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Frontiers in Energy

ISSN 2095-1701

ISSN 2095-1698(Online)

CN 11-6017/TK

邮发代号 80-972

2019 Impact Factor: 2.657

Frontiers in Energy  2021, Vol. 15 Issue (3): 752-759   https://doi.org/10.1007/s11708-021-0779-3
  研究论文 本期目录
少层MoS2原位生长于CdS纳米棒表面提高光催化制氢活性
陈威(), 刘香, 卫少杰, 衡倩倩, 王缤纷, 刘诗龙, 高丽(), 毛立群
河南省废弃物资源能源化工程技术中心,河南大学,开封,475004
In situ growth of a-few-layered MoS2 on CdS nanorod for high efficient photocatalytic H2 production
Wei CHEN(), Xiang LIU, Shaojie WEI, Qianqian HENG, Binfen WANG, Shilong LIU, Li GAO(), Liqun MAO
Henan Engineering Research Center of Resource and Energy Recovery from Waste, Henan University, Kaifeng 475004, China
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摘要:

以硫粉为硫源,固相法原位生长超薄MoS2于CdS纳米棒表面并进行光催化产氢研究。表征结果显示少层(单层或两层)MoS2担载在CdS纳米棒表面且二者具有良好的界面接触。光电化学测试结果表明MoS2不仅有利于光生电荷的分离同时为活性位从而提高光催化制氢活性。负载的MoS2可以显著提升CdS的光催化活性。质量比为MoS2:CdS = 1:50 时,催化剂的产氢速率达到542 μmol/h, 为未负载CdS的6倍。该研究不仅为设计高活性的光催化材料提供思路而且加深理解MoS2提升光催化活性的作用。

Abstract

An ultrathin MoS2 was grown on CdS nanorod by a solid state method using sulfur powder as sulfur source for photocatalytic H2 production. The characterization result reveals that the ultrathin MoS2 nanosheets loaded on CdS has a good contact state. The photoelectrochemical result shows that MoS2 not only are beneficial for charge separation, but also works as active sites, thus enhancing photocatalytic activity. Compared with pure CdS, the photocatalytic activity of MoS2 loaded CdS was significantly improved. The hydrogen evolution rate on m(MoS2): m(CdS) = 1: 50 (m is mass) reaches 542 μmol/h, which is 6 times of that on pure CdS (92 μmol/h). This work provides a new design for photocatalysts with high photocatalytic activities and provides a deeper understanding of the effect of MoS2 on enhancing photocatalytic activity.

Key wordsphotocatalytic H2 production    CdS    MoS2 cocatalyst    charge separation
收稿日期: 2021-03-13      出版日期: 2021-10-09
通讯作者: 陈威,高丽     E-mail: chanwee@henu.edu.cn (Wei CHEN);gaoli@henu.edu.cn (Li GAO)
Corresponding Author(s): Wei CHEN,Li GAO   
 引用本文:   
陈威, 刘香, 卫少杰, 衡倩倩, 王缤纷, 刘诗龙, 高丽, 毛立群. 少层MoS2原位生长于CdS纳米棒表面提高光催化制氢活性[J]. Frontiers in Energy, 2021, 15(3): 752-759.
Wei CHEN, Xiang LIU, Shaojie WEI, Qianqian HENG, Binfen WANG, Shilong LIU, Li GAO, Liqun MAO. In situ growth of a-few-layered MoS2 on CdS nanorod for high efficient photocatalytic H2 production. Front. Energy, 2021, 15(3): 752-759.
 链接本文:  
https://academic.hep.com.cn/fie/CN/10.1007/s11708-021-0779-3
https://academic.hep.com.cn/fie/CN/Y2021/V15/I3/752
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Photo-
catalyst
Catalyst dosage
/mg
Cocatalyst/(mass fraction, %) Preparation
method
Sacrificial
reagent
Light source H2 evolution rate/(μmol?h−1?g−1) Ref.
CdS 50 2.0% MoS2 Solid state (S powder) Lactic acid 300 W Xenon lamp, λ>420 nm 10840 This work
CdS 50 5% MoS2 Hydrothermal Amoxicillin 300 W Xenon lamp, λ>420 nm 1760 [10]
CdS 100 3% MoS2 Solid state (H2S) Lactic acid 300 W Xenon lamp, λ>420 nm 5330 [11]
CdS 300 1.0% NiS Hydrothermal Lactic acid 300 W Xenon lamp, λ>420 nm 7000 [8]
CdS 200 2% MoS2 Adsorption Lactic acid 300 W Xenon lamp, λ>420 nm 12950 [14]
CdS 20 25% MoS2 Hydrothermal TEOA 300 W Xenon lamp, λ>400 nm 1145 [19]
CdS 10 6.39% MoS2 Hydrothermal Na2S+ Na2SO3 300 W Xenon lamp, λ>420 nm 4540 [22]
Tab.1  
Fig.7  
Fig.8  
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