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Frontiers in Energy

ISSN 2095-1701

ISSN 2095-1698(Online)

CN 11-6017/TK

邮发代号 80-972

2019 Impact Factor: 2.657

Frontiers in Energy  2018, Vol. 12 Issue (3): 466-480   https://doi.org/10.1007/s11708-018-0561-3
  本期目录
发展中国家道路交通温室气体减排机遇:氢能燃料电池汽车
郝瀚1, 牟哲萱2, 刘宗巍2, 赵福全2()
1. 中国北京市清华大学汽车安全与节能国家重点实验室(100084);清华大学车用能源研究中心(10084)
2. 中国北京市清华大学汽车安全与节能国家重点实验室(10084)
Abating transport GHG emissions by hydrogen fuel cell vehicles: Chances for the developing world
Han HAO1, Zhexuan MU2, Zongwei LIU2, Fuquan ZHAO2()
1. State Key Laboratory of Automotive Safety and Energy; China Automotive Energy Research Center, Tsinghua University, Beijing 100084, China
2. State Key Laboratory of Automotive Safety and Energy, Tsinghua University, Beijing 100084, China
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摘要:

燃料电池汽车普遍被认为是未来清洁交通的终极技术。发展中国家的相关基础设施尚不完全,没有路径锁定效应。本文以中国为例,一方面回顾并分析了燃料电池汽车的发展及其独特优势,另一方面对中国19种燃料电池制氢路径的全生命周期碳排放进行了计算。结果表明在中国目前的电力结构下,从制氢角度,电解水制氢手段有最高的碳排放,为3.10 kgCO2/km;氯碱工业副产氢是碳排放最低的一种制氢方式,为0.08 kgCO2/km。从氢气储运角度,气氢公路运输与一级压缩加氢站的组合碳排放最低;从燃料电池汽车角度,间接甲醇燃料电池汽车从整个燃料生命周期角度看,其碳排放要低于大多数直接氢气燃料电池汽车。虽然对于大多数发展中国家来说,氢能燃料电池汽车的发展对于温室气体减排有一定的潜力,但是为保证构建可持续交通的燃料电池汽车发展路线,必须慎重考虑相应的车辆技术与氢气来源。

Abstract

Fuel cell vehicles, as the most promising clean vehicle technology for the future, represent the major chances for the developing world to avoid high-carbon lock-in in the transportation sector. In this paper, by taking China as an example, the unique advantages for China to deploy fuel cell vehicles are reviewed. Subsequently, this paper analyzes the greenhouse gas (GHG) emissions from 19 fuel cell vehicle utilization pathways by using the life cycle assessment approach. The results show that with the current grid mix in China, hydrogen from water electrolysis has the highest GHG emissions, at 3.10 kgCO2/km, while by-product hydrogen from the chlor-alkali industry has the lowest level, at 0.08 kgCO2/km. Regarding hydrogen storage and transportation, a combination of gas-hydrogen road transportation and single compression in the refueling station has the lowest GHG emissions. Regarding vehicle operation, GHG emissions from indirect methanol fuel cell are proved to be lower than those from direct hydrogen fuel cells. It is recommended that although fuel cell vehicles are promising for the developing world in reducing GHG emissions, the vehicle technology and hydrogen production issues should be well addressed to ensure the life-cycle low-carbon performance.

Key wordshydrogen    fuel cell vehicle    life cycle assessment    energy consumption    greenhouse gas (GHG) emissions    China
收稿日期: 2017-11-05      出版日期: 2018-09-05
通讯作者: 赵福全     E-mail: zhaofuquan@tsinghua.edu.cn
Corresponding Author(s): Fuquan ZHAO   
 引用本文:   
郝瀚, 牟哲萱, 刘宗巍, 赵福全. 发展中国家道路交通温室气体减排机遇:氢能燃料电池汽车[J]. Frontiers in Energy, 2018, 12(3): 466-480.
Han HAO, Zhexuan MU, Zongwei LIU, Fuquan ZHAO. Abating transport GHG emissions by hydrogen fuel cell vehicles: Chances for the developing world. Front. Energy, 2018, 12(3): 466-480.
 链接本文:  
https://academic.hep.com.cn/fie/CN/10.1007/s11708-018-0561-3
https://academic.hep.com.cn/fie/CN/Y2018/V12/I3/466
Fig.1  
Pathway No. Feedstock processing Product fuel transporting Product fuel storing Vehicle fuel use
1 Coal gasification GH2 by tube trailer Off-site HRS1 DHFCV
2 Coal gasification LH2 by tank Off-site HRS2 DHFCV
3 Coal gasification GH2 by pipeline Off-site HRS2 DHFCV
4 NG reforming GH2 by tube trailer Off-site HRS1 DHFCV
5 NG reforming LH2 by tank Off-site HRS2 DHFCV
6 NG reforming GH2 by pipeline Off-site HRS2 DHFCV
7 Water electrolysis (State grid electricity) GH2 by tube trailer Off-site HRS1 DHFCV
8 Water electrolysis (State grid electricity) LH2 by tank Off-site HRS2 DHFCV
9 Water electrolysis (State grid electricity) GH2 by pipeline Off-site HRS2 DHFCV
10 Water electrolysis (Water electricity) GH2 by tube trailer Off-site HRS1 DHFCV
11 Water electrolysis (Water electricity) LH2 by tank Off-site HRS2 DHFCV
12 Water electrolysis (Water electricity) GH2 by pipeline Off-site HRS2 DHFCV
13 By-product H2 of chlor-alkali industry GH2 by tube trailer Off-site HRS1 DHFCV
14 By-product H2 of chlor-alkali industry LH2 by tank Off-site HRS2 DHFCV
15 By-product H2 of chlor-alkali industry GH2 by pipeline Off-site HRS2 DHFCV
16 NG production CNG by tank On-site HRS via GN Gasification DHFCV
17 NG production LNG by tank On-site HRS via GN Gasification DHFCV
18 / / On-site HRS via water electrolysis DHFCV
19 Methanol via coal Methanol by tank MRS IMFCV
Tab.1  
Process energy Average lower heating value GHG emissions factor Data source
Coal 20908 kJ/kg 94.75 g-CO2/MJ [20]
Natural gas 38931 kJ/m3 63.48 g-CO2/MJ [20]
Gasoline 43070 kJ/kg 81.98 g-CO2/MJ [20]
Diesel 42552 kJ/kg 79.91 g-CO2/MJ [20]
Electricity (grid) 834.5 g-CO2/kWh *
Tab.2  
Subsystem Data source
Feedstock processing subsystem Hydrogen via coal gasification [21,22]
Hydrogen via natural gas reforming [21,23]
Hydrogen from water electrolysis Factory data
By-product hydrogen of chlor-alkali industry [22,24]
Methanol via coal [25]
Natural gas production [21]
Product fuel transporting subsystem Gas hydrogen transported by tube trailer ①,②
Liquid hydrogen transported by tank [26,27]
Gas hydrogen transported by pipeline
CNG transported by tank ②,③,[33]
LNG transported by tank ②,⑤, [28]
Liquid methanol transported by tank ②,⑥
Product fuel storing subsystem Off-site hydrogen refueling station Factory data
On-site hydrogen refueling station via NG gasification [23]
On-site hydrogen refueling station via water electrolysis Factory data
Methanol refueling station
Vehicle fuel use subsystem Direct hydrogen FCV Factory data
Indirect methanol fuel cell station Factory data
Tab.3  
Fig.2  
Fig.3  
Technical routes Subsystems
Feedstock processing Product fuel transporting Product fuel storing Vehicle fuel use
H2 via coal gasification-GH2 by tube trailer-off-site HRS1-DHFCV 11.5265 5.2212 0.2321 9.3746
H2 via coal gasification-LH2 by Tank-off-site HRS2-DHFCV 11.5265 9.6198 4.6295 9.3746
H2 via coal gasification-GH2 by pipeline-off-site HRS2-DHFCV 11.5265 1.8168 4.6295 9.3746
H2 via NG reforming-GH2 by tube trailer-off-site HRS1-DHFCV 5.2366 5.2212 0.2321 9.3746
H2 via NG reforming-LH2 by tank-off-site HRS2-DHFCV 5.2366 9.6198 4.6295 9.3746
H2 via NG reforming-GH2 by pipeline-off-site HRS2-DHFCV 5.2366 2.0106 4.6295 9.3746
H2 via water electrolysis (G-Ele)-GH2 by tube Trailer-off-site HRS1-DHFCV 27.6008 5.2212 0.2321 9.3746
H2 via water electrolysis (G-Ele)-LH2 by tank-off-site HRS2-DHFCV 27.6008 9.6198 4.6295 9.3746
H2 via water electrolysis (G-Ele)-GH2 by pipeline-off-site HRS2-DHFCV 27.6008 2.0106 4.6295 9.3746
H2 via water electrolysis (W-Ele)-GH2 by tube trailer-off-site HRS1-DHFCV 0 5.2212 0.2321 9.3746
H2 via water electrolysis(W-Ele)-LH2 by tank-off-site HRS2-DHFCV 0 9.6198 4.6295 9.3746
H2 via water electrolysis(W-Ele)-GH2 by pipeline-off-site HRS2-DHFCV 0 2.0106 4.6295 9.3746
By-product H2 via chlor-alkali industry-GH2 by tube trailer-off-site HRS1-DHFCV 0.9411 4.8074 0.2321 9.3746
By-product H2 via chlor-alkali industry-LH2 by tank-off-site HRS2-DHFCV 0.9411 8.6937 4.6295 9.3746
By-product H2 via chlor-alkali industry-GH2 by pipeline-off-site HRS2-DHFCV 0.9411 2.0106 4.6295 9.3746
NG production-CNG by Tank-on-site HRS via NG gasification-DHFCV 0.5058 0.6164 9.36 9.3746
NG production-LNG by tank-on-site HRS via NG gasification-DHFCV 0.5058 0.874 9.36 9.3746
On-site HRS via water electrolysis-DHFCV 0 0 32.23 9.3746
Methanol via coal-liquid methanol by tank-MRS-IMFCV 11.0493 0.002 0 10.8942
Diesel via coal-diesel transportation-diesel RS-diesel ICEV 2.771922384 0.02688588 0 8.3997648
Power plant-transmission loss-charging loss-BEV 10.34652406 0.278074866 0.427807487 3.6
Tab.4  
Technical routes Subsystems
Feedstock processing Product fuel transporting Product fuel storing Vehicle fuel use
H2 via coal gasification-GH2 by tube trailer-off-site HRS1-DHFCV 1.9734 0.4343 0.0194 0
H2 via coal gasification-LH2 by tank-off-site HRS2-DHFCV 1.9734 0.806 0.3879 0
H2 via coal gasification-GH2 by pipeline-off-site HRS2-DHFCV 1.9734 0.1685 0.3879 0
H2 via NG reforming-GH2 by tube trailer-off-site HRS1-DHFCV 1.1234 0.4343 0.0194 0
H2 via NG reforming-LH2 by tank-off-site HRS2-DHFCV 1.1234 0.806 0.3879 0
H2 via NG reforming-GH2 by pipeline-off-site HRS2-DHFCV 1.1234 0.1685 0.3879 0
H2 via water electrolysis (G-Ele)-GH2 by tube trailer-off-site HRS1-DHFCV 3.098 0.4343 0.0194 0
H2 via water electrolysis (G-Ele)-LH2 by tank-off-site HRS2-DHFCV 3.098 0.806 0.3879 0
H2 via water electrolysis (G-Ele)-GH2 by pipeline-off-site HRS2-DHFCV 3.098 0.1685 0.3879 0
H2 via water electrolysis (W-Ele)-GH2 by tube trailer-off-site HRS1-DHFCV 0 0.4343 0.0194 0
H2 via water electrolysis(W-Ele)-LH2 by tank-off-site HRS2-DHFCV 0 0.806 0.3879 0
H2 via water electrolysis(W-Ele)-GH2 by pipeline-off-site HRS2-DHFCV 0 0.1685 0.3879 0
By-product H2 via chlor-alkali industry-GH2 by tube trailer-off-site HRS1-DHFCV 0.0789 0.4351 0.0194 0
By-product H2 via chlor-alkali industry-LH2 by tank-off-site HRS2-DHFCV 0.0789 0.806 0.3879 0
By-product H2 via chlor-alkali industry-GH2 by pipeline-off-site HRS2-DHFCV 0.0789 0.1685 0.3879 0
NG production-CNG by tank-on-site HRS via NG gasification-DHFCV 0.0427 0.0517 1.3609 0
NG production-LNG by tank-on-site HRS via NG gasification-DHFCV 0.0427 0.0731 1.3609 0
On-site HRS via water electrolysis-DHFCV 0 0 3.4859 0
Methanol via coal-liquid methanol by tank-MRS-IMFCV 0.6067 0.00015 0 0.546
Diesel via coal-diesel transportation-diesel RS-diesel ICEV 0.2507 0.0022 0 0.6106
Power plant-transmission loss-charging loss-BEV 1.1151 0.0645 0.0992 0
Tab.5  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
Fig.9  
Fig.10  
Fig.11  
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