1. School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi 832003, China 2. Institute of Materials, National Autonomous University of Mexico, Mexico City 04510, Mexico 3. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
Novel CaCO3-enhanced Mn–Fe mixed metal oxides (CMFC) were successfully prepared for the first time by a simple-green hydrothermal strategy without any surfactant or template combined with calcination process. These oxides were then employed as an adsorbent for adsorptive removal of excess fluoride ions. The adsorbent was characterized by SEM, XPS, XRD, FTIR, and BET analysis techniques. The adsorption property of CMFC toward fluoride ion was analyzed by batch experiments. In fact, CMFC exhibited adsorption capacity of 227.3 mg∙g‒1 toward fluoride ion. Results showed that ion exchange, electrostatic attraction and chemical adsorption were the main mechanism for the adhesion of large amount of fluoride ion on the CMFC surface, and the high adsorption capacity responded to the low pH of the adsorption system. When the fluoride ion concentration was increased from 20 to 200 mg∙L‒1, Langmuir model was more in line with experimental results. The change of fluoride ion adsorption with respect to time was accurately described by pseudo-second-order kinetics. After five cycles of use, the adsorbent still maintains a performance of 70.6% of efficiency, compared to the fresh adsorbent. Therefore, this material may act as a potential candidate for adsorbent with broad range of application prospects.
Z Yu, C Xu, K Yuan, X Gan, C Feng, X Wang, L Zhu, G Zhang, D Xu. Characterization and adsorption mechanism of ZrO2 mesoporous fibers for health-hazardous fluoride removal. Journal of Hazardous Materials, 2018, 346 : 82– 92 https://doi.org/10.1016/j.jhazmat.2017.12.024
2
S I Alhassan, L Huang, Y He, L Yan, B Wu, H Wang. Fluoride removal from water using alumina and aluminum-based composites: a comprehensive review of progress. Critical Reviews in Environmental Science and Technology, 2021, 51( 18): 1– 35
3
J J Zhang, L Yu, H B Yang, B C Ye. Migration and transformation of fluoride through fluoride-containing water for the irrigation of a soil-plant system. Human and Ecological Risk Assessment, 2019, 25( 4): 1048– 1058 https://doi.org/10.1080/10807039.2018.1460577
4
W Liu, X Huang, K Peng, Y Xiong, J Zhang, L Lu, J Liu, S Li. PDA-PEI copolymerized highly hydrophobic sponge for oil-in-water emulsion separation via oil adsorption and water filtration. Surface and Coatings Technology, 2021, 406 : 126743 https://doi.org/10.1016/j.surfcoat.2020.126743
5
X Borgohain, A Boruah, G K Sarma, M H Rashid. Rapid and extremely high adsorption performance of porous MgO nanostructures for fluoride removal from water. Journal of Molecular Liquids, 2020, 305 : 112799 https://doi.org/10.1016/j.molliq.2020.112799
6
H P Karki, L Kafle, D P Ojha, J H Song, H J Kim. Cellulose/polyacrylonitrile electrospun composite fiber for effective separation of the surfactant-free oil-in-water mixture under a versatile condition. Separation and Purification Technology, 2019, 210 : 913– 919 https://doi.org/10.1016/j.seppur.2018.08.053
7
M Contreras, M I Martin, M J Gazquez, M Romero, J P Bolivar. Valorisation of ilmenite mud waste in the manufacture of commercial ceramic. Construction & Building Materials, 2014, 72 : 31– 40 https://doi.org/10.1016/j.conbuildmat.2014.08.091
8
Y S Solanki, M Agrawal, S Gupta, P Shukla, M O Midda. Application of synthesized Fe/Al/Ca based adsorbent for defluoridation of drinking water and its significant parameters optimization using response surface methodology. Journal of Environmental Chemical Engineering, 2019, 7( 6): 103465 https://doi.org/10.1016/j.jece.2019.103465
9
K Abeykoon, S P Dunuweera, D N D Liyanage, R M G Rajapakse. Removal of fluoride from aqueous solution by porous vaterite calcium carbonate nanoparticles. Materials Research Express, 2020, 7( 3): 035009 https://doi.org/10.1088/2053-1591/ab7692
10
H Eslami, A Esmaeili, M H Ehrampoush, A A Ebrahimi, M Taghavi, R Khosravi. Simultaneous presence of poly titanium chloride and Fe2O3–Mn2O3 nanocomposite in the enhanced coagulation for high rate As(V) removal from contaminated water. Journal of Water Process Engineering, 2020, 36 : 101342 https://doi.org/10.1016/j.jwpe.2020.101342
11
J Liu, G Wan, Z Pang, Z Tang. Hollow metal–organic-framework micro/nanostructures and their derivatives: emerging multifunctional materials. Advanced Materials, 2018, 31( 38): e1803291 https://doi.org/10.1002/adma.201803291
12
S P Adhikari, G P Awasthi, K S Kim, H P Chan, C S Kim. Synthesis of three-dimensional mesoporous Cu–Al layered double hydroxide/g-C3N4 nanocomposites on Ni-foam for enhanced supercapacitors with excellent long-term cycling stability. Dalton Transactions, 2018, 47( 13): 47 https://doi.org/10.1039/C7DT04192F
13
H T Wang, C Jin, Y N Liu, X H Kang, S W Bian, Q Zhu. Cotton yarns modified with three-dimensional metallic Ni conductive network and pseudocapacitive Co–Ni layered double hydroxide nanosheet array as electrode materials for flexible yarn supercapacitors. Electrochimica Acta, 2018, 283 : 1789– 1797 https://doi.org/10.1016/j.electacta.2018.07.090
14
C Liu, F Xie. Highly efficient removal of As(III) by Fe–Mn–Ca composites with the synergistic effect of oxidation and adsorption. Science of the Total Environment, 2021, 777 : 145289 https://doi.org/10.1016/j.scitotenv.2021.145289
15
M B Baskan, A R Biyikli. The adsorption of fluoride from aqueous solutions by Fe, Mn, and Fe/Mn modified natural clinoptilolite and optimization using response surface methodology. Water Environment Research, 2021, 93( 4): 620– 635
16
D Xie, Y Gu, H Wang, Y Wang, W Qin, G Wang, H Zhang, Y Zhang. Enhanced fluoride removal by hierarchically porous carbon foam monolith with high loading of UiO-66. Journal of Colloid and Interface Science, 2019, 542 : 269– 280 https://doi.org/10.1016/j.jcis.2019.02.027
17
J Singh, N S Mishra, S Banerjee, Y C Sharma. Comparative studies of physical characteristics of raw and modified sawdust for their use as adsorbents for removal of acid dye. BioResources, 2011, 6( 3): 2732– 2743
18
B Qin, M Lin, Z Yao, J Zhu, J Ruan, Y Tang, R Qiu. A novel approach of accurately rationing adsorbent for capturing pollutants via chemistry calculation: rationing the mass of CaCO3 to capture Br-containing substances in the pyrolysis of nonmetallic particles of waste printed circuit boards. Journal of Hazardous Materials, 2020, 393 : 122410 https://doi.org/10.1016/j.jhazmat.2020.122410
19
G Avgouropoulos, T Ioannides. Effect of synthesis parameters on catalytic properties of CuO–CeO2. Applied Catalysis B: Environmental, 2006, 67( 1–2): 1– 11 https://doi.org/10.1016/j.apcatb.2006.04.005
20
K S W Sing, R T Williams. Physisorption hysteresis loops and the characterization of nanoporous materials. Adsorption Science and Technology, 2004, 22( 10): 773– 782 https://doi.org/10.1260/0263617053499032
21
M Thommes, K Kaneko, A V Neimark, J P Olivier, F Rodriguez-Reinoso, J Rouquerol, K S W Sing. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 2015, 87( 9–10): 1051– 1069 https://doi.org/10.1515/pac-2014-1117
22
L Kong, H Adidharma. A new adsorption model based on generalized van der Waals partition function for the description of all types of adsorption isotherms. Chemical Engineering Journal, 2019, 375 : 122112 https://doi.org/10.1016/j.cej.2019.122112
23
L Zhu, H Li, P Xia, Z Liu, D Xiong. Hierarchical ZnO decorated with CeO2 nanoparticles as the direct Z-scheme heterojunction for enhanced photocatalytic activity. ACS Applied Materials & Interfaces, 2018, 10( 46): 39679– 39687 https://doi.org/10.1021/acsami.8b13782
24
H K Agbovi, L D Wilson. Design of amphoteric chitosan flocculants for phosphate and turbidity removal in wastewater. Carbohydrate Polymers, 2018, 189 : 360– 370 https://doi.org/10.1016/j.carbpol.2018.02.024
25
J Kang, T G Levitskaia, S Park, J Kim, T Varga, W Um. Nanostructured MgFe and CoCr layered double hydroxides for removal and sequestration of iodine anions. Chemical Engineering Journal, 2020, 380 : 122408 https://doi.org/10.1016/j.cej.2019.122408
26
Y Lu, X L Liu, L He, Y X Zhang, Z Y Hu, G Tian, X Cheng, S M Wu, Y Z Li, X H Yang, L Y Wang, J W Liu, C Janiak, G G Chang, W H Li, G Van Tendeloo, X Y Yang, B L Su. Spatial heterojunction in nnanostructured TiO2 and its cascade effect for efficient photocatalysis. Nano Letters, 2020, 20( 5): 3122– 3129 https://doi.org/10.1021/acs.nanolett.9b05121
27
L N Affonso, J L Jr Marques, V V C Lima, J O Gonçalves, S C Barbosa, E G Primel, T A L Burgo, G L Dotto, L A A Pinto, T R S Jr Cadaval. Removal of fluoride from fertilizer industry effluent using carbon nanotubes stabilized in chitosan sponge. Journal of Hazardous Materials, 2020, 388 : 122042 https://doi.org/10.1016/j.jhazmat.2020.122042
28
X Wang, H Pfeiffer, J Wei, J Dan, J Wang, J Zhang. 3D porous Ca-modified Mg–Zr mixed metal oxide for fluoride adsorption. Chemical Engineering Journal, 2022, 428 : 131371 https://doi.org/10.1016/j.cej.2021.131371
29
M Gao, W Wang, H Yang, B C Ye. Efficient removal of fluoride from aqueous solutions using 3D flower-like hierarchical zinc–magnesium–aluminum ternary oxide microspheres. Chemical Engineering Journal, 2020, 380 : 122459 https://doi.org/10.1016/j.cej.2019.122459
30
W Li, T Zhang, L Lv, Y Chen, W Tang, S Tang. Room-temperature synthesis of MIL-100(Fe) and its adsorption performance for fluoride removal from water. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 624 : 126791 https://doi.org/10.1016/j.colsurfa.2021.126791
31
S Sekar S E Panchu E Kolanthai V Rajaram N K Subbaraya. Enhanced stability of hydroxyapatite/sodium alginate nanocomposite for effective fluoride adsorption. Materials Today: Proceedings, 2021
32
Y Yang, X Li, Y Gu, H Lin, B Jie, Q Zhang, X Zhang. Adsorption property of fluoride in water by metal organic framework: optimization of the process by response surface methodology technique. Surfaces and Interfaces, 2022, 28 : 101649 https://doi.org/10.1016/j.surfin.2021.101649
33
M Gao, W Wang, M Cao, H Yang, Y Li. Constructing hydrangea-like hierarchical zinc–zirconium oxide microspheres for accelerating fluoride elimination. Journal of Molecular Liquids, 2020, 317 : 114133 https://doi.org/10.1016/j.molliq.2020.114133
34
X Wang, J Wei, W Peng, J Dan, J Wang, J Zhang. Evaluation and DFT analysis of 3D porous rhombohedral Fe-modified MgO for removing fluoride efficiently. Applied Surface Science, 2021, 552 : 149423 https://doi.org/10.1016/j.apsusc.2021.149423
35
L Zhu, C Zhang, L Wang, J Zhang. The simple synthesis of metal organic frameworks with high fluoride adsorption performance from water. Journal of Solid State Chemistry, 2022, 307 : 122866 https://doi.org/10.1016/j.jssc.2021.122866
36
B Wu, J Wan, Y Zhang, B C Pan, I Lo. Selective phosphate removal from water and wastewater using sorption: process fundamentals and removal mechanisms. Environmental Science & Technology, 2019, 54( 1): 50– 66 https://doi.org/10.1021/acs.est.9b05569
37
L Ai, H Yue, J Jiang. Sacrificial template-directed synthesis of mesoporous manganese oxide architectures with superior performance for organic dye adsorption. Nanoscale, 2012, 4( 17): 5401– 5408 https://doi.org/10.1039/C2NR31333B
38
W Zhu, Y Li, L Dai, J Li, X Li, W Li, T Duan, J Lei, T Chen. Bioassembly of fungal hyphae/carbon nanotubes composite as a versatile adsorbent for water pollution control. Chemical Engineering Journal, 2018, 339 : 214– 222 https://doi.org/10.1016/j.cej.2018.01.134
39
H Cai, L Xu, G Chen, C Peng, F Ke, Z Liu, D Li, Z Zhang, X Wan. Removal of fluoride from drinking water using modified ultrafine tea powder processed using a ball-mill. Applied Surface Science, 2016, 375 : 74– 84 https://doi.org/10.1016/j.apsusc.2016.03.005
40
S M Prabhu, S S Elanchezhiyan, G Lee, A Khan, S Meenakshi. Assembly of nano-sized hydroxyapatite onto graphene oxide sheets via in-situ fabrication method and its prospective application for defluoridation studies. Chemical Engineering Journal, 2016, 300 : 334– 342 https://doi.org/10.1016/j.cej.2016.04.111
41
H Yan, Q Chen, J Liu, Y Feng, K Shih. Phosphorus recovery through adsorption by layered double hydroxide nano-composites and transfer into a struvite-like fertilizer. Water Research, 2018, 145 : 721– 730 https://doi.org/10.1016/j.watres.2018.09.005
42
C E Choong, K T Wong, S B Jang, I W Nah, J Choi, S Ibrahim, Y Yoon, M Jang. Fluoride removal by palm shell waste based powdered activated carbon vs. functionalized carbon with magnesium silicate: implications for their application in water treatment. Chemosphere, 2020, 239 : 124765 https://doi.org/10.1016/j.chemosphere.2019.124765
43
S Mandal, S Mayadevi. Defluoridation of water using as-synthesized Zn/Al/Cl anionic clay adsorbent: equilibrium and regeneration studies. Journal of Hazardous Materials, 2009, 167( 1): 873– 878 https://doi.org/10.1016/j.jhazmat.2009.01.069
44
F Li, L Zhang, D G Evans, X Duan. Structure and surface chemistry of manganese-doped copper-based mixed metal oxides derived from layered double hydroxides. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 244( 1): 169– 177 https://doi.org/10.1016/j.colsurfa.2004.06.022
45
M Gao, W Wang, H Yang, B C Ye. Efficient removal of fluoride from aqueous solutions using 3D flower-like hierarchical zinc–magnesium–aluminum ternary oxide microspheres. Chemical Engineering Journal, 2020, 380 : 380 https://doi.org/10.1016/j.cej.2019.122459
46
X Dou, D Mohan, C U Jr Pittman, S Yang. Remediating fluoride from water using hydrous zirconium oxide. Chemical Engineering Journal, 2012, 198 : 236– 245 https://doi.org/10.1016/j.cej.2012.05.084
47
X Wu, Y Zhang, X Dou, B Zhao, M Yang. Fluoride adsorption on an Fe–Al–Ce trimetal hydrous oxide: characterization of adsorption sites and adsorbed fluorine complex species. Chemical Engineering Journal, 2013, 223 : 364– 370 https://doi.org/10.1016/j.cej.2013.03.027
J Tian, K Zhang, W Wang, F Wang, J Dan, S Yang, J Zhang, B Dai, F Yu. Enhanced selective catalytic reduction of NO with NH3 via porous micro-spherical aggregates of Mn–Ce–Fe–Ti mixed oxide nanoparticles. Green Energy & Environment, 2019, 4( 3): 311– 321 https://doi.org/10.1016/j.gee.2019.05.001
50
Y Yu, L Yu, J Paul Chen. Adsorption of fluoride by Fe–Mg–La triple–metal composite: adsorbent preparation, illustration of performance and study of mechanisms. Chemical Engineering Journal, 2015, 262 : 839– 846 https://doi.org/10.1016/j.cej.2014.09.006
