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Frontiers of Mechanical Engineering

ISSN 2095-0233

ISSN 2095-0241(Online)

CN 11-5984/TH

邮发代号 80-975

2019 Impact Factor: 2.448

Frontiers of Mechanical Engineering  2016, Vol. 11 Issue (3): 258-274   https://doi.org/10.1007/s11465-016-0381-2
  本期目录
Research on the theory and application of adsorbed natural gas used in new energy vehicles: A review
Zhengwei NIE1, Yuyi LIN1(), Xiaoyi JIN2
1. Department of Mechanical & Aerospace Engineering, University of Missouri, Columbia, MO 65211, USA
2. College of Mechanical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
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Abstract

Natural gas, whose primary constituent is methane, has been considered a convincing alternative for the growth of the energy supply worldwide. Adsorbed natural gas (ANG), the most promising methane storage method, has been an active field of study in the past two decades. ANG constitutes a safe and low-cost way to store methane for natural gas vehicles at an acceptable energy density while working at substantially low pressures (3.5–4.0 MPa), allowing for conformable store tank. This work serves to review the state-of-the-art development reported in the scientific literature on adsorbents, adsorption theories, ANG conformable tanks, and related technologies on ANG vehicles. Patent literature has also been searched and discussed. The review aims at illustrating both achievements and problems of the ANG technologies-based vehicles, as well as forecasting the development trends and critical issues to be resolved of these technologies.

Key wordsadsorbed natural gas (ANG)    adsorbent    adsorption theory    conformable tank    natural gas vehicles (NGVs)
收稿日期: 2015-11-03      出版日期: 2016-08-31
Corresponding Author(s): Yuyi LIN   
 引用本文:   
. [J]. Frontiers of Mechanical Engineering, 2016, 11(3): 258-274.
Zhengwei NIE, Yuyi LIN, Xiaoyi JIN. Research on the theory and application of adsorbed natural gas used in new energy vehicles: A review. Front. Mech. Eng., 2016, 11(3): 258-274.
 链接本文:  
https://academic.hep.com.cn/fme/CN/10.1007/s11465-016-0381-2
https://academic.hep.com.cn/fme/CN/Y2016/V11/I3/258
Fig.1  
Institution Raw materials Activator Specific surface area/(m2?g)
Harry Mash, UK Petroleum coke, charcoal KOH 2700
Amoco, US [16] Activated carbon KOH 3000
University of Missouri-Columbia, US [1820] Activated carbon KOH 3500
Kawasaki Steel, Japan [17] Carbon microspheres KOH 2145
University of Petroleum of China, China Lignin, petroleum coke 2912, 2399
Shanxi Institute of Coal Chemistry, China Petroleum coke 3882
South China University of Technology, China PVC 3191
Beijing University of Chemical Technology, China Activator 2966
Tab.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
Fig.9  
Type Methane capacity/(mg?g?1) Reference
5A 50 [47]
13X 53 [47]
Na-ZSM-5 31 [48]
Silicalite 44 [49]
NaX 66 [46]
MgX 66 [46]
CaX 82 [46]
SrX 62 [46]
BaX 67 [46]
NaY 56 [50]
MgY 62 [50]
CaY 63 [50]
SrY 61 [50]
BaY 54 [50]
Tab.2  
Fig.10  
Project Years Investigation method Pressure/MPa Tank uptake/(V?V?1) Tank delivery V/V to engine Adsorbent price Vessel (tank) design features
Atlanta Gas Light Adsorbent Research Group (AGLARG) 1990?1999 Chrysler B-van, Dodge Dakota Truck 3.5?4.0 150 in laboratory condition 142 Prohibitive Multicell of extruded aluminum
EU FPS LEVINGS program (FIAT) 1997?2000 FIAT Marea, on-board, field testing 3.5?4.0 123 107 High, but about 10 times less than AGLARG Multicell of steel tubes
Oak Ridge National Laboratory (ORNL) To 2000 Laboratory investigations 3.5 150 Not relevant Supposedly very high Small laboratory vessel of volume 0.05 L
Honda Motors Since 2000 Tank development adsorbent laboratory tests 3.5 155 ? Supposedly similar to AGLAG Multicell
University of Petroleum China (UPC) 1994?1995 Car XIALI 713IU on-board, field testing 5.0 100?110 Unknown Unknown Unknown
University of Petroleum China (UPC) 1994?1995 Car XIALI 713IU on-board, field testing 12.5 170?180 Unknown Unknown Unknown
ALL-CRAFT (University of Missouri) Since 2007 Laboratory investigation, adsorbent optimization, field testing 3.5 Intragranular, capability: 202 V/V; monolith capability: 161 V/V ? To be determined Cylindrical tank (2007) flat tank (2012) 3rd generation ANG tank (201x)
ALL-CRAFT (University of Missouri) Since 2007 Laboratory investigation, adsorbent optimization, field testing 25.0 Intragranular, capability: 337 V/V; monolith capability: To be determined ? To be determined Cylindrical tank (2007) flat tank (2012) 3rd generation ANG tank (201x)
Brazilian Gas Technology Center (CTGAS) Since 2000 Laboratory investigation on full-size prototype 3.5?4.0 130?150 Unknown Unknown Cylindrical from with volume 30 L
Tab.3  
Fig.11  
Fig.12  
Fig.13  
Adsorbent Pore shape Theoretical methane capacity/(mg?g−1) Pore size/Å Reference
Carbon (AX-21) Slit 221 12.60 [70]
Triangular 157 [70]
Carbon (274 K) Slit 187 11.43 [73]
Carbon (298 K) Slit 139 11.43 [74]
Carbon (300 K) Slit 168 [75]
Triangular 85 [75]
Carbon (274 K) Slit 166 11.43 [68]
Tab.4  
Fig.14  
Fig.15  
Fig.16  
Fig.17  
Fig.18  
Fig.19  
Fig.20  
Fig.21  
Fig.22  
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