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Frontiers of Materials Science

ISSN 2095-025X

ISSN 2095-0268(Online)

CN 11-5985/TB

邮发代号 80-974

2019 Impact Factor: 1.747

Frontiers of Materials Science  2012, Vol. 6 Issue (4): 319-325   https://doi.org/10.1007/s11706-012-0183-3
  RESEARCH ARTICLE 本期目录
Bulk scale production of carbon nanofibers in an economical way
Bulk scale production of carbon nanofibers in an economical way
Ravindra RAJARAO, Badekai Ramachandra BHAT()
Catalysis and Materials Laboratory, Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Mangalore-575 025, India
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Abstract

An economical route for the scalable production of carbon nanofibers (CNFs) on a sodium chloride support has been developed. CNFs have been synthesized by chemical vapor deposition (CVD) method by using metal formate as catalyst precursors at 680°C. Products were characterized by SEM, TEM, Raman spectroscopy and XRD method. By thermal analysis, the purity of the as grown products and purified products were determined. This method avoids calcination and reduction process which was employed in commercial catalysts such as metal oxide or nitrate. The problems such as detrimental effect, environmental and even cost have been overcome by using sodium chloride as support. The yield of CNFs up to 7800 wt.% relative to the nickel catalyst has been achieved in the growth time of 15 min. The advantage of this synthesis technique is the simplicity and use of easily available low cost precursors.

Key wordsmetal formate    carbon nanofiber (CNF)    chemical vapor deposition (CVD)    high yield    sodium chloride support    environmental friendly route
收稿日期: 2012-06-06      出版日期: 2012-12-05
Corresponding Author(s): BHAT Badekai Ramachandra,Email:chandpoorna@yahoo.com   
 引用本文:   
. Bulk scale production of carbon nanofibers in an economical way[J]. Frontiers of Materials Science, 2012, 6(4): 319-325.
Ravindra RAJARAO, Badekai Ramachandra BHAT. Bulk scale production of carbon nanofibers in an economical way. Front Mater Sci, 2012, 6(4): 319-325.
 链接本文:  
https://academic.hep.com.cn/foms/CN/10.1007/s11706-012-0183-3
https://academic.hep.com.cn/foms/CN/Y2012/V6/I4/319
Catalyst precursorContent of metal in support /wt.%Gas flow rate /(mL·min-1)Temperature /°CYield /%Morphology of CNFs
C2H2Ar
Nickel formate3202006807800straight, ID/IG = 1.05
Cobalt formate3202006807200curved, ID/IG = 1.04
Iron formate3202006806700worm-shaped, ID/IG = 1.10
Tab.1  
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