalysts for the selective oxidation of alkanes.

Key words： Co₃O₄–CeO₂ composite oxides cyclohexanone cyclohexanol ultrasonic-assisted co-precipitation selective oxidation solvent-free

收稿日期: 2021-08-13 出版日期: 2022-08-02

Corresponding Author(s): Kuiyi You,Zhenpan Chen

引用本文:

. [J]. Frontiers of Chemical Science and Engineering, 2022, 16(8): 1211-1223.
Shangjun Fu, Kuiyi You, Zhenpan Chen, Taobo Liu, Qiong Wang, Fangfang Zhao, Qiuhong Ai, Pingle Liu, He’an Luo. Ultrasound-assisted co-precipitation synthesis of mesoporous Co₃O₄–CeO₂ composite oxides for highly selective catalytic oxidation of cyclohexane. Front. Chem. Sci. Eng., 2022, 16(8): 1211-1223.

链接本文:

https://academic.hep.com.cn/fcse/CN/10.1007/s11705-022-2145-3
https://academic.hep.com.cn/fcse/CN/Y2022/V16/I8/1211

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