Honeycomb-like polyaniline for flexible and folding all-solid-state supercapacitors
Ge JU1, Muhammad Arif KHAN2, Huiwen ZHENG1, Zhongxun AN3, Mingxia WU3, Hongbin ZHAO1(), Jiaqiang XU1(), Lei ZHANG4, Salma BILAL5, Jiujun ZHANG1,6
1. NEST Lab, Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China 2. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China 3. National Engineering Research Center for Supercapacitor for Vehicles, Shanghai AOWEI Technology Development Co., Ltd., Shanghai 201203, China 4. Institute for Fuel Cell Innovation, National Research Council of Canada, 4250 Wesbrook Mall, Vancouver, Canada 5. National Centre of Excellence in Physical Chemistry, University of Peshawar, 25120 Peshawar, Pakistan 6. Institute of Sustainable Energy, Shanghai University, Shanghai 200444, China
Porous polyaniline (PANI) was prepared through an efficient and cost-effective method by polymerization of aniline in the NaCl solution at room temperature. The resulting PANI provided large surface area due to its highly porous structure and the intercrossed nanorod, resulting in good electrochemical performance. The porous PANI electrodes showed a high specific capacitance of 480 F∙g−1, 3 times greater than that of PANI without using the NaCl solution. We also make chemically crosslinked hydrogel film for hydrogel polymer electrolyte as well as the flexible supercapacitors (SCs) with PANI. The specific capacitance of the device was 234 F∙g−1 at the current density of 1 A∙g−1. The energy density of the device could reach as high as 75 W∙h∙kg−1 while the power density was 0.5 kW∙kg−1, indicating that PANI be a promising material in flexible SCs.
. [J]. Frontiers of Materials Science, 2019, 13(2): 133-144.
Ge JU, Muhammad Arif KHAN, Huiwen ZHENG, Zhongxun AN, Mingxia WU, Hongbin ZHAO, Jiaqiang XU, Lei ZHANG, Salma BILAL, Jiujun ZHANG. Honeycomb-like polyaniline for flexible and folding all-solid-state supercapacitors. Front. Mater. Sci., 2019, 13(2): 133-144.
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