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Frontiers of Materials Science

ISSN 2095-025X

ISSN 2095-0268(Online)

CN 11-5985/TB

邮发代号 80-974

2019 Impact Factor: 1.747

Frontiers of Materials Science  2012, Vol. 6 Issue (1): 69-78   https://doi.org/10.1007/s11706-012-0158-4
  RESEARCH ARTICLE 本期目录
Electrical and non-linear optical studies on electrospun ZnO/BaO composite nanofibers
Electrical and non-linear optical studies on electrospun ZnO/BaO composite nanofibers
G. NIXON SAMUEL VIJAYAKUMAR1,2, M. RATHNAKUMARI2, P. SURESHKUMAR2()
1. Department of Physics, R. M. K. Engineering College, R. S. M. Nagar, Kavaraipettai 601 206, India; 2. Materials Research Centre, Department of Physics, Velammal Engineering College, Chennai 600 066, India
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Abstract

Nanocapacitors and nonvolatile ferroelectric random access memories require nanoscale thin film coatings with ferroelectric properties. One dimensional ferroelectric nanofibers are used in ferroelectric memory devices owing to the fact that decrease of the dimensionality of the memory device elements will reduce the addressing and appreciably increase the storage capacity. Novel ZnO/BaO nanocomposite fibers exhibiting ferroelectric properties have been prepared in the form of non-woven mesh by electrospinning the sol derived from the sol-gel route. Thin cylindrical nanofibers of average diameter 100 nm have been obtained and their morphology is confirmed by SEM and AFM images. In the electrospinning process, the effect of the working distance on the fiber morphology was studied and it showed that working distance between 11 and 15 cm can produce fibers without beads and the decrease in working distance in this range increases the fiber diameter. Powder XRD was used to identify the phases and EDX analysis confirmed the presence of ZnO/BaO. Dielectric and non-linear optical properties have also been studied. The dielectric studies showed that ZnO/BaO composite nanofibers undergo a phase transition from ferroelectric to paraelectric at 323 K.

Key wordsnanocomposite fiber    sol-gel process    dielectric property    non-linear optical property    ferroelectric property
收稿日期: 2011-09-28      出版日期: 2012-03-05
Corresponding Author(s): SURESHKUMAR P.,Email:suresrath@ymail.com   
 引用本文:   
. Electrical and non-linear optical studies on electrospun ZnO/BaO composite nanofibers[J]. Frontiers of Materials Science, 2012, 6(1): 69-78.
G. NIXON SAMUEL VIJAYAKUMAR, M. RATHNAKUMARI, P. SURESHKUMAR. Electrical and non-linear optical studies on electrospun ZnO/BaO composite nanofibers. Front Mater Sci, 2012, 6(1): 69-78.
 链接本文:  
https://academic.hep.com.cn/foms/CN/10.1007/s11706-012-0158-4
https://academic.hep.com.cn/foms/CN/Y2012/V6/I1/69
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Electrospinning parametersOptimized values
Applied voltage18 kV
Distance between electrodes15 cm
Size of the needle opening25 G
Conductivity of the sol18.7 mS/cm
Temperature of the sol303 K
Viscosity of the sol1.23 Pa·s
Calcining temperature1123 K
Time of calcining8 h
Average diameter of fibers after calcining100 nm
Tab.1  
Fig.6  
Fig.7  
Fig.8  
Fig.9  
Fig.10  
Fig.11  
Fig.12  
Fig.13  
Fig.14  
Fig.15  
Fig.16  
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