1. School of Environmental and Materials Engineering, Yantai University, Yantai 264405, China 2. Shandong Key Laboratory of Optical Communication Science and Technology, School of Physics Science and Information Technology, Liaocheng University, Liaocheng 252000, China
Development of porous materials with anti-fouling and remote control- lability is highly desired for oil–water separation application yet still challenging. Herein, to address this challenge, a sponge with unusual superhydrophilicity/superoleophobicity and magnetic property was fabricated through a dip-coating process. To exploit its superhydrophilic/superoleophobic property, the obtained sponge was used as a reusable water sorbent scaffold to collect water from bulk oils without absorbing any oil. Owing to its magnetic property, the sponge was manipulated remotely by a magnet without touching it directly during the whole water collection process, which could potentially lower the cost of the water collection process. Apart from acting as a water-absorbing material, the sponge can also be used as affiliation material to separate water from oil–water mixture and oil in water emulsion selectively, when fixed into a cone funnel. This research provides a key addition to the field of oil–water separation materials.
B Wang, W Liang, Z Guo, et al.. Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature. Chemical Society Reviews, 2015, 44(1): 336–361 https://doi.org/10.1039/C4CS00220B
pmid: 25311259
3
J Ge, H Y Zhao, H W Zhu, et al.. Advanced sorbents for oil-spill cleanup: recent advances and future perspectives. Advanced Materials, 2016, 28(47): 10459–10490 https://doi.org/10.1002/adma.201601812
pmid: 27731513
4
A B Nordvik, J L Simmons, K R Bitting, et al.. Oil and water separation in marine oil spill clean-up operations. Spill Science & Technology Bulletin, 1996, 3(3): 107–122 https://doi.org/10.1016/S1353-2561(96)00021-7
5
Z Chu, Y Feng, S Seeger. Oil/water separation with selective superantiwetting/superwetting surface materials. Angewandte Chemie International Edition, 2015, 54(8): 2328–2338 https://doi.org/10.1002/anie.201405785
pmid: 25425089
6
Y B Peng, Z G Guo. Recent advances in biomimetic thin membranes applied in emulsified oil/water separation. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2016, 4(41): 15749–15770 https://doi.org/10.1039/C6TA06922C
7
Q Ma, H Cheng, A G Fane, et al.. Recent development of advanced materials with special wettability for selective oil/water separation. Small, 2016, 12(16): 2186–2202 https://doi.org/10.1002/smll.201503685
pmid: 27000640
X Zhu, Z Zhang, B Ge, et al.. A versatile approach to produce superhydrophobic materials used for oil–water separation. Journal of Colloid and Interface Science, 2014, 432: 105–108 https://doi.org/10.1016/j.jcis.2014.06.056
pmid: 25086383
10
J Li, R Kang, Y Zhang, et al.. Facile fabrication of superhydrophobic meshes with different water adhesion and their influence on oil/water separation. RSC Advances, 2016, 6(93): 90824–90830 https://doi.org/10.1039/C6RA17153B
11
G Ren, Y Song, X Li, et al.. A superhydrophobic copper mesh as an advanced platform for oil–water separation. Applied Surface Science, 2018, 428: 520–525 https://doi.org/10.1016/j.apsusc.2017.09.140
12
H Guan, Z Cheng, X Wang. Highly compressible wood sponges with a spring-like lamellar structure as effective and reusable oil absorbents. ACS Nano, 2018, 12(10): 10365–10373 https://doi.org/10.1021/acsnano.8b05763
pmid: 30272949
13
T L Yu, S X Lu, W G Xu. A reliable filter for oil–water separation: Bismuth coated superhydrophobic/superoleophilic iron mesh. Journal of Alloys and Compounds, 2018, 769: 576–587 https://doi.org/10.1016/j.jallcom.2018.07.305
14
Z Xue, S Wang, L Lin, et al.. A novel superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation. Advanced Materials, 2011, 23(37): 4270–4273 https://doi.org/10.1002/adma.201102616
pmid: 22039595
15
A K Kota, G Kwon, W Choi, et al.. Hygro-responsive membranes for effective oil–water separation. Nature Communications, 2012, 3(1): 1025 https://doi.org/10.1038/ncomms2027
pmid: 22929782
16
K He, H Duan, G Y Chen, et al.. Cleaning of oil fouling with water enabled by zwitterionic polyelectrolyte coatings: overcoming the imperative challenge of oil–water separation membranes. ACS Nano, 2015, 9(9): 9188–9198 https://doi.org/10.1021/acsnano.5b03791
pmid: 26260326
17
R Yang, P Moni, K K Gleason. Ultrathin zwitter ionic coatings for roughness-independent underwater superoleophobicity and gravity-driven oil–water separation. Advanced Materials Interfaces, 2015, 2(2): 1400489 https://doi.org/10.1002/admi.201400489
18
S Gao, J Sun, P Liu, et al.. A robust polyionized hydrogel with an unprecedented underwater anti-crude-oil-adhesion property. Advanced Materials, 2016, 28(26): 5307–5314 https://doi.org/10.1002/adma.201600417
pmid: 27159880
19
S Zhang, G Jiang, S Gao, et al.. Cupric phosphate nanosheets-wrapped inorganic membranes with superhydrophilic and outstanding anticrude oil-fouling property for oil/water separation. ACS Nano, 2018, 12(1): 795–803 https://doi.org/10.1021/acsnano.7b08121
pmid: 29298377
20
H C Yang, Y Xie, H Chan, et al.. Crude-oil-repellent membranes by atomic layer deposition: oxide interface engineering. ACS Nano, 2018, 12(8): 8678–8685 https://doi.org/10.1021/acsnano.8b04632
pmid: 30107114
21
R N Wenzel. Resistance of solid surfaces to wetting by water. Industrial & Engineering Chemistry, 1936, 28(8): 988–994 https://doi.org/10.1021/ie50320a024
22
Y C Jung, B Bhushan. Wetting behavior of water and oil droplets in three-phase interfaces for hydrophobicity/philicity and oleophobicity/philicity. Langmuir, 2009, 25(24): 14165–14173 https://doi.org/10.1021/la901906h
pmid: 19637877
23
J Yang, Z Zhang, X Xu, et al.. Superhydrophilic–superoleophobic coatings. Journal of Materials Chemistry, 2012, 22(7): 2834– 2837 https://doi.org/10.1039/c2jm15987b
24
Z Xu, Y Zhao, H Wang, et al.. A superamphiphobic coating with an ammonia-triggered transition to superhydrophilic and superoleophobic for oil–water separation. Angewandte Chemie International Edition, 2015, 54(15): 4527–4530 https://doi.org/10.1002/anie.201411283
pmid: 25694216
25
Q Zhu, F Tao, Q Pan. Fast and selective removal of oils from water surface via highly hydrophobic core–shell Fe2O3@C nanoparticles under magnetic field. ACS Applied Materials & Interfaces, 2010, 2(11): 3141–3146 https://doi.org/10.1021/am1006194
pmid: 20942429
26
P Calcagnile, D Fragouli, I S Bayer, et al.. Magnetically driven floating foams for the removal of oil contaminants from water. ACS Nano, 2012, 6(6): 5413–5419 https://doi.org/10.1021/nn3012948
pmid: 22577733
27
N Chen, Q Pan. Versatile fabrication of ultralight magnetic foams and application for oil–water separation. ACS Nano, 2013, 7(8): 6875–6883 https://doi.org/10.1021/nn4020533
pmid: 23875978
D Owens, R Wendt. Estimation of the surface free energy of polymers. Journal of Applied Polymer Science, 1969, 13(8): 1741–1747 https://doi.org/10.1002/app.1969.070130815
30
Y Wang, J Di, L Wang, et al.. Infused-liquid-switchable porous nanofibrous membranes for multiphase liquid separation. Nature Communications, 2017, 8(1): 575 https://doi.org/10.1038/s41467-017-00474-y