Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, Harbin 150040, China
Phase change materials are potential candidates for the application of latent heat storage. Herein, we fabricated porous capsules as shape-stable materials from cellulose-based polyelectrolyte complex, which were first prepared using cellulose 6-(N-pyridinium)hexanoyl ester as the cationic polyelectrolyte and carboxymethyl cellulose as the anionic polyelectrolyte to encapsulate polyethylene glycol by the vacuum impregnation method. Furthermore, the multi-walled carbon nanotube or graphene oxide, which were separately composited into the polyelectrolytes complex capsules to enhance thermal conductivity and light-to-thermal conversion efficiency. These capsules owned a typical core–shell structure, with an extremely high polyethylene glycol loading up to 34.33 g∙g‒1. After loading of polyethylene glycol, the resulted cellulose-based composite phase change materials exhibited high thermal energy storage ability with the latent heat up to 142.2 J∙g‒1, which was 98.5% of pure polyethylene glycol. Further results showed that the composite phase change materials demonstrated good form-stable property and thermal stability. Moreover, studies involving light-to-thermal conversion determined that composite phase change materials exhibited outstanding light-to-thermal conversion performance. Considering their exceptional comprehensive features, innovative composite phase change materials generated from cellulose presented a highly interesting choice for thermal management and renewable thermal energy storage.
J Guo, Y Jiang, Y Wang, B Zou. Thermal storage and thermal management properties of a novel ventilated mortar block integrated with phase change material for floor heating: an experimental study. Energy Conversion and Management, 2020, 205: 112288 https://doi.org/10.1016/j.enconman.2019.112288
2
H Yang, Y Bai, C Ge, L He, W Liang, X Zhang. Polyethylene glycol-based phase change materials with high photothermal conversion efficiency and shape stability in an aqueous environment for solar water heater. Composites Part A: Applied Science and Manufacturing, 2022, 154: 106778 https://doi.org/10.1016/j.compositesa.2021.106778
3
C Li, H Yu, Y Song, Z Liu. Novel hybrid microencapsulated phase change materials incorporated wallboard for year-long year energy storage in buildings. Energy Conversion and Management, 2019, 183: 791–802 https://doi.org/10.1016/j.enconman.2019.01.036
4
Z Huang, X Gao, T Xu, Y Fang, Z Zhang. Thermal property measurement and heat storage analysis of LiNO3/KCl-expanded graphite composite phase change material. Applied Energy, 2014, 115: 265–271 https://doi.org/10.1016/j.apenergy.2013.11.019
5
Z Khan, Z Khan, A Ghafoor. A review of performance enhancement of PCM based latent heat storage system within the context of materials, thermal stability and compatibility. Energy Conversion and Management, 2016, 115: 132–158 https://doi.org/10.1016/j.enconman.2016.02.045
6
S Y Kee, Y Munusamy, K S Ong. Review of solar water heaters incorporating solid-liquid organic phase change materials as thermal storage. Applied Thermal Engineering, 2018, 131: 455–471 https://doi.org/10.1016/j.applthermaleng.2017.12.032
7
K Sun, Y Kou, Y Zhang, T Liu, Q Shi. Photo-triggered hierarchical porous carbon-based composite phase-change materials with superior thermal energy conversion capacity. ACS Sustainable Chemistry & Engineering, 2020, 8(8): 3445–3453 https://doi.org/10.1021/acssuschemeng.9b07659
8
Z Sun, K Sun, H Zhang, H Liu, D Wu, X Wang. Development of poly(ethylene glycol)/silica phase-change microcapsules with well-defined core–shell structure for reliable and durable heat energy storage. Solar Energy Materials and Solar Cells, 2021, 225: 111069 https://doi.org/10.1016/j.solmat.2021.111069
9
Z Zheng, T Shi, H Liu, D Wu, X Wang. Polyimide/phosphorene hybrid aerogel-based composite phase change materials for high-efficient solar energy capture and photothermal conversion. Applied Thermal Engineering, 2022, 207: 118173 https://doi.org/10.1016/j.applthermaleng.2022.118173
10
Z Lang, Y Ju, Y Wang, Z Xiao, H Wang, D Liang, J Li, Y Xie. Cellulose-derived solid-solid phase change thermal energy storage membrane with switchable optical transparency. Chemical Engineering Journal, 2022, 435: 134851 https://doi.org/10.1016/j.cej.2022.134851
11
Z Yu, D Feng, Y Feng, X Zhang. Thermal conductivity and energy storage capacity enhancement and bottleneck of shape-stabilized phase change composites with graphene foam and carbon nanotubes. Composites Part A: Applied Science and Manufacturing, 2022, 152: 106703 https://doi.org/10.1016/j.compositesa.2021.106703
12
P A Advincula, A C de Leon, B J Rodier, J Kwon, R C Advincula, E B Pentzer. Accommodating volume change and imparting thermal conductivity by encapsulation of phase change materials in carbon nanoparticles. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(6): 2461–2467 https://doi.org/10.1039/C7TA09664J
13
Z Sun, T Shi, Y Wang, J Li, H Liu, X Wang. Hierarchical microencapsulation of phase change material with carbon-nanotubes/polydopamine/silica shell for synergistic enhancement of solar photothermal conversion and storage. Solar Energy Materials and Solar Cells, 2022, 236: 111539 https://doi.org/10.1016/j.solmat.2021.111539
14
L Zhang, L An, Y Wang, A Lee, Y Schuman, A Ural, A S Fleischer, G Feng. Thermal enhancement and shape stabilization of a phase-change energy-storage material via copper nanowire aerogel. Chemical Engineering Journal, 2019, 373: 857–869 https://doi.org/10.1016/j.cej.2019.05.104
15
A Arshad, M Jabbal, Y Yan, J Darkwa. The micro-/nano-PCMs for thermal energy storage systems: a state of art review. International Journal of Energy Research, 2019, 43(11): 5572–5620 https://doi.org/10.1002/er.4550
16
G Bahsi Kaya, Y Kim, K Callahan, S Kundu. Microencapsulated phase change material via Pickering emulsion stabilized by cellulose nanofibrils for thermal energy storage. Carbohydrate Polymers, 2022, 276: 118745 https://doi.org/10.1016/j.carbpol.2021.118745
17
F Wang, Y Zhang, X Li, B Wang, X Feng, H Xu, Z Mao, X Sui. Cellulose nanocrystals-composited poly (methyl methacrylate) encapsulated n-eicosane via a Pickering emulsion-templating approach for energy storage. Carbohydrate Polymers, 2020, 234: 115934 https://doi.org/10.1016/j.carbpol.2020.115934
18
Y Yoo, C Martinez, J P Youngblood. Synthesis and characterization of microencapsulated phase change materials with poly(urea-urethane) shells containing cellulose nanocrystals. ACS Applied Materials & Interfaces, 2017, 9(37): 31763–31776 https://doi.org/10.1021/acsami.7b06970
19
Z Zheng, H Liu, D Wu, X Wang. Polyimide/MXene hybrid aerogel-based phase-change composites for solar-driven seawater desalination. Chemical Engineering Journal, 2022, 440: 135862 https://doi.org/10.1016/j.cej.2022.135862
20
T Xu, K Liu, N Sheng, M Zhang, W Liu, H Liu, L Dai, X Zhang, C Si, H Du, K Zhang. Biopolymer-based hydrogel electrolytes for advanced energy storage/conversion devices: properties, applications, and perspectives. Energy Storage Materials, 2022, 48: 244–262 https://doi.org/10.1016/j.ensm.2022.03.013
21
H Liu, H Du, T Zheng, K Liu, X Ji, T Xu, X Zhang, C Si. Cellulose based composite foams and aerogels for advanced energy storage devices. Chemical Engineering Journal, 2021, 426: 130817 https://doi.org/10.1016/j.cej.2021.130817
22
M Cheng, J Hu, J Xia, Q Liu, T Wei, Y Ling, W Li, B Liu. One-step in-situ green synthesis of cellulose nanocrystal aerogel based shape stable phase change material. Chemical Engineering Journal, 2022, 431: 133935 https://doi.org/10.1016/j.cej.2021.133935
23
Y Qian, N Han, X Gao, X Gao, W Li, X Zhang. Cellulose-based phase change fibres for thermal energy storage and management applications. Chemical Engineering Journal, 2021, 412: 128596 https://doi.org/10.1016/j.cej.2021.128596
24
D Xiao, W Liang, Z Xie, J Cheng, Y Du, J Zhao. A temperature-responsive release cellulose-based microcapsule loaded with chlorpyrifos for sustainable pest control. Journal of Hazardous Materials, 2021, 403: 123654 https://doi.org/10.1016/j.jhazmat.2020.123654
25
K Yuan, J Liu, X Fang, Z Zhang. Novel facile self-assembly approach to construct graphene oxide-decorated phase-change microcapsules with enhanced photo-to-thermal conversion performance. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(10): 4535–4543 https://doi.org/10.1039/C8TA00215K
26
Y Lin, C Zhu, G Alva, G Fang. Microencapsulation and thermal properties of myristic acid with ethyl cellulose shell for thermal energy storage. Applied Energy, 2018, 231: 494–501 https://doi.org/10.1016/j.apenergy.2018.09.154
27
S Han, S Lyu, S Wang, F Fu. High-intensity ultrasound assisted manufacturing of melamine-urea-formaldehyde/paraffin nanocapsules. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 568: 75–83 https://doi.org/10.1016/j.colsurfa.2019.01.054
28
L Jasmani, S Eyley, R Wallbridge, W Thielemans. A facile one-pot route to cationic cellulose nanocrystals. Nanoscale, 2013, 5(21): 10207–10211 https://doi.org/10.1039/c3nr03456a
29
J F S Pedrosa, M G Rasteiro, C P Neto, P J T Ferreira. Effect of cationization pretreatment on the properties of cationic Eucalyptus micro/nanofibrillated cellulose. International Journal of Biological Macromolecules, 2022, 201: 468–479 https://doi.org/10.1016/j.ijbiomac.2022.01.068
30
M Matandabuzo, P A Ajibade. Synthesis, characterization, and physicochemical properties of hydrophobic pyridinium-based ionic liquids with N-propyl and N-isopropyl. Zeitschrift für Anorganische und Allgemeine Chemie, 2018, 644(10): 489–495 https://doi.org/10.1002/zaac.201800006
31
W Tan, Q Li, F Dong, J Zhang, F Luan, L Wei, Y Chen, Z Guo. Novel cationic chitosan derivative bearing 1,2,3-triazolium and pyridinium: synthesis, characterization, and antifungal property. Carbohydrate Polymers, 2018, 182: 180–187 https://doi.org/10.1016/j.carbpol.2017.11.023
32
S Liu, K J Edgar. Water-soluble co-polyelectrolytes by selective modification of cellulose esters. Carbohydrate Polymers, 2017, 162: 1–9 https://doi.org/10.1016/j.carbpol.2017.01.008
33
T Rashid, C F Kait, I Regupathi, T Murugesan. Dissolution of kraft lignin using protic ionic liquids and characterization. Industrial Crops and Products, 2016, 84: 284–293 https://doi.org/10.1016/j.indcrop.2016.02.017
34
X Zhang, B Shen, S Zhu, H Xu, L Tian. UiO-66 and its Br-modified derivates for elemental mercury removal. Journal of Hazardous Materials, 2016, 320: 556–563 https://doi.org/10.1016/j.jhazmat.2016.08.039
35
H Mao, Y Fu, H Yang, S Zhang, J Liu, S Wu, Q Wu, T Ma, X M Song. Structure-activity relationship toward electrocatalytic nitrogen reduction of MoS2 growing on polypyrrole/graphene oxide affected by pyridinium-type ionic liquids. Chemical Engineering Journal, 2021, 425: 131769 https://doi.org/10.1016/j.cej.2021.131769
36
K Shimizu, A Shchukarev, P A Kozin, J F Boily. X-ray photoelectron spectroscopy of fast-frozen hematite colloids in aqueous solutions. 5. Halide ion (F‒, Cl‒, Br‒, I‒) adsorption. Langmuir, 2013, 29(8): 2623–2630 https://doi.org/10.1021/la3039973
37
W Shi, Y C Ching, C H Chuah. Preparation of aerogel beads and microspheres based on chitosan and cellulose for drug delivery: a review. International Journal of Biological Macromolecules, 2021, 170: 751–767 https://doi.org/10.1016/j.ijbiomac.2020.12.214
38
M Rasoulzadeh, H Namazi. Carboxymethyl cellulose/graphene oxide bio-nanocomposite hydrogel beads as anticancer drug carrier agent. Carbohydrate Polymers, 2017, 168: 320–326 https://doi.org/10.1016/j.carbpol.2017.03.014
39
M Yadollahi, S Farhoudian, S Barkhordari, I Gholamali, H Farhadnejad, H Motasadizadeh. Facile synthesis of chitosan/ZnO bio-nanocomposite hydrogel beads as drug delivery systems. International Journal of Biological Macromolecules, 2016, 82: 273–278 https://doi.org/10.1016/j.ijbiomac.2015.09.064
40
Y Li, K Sun, Y Kou, H Liu, L Wang, N Yin, H Dong, Q Shi. One-step synthesis of graphene-based composite phase change materials with high solar-thermal conversion efficiency. Chemical Engineering Journal, 2022, 429: 132439 https://doi.org/10.1016/j.cej.2021.132439
41
Y Fang, S Liu, X Li, X Hu, H Wu, X Lu, J Qu. Biomass porous potatoes/MXene encapsulated PEG-based PCMs with improved photo-to-thermal conversion capability. Solar Energy Materials and Solar Cells, 2022, 237: 111559 https://doi.org/10.1016/j.solmat.2021.111559
42
X Chen, P Cheng, Z Tang, X Xu, H Gao, G Wang. Carbon-based composite phase change materials for thermal energy storage, transfer, and conversion. Advanced Science, 2021, 8(9): 2001274 https://doi.org/10.1002/advs.202001274
43
F Xue, Y Lu, X D Qi, J H Yang, Y Wang. Melamine foam-templated graphene nanoplatelet framework toward phase change materials with multiple energy conversion abilities. Chemical Engineering Journal, 2019, 365: 20–29 https://doi.org/10.1016/j.cej.2019.02.023
44
Y Liu, Y Yang, S Li. Graphene oxide modified hydrate salt hydrogels: form-stable phase change materials for smart thermal management. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2016, 4(46): 18134–18143 https://doi.org/10.1039/C6TA08850C
45
Y Wang, Z Qiu, Z Lang, Y Xie, Z Xiao, H Wang, D Liang, J Li, K Zhang. Multifunctional reversible self-assembled structures of cellulose-derived phase-change nanocrystals. Advanced Materials, 2021, 33(3): e2005263 https://doi.org/10.1002/adma.202005263
46
S Hou, M Wang, S Guo, M Su. Photothermally driven refreshable microactuators based on graphene oxide doped paraffin. ACS Applied Materials & Interfaces, 2017, 9(31): 26476–26482 https://doi.org/10.1021/acsami.7b08728
47
N Nandihalli, C J Liu, T Mori. Polymer based thermoelectric nanocomposite materials and devices: fabrication and characteristics. Nano Energy, 2020, 78: 105186 https://doi.org/10.1016/j.nanoen.2020.105186
48
Y Xie, W Li, H Huang, D Dong, X Zhang, L Zhang, Y Chen, X Sheng, X Lu. Bio-based radish@PDA/PEG sandwich composite with high efficiency solar thermal energy storage. ACS Sustainable Chemistry & Engineering, 2020, 8(22): 8448–8457 https://doi.org/10.1021/acssuschemeng.0c02959