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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

邮发代号 80-969

2019 Impact Factor: 3.552

Frontiers of Chemical Science and Engineering  2023, Vol. 17 Issue (11): 1765-1775   https://doi.org/10.1007/s11705-023-2323-y
  本期目录
Durable and recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation of dyes under visible light irradiation
Jialiang Xu1, Jian Jian1,2,3(), Yixiao Dan1, Jie Song1, Lingxi Meng1, Pei Deng1, Weijie Sun2, Yusheng Zhang1(), Jinhua Xiong3, Zhengqiu Yuan1, Hu Zhou1()
1. School of Chemistry and Chemical Engineering, Hunan Engineering Research Center for Functional Film Materials, Hunan University of Science and Technology, Xiangtan 411201, China
2. School of Chemical Engineering, Post Doctoral Mobile Station in Chemistry, Xiangtan University, Xiangtan 411105, China
3. Post Doctoral Research Workstation, Anhui Huaxing Chemical Industry Co., Ltd., Hexian 238251, China
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Abstract

A stable and recyclable of BiOBr/silk fibroin-cellulose acetate composite film was prepared by blending-wet phase transformation and in situ precipitate technology. The cellulose acetate film modified by silk fibroin formed a finger-shaped porous structure, which provided a large space for the uniform growth of BiOBr nanosheets and facilitated the shuttle flow of dyes in film. The morphology, phase structure, and optical properties of the composite films were characterized using various techniques, and their photocatalytic performance for dye wastewater was evaluated under visible light irradiation. Results showed that the BiOBr/SF-CA composite film exhibited efficient photocatalytic activity with 99.9% of rhodamine B degradation rate. Moreover, the composite film maintained high catalytic stability because Bi as the active species deposited on the film showed almost no loss. Finally, the possible photocatalytic mechanisms in the BiOBr/SF-CA composite film were speculated through radical-trapping experiments and electron spin resonance testing.

Key wordsBiOBr nanosheet    cellulose acetate    silk fibroin    photocatalytic degradation    dye wastewater
收稿日期: 2022-12-07      出版日期: 2023-10-25
Corresponding Author(s): Jian Jian,Yusheng Zhang,Hu Zhou   
 引用本文:   
. [J]. Frontiers of Chemical Science and Engineering, 2023, 17(11): 1765-1775.
Jialiang Xu, Jian Jian, Yixiao Dan, Jie Song, Lingxi Meng, Pei Deng, Weijie Sun, Yusheng Zhang, Jinhua Xiong, Zhengqiu Yuan, Hu Zhou. Durable and recyclable BiOBr/silk fibroin-cellulose acetate composite film for efficient photodegradation of dyes under visible light irradiation. Front. Chem. Sci. Eng., 2023, 17(11): 1765-1775.
 链接本文:  
https://academic.hep.com.cn/fcse/CN/10.1007/s11705-023-2323-y
https://academic.hep.com.cn/fcse/CN/Y2023/V17/I11/1765
  
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
PhotocatalystPhotocatalyst formsCatalyst dosage/(g·L–1)Dyes concentration/(mg·L–1)Time/minDegradation rate/minRef.
CC/BiOBr compositesPowder1.010.040> 80.0[18]
BiOBr-OAPowder1.010.040> 99.9[33]
Fe-Cu-BiOBrPowder0.410.090> 95.0[34]
QDs-Cu2O/BiOBrPowder1.010.06095.0[43]
Bi/BiOBr compositesPowder1.010.03095.5[46]
BiOBr/Bio-veinsFilm1.010.012097.8[41]
BiOBr/SF-CAFilm1.010.012099.9This work
Tab.1  
Fig.7  
Fig.8  
  
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