Tailoring the microstructure and properties of PES/SPSf loose nanofiltration membranes using SPES as a hydrophilic polymer for the effective removal of dyes via steric hindrance and charge effect
1. State Key Laboratory of Separation Membranes and Membrane Processes, National Center for International Joint Research on Separation Membranes, School of Materials Science and Engineering, Tiangong University, Tianjin 300387, China 2. Collaborative Innovation Center for Eco-Textiles of Shandong Province, Qingdao 266071, China 3. Institute for Nanotechnology and Water Sustainability College of Science Engineering and Technology, University of South Africa, Science Campus, Florida 1710, Johannesburg, South Africa
Herein, polyethersulfone (PES) and sulfonated polysulfone (SPSf) blend membranes were prepared with addition of sulfonated polyethersulfone (SPES) as a hydrophilic polymer and adipic acid as a porogen via non-solvent induced phase separation method for effective fractionation of dyes based on the influence of steric hindrance and charge effect. Raman spectroscopy and molecular dynamic simulation modeling confirmed that hydrogen bonds between PES, SPSf, SPES, and adipic acid were crucial to membrane formation and spatial arrangement. Further addition of hydrophilic SPES resulted in a membrane with reduced pore size and molecular weight cut-off as well as amplified negative charge and pure water permeance. During separation, the blend membranes exhibited higher rejection rates for nine types of small molecular weight (269.3–800 Da) dyes than for neutral polyethylene glycol molecules (200–1000 Da). This was attributed to the size effect and the synergistic effect between steric hindrance and charge repulsion. Notably, the synergistic impact decreased with dye molecular weight, while greater membrane negative charge enhanced small molecular dye rejection. Ideal operational stability and anti-fouling performance were best observed in M2 (PES/SPSf/SPES, 3.1 wt %). Summarily, this study demonstrates that SPES with –SO3‒ functional groups can be applied to control the microstructure and separation of membranes.
. [J]. Frontiers of Chemical Science and Engineering, 2023, 17(10): 1555-1567.
Xiaowei Liu, Christine Matindi, Sania Kadanyo, Mengyang Hu, Shuqian Yang, Gansheng Liu, Ran Tao, Zhenyu Cui, Xiaohua Ma, Kuanjun Fang, Jianxin Li. Tailoring the microstructure and properties of PES/SPSf loose nanofiltration membranes using SPES as a hydrophilic polymer for the effective removal of dyes via steric hindrance and charge effect. Front. Chem. Sci. Eng., 2023, 17(10): 1555-1567.
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