Pt–C interactions in carbon-supported Pt-based electrocatalysts
Yu-Xuan Xiao1, Jie Ying1(), Hong-Wei Liu1, Xiao-Yu Yang2()
1. School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China 2. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & Shenzhen Research Institute & Joint Laboratory for Marine Advanced Materials in Pilot National Laboratory for Marine Science and Technology (Qingdao), Wuhan University of Technology, Wuhan 430070, China
Carbon-supported Pt-based materials are highly promising electrocatalysts. The carbon support plays an important role in the Pt-based catalysts by remarkably influencing the growth, particle size, morphology, dispersion, electronic structure, physiochemical property and function of Pt. This review summarizes recent progress made in the development of carbon-supported Pt-based catalysts, with special emphasis being given to how activity and stability enhancements are related to Pt–C interactions in various carbon supports, including porous carbon, heteroatom doped carbon, carbon-based binary support, and their corresponding electrocatalytic applications. Finally, the current challenges and future prospects in the development of carbon-supported Pt-based catalysts are discussed.
3D hierarchical bimodal macroporous carbon nanospheres
Soft template
Macropore
~120 nm
[62]
Cornstalk-derived macroporous carbon
Direct pyrolysis
Macropore
5.0–20.0 μm
[63]
Macroporous carbon
Direct pyrolysis
Macropore
250 nm
[64]
Eggplant-derived macroporous carbon tubes
Direct pyrolysis
Macropore
40–50 μm
[65]
Well-ordered macroporous carbon
Direct pyrolysis
Macropore
4–40?μm
[66]
Tab.1
Fig.2
Fig.3
Fig.4
Fig.5
Fig.6
Fig.7
Fig.8
Fig.9
Fig.10
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