1. College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China 2. Department of Chemistry and the Tsinghua Center for Frontier Polymer Research, Tsinghua University, Beijing 100084, China
The unique feather-like arrays composing of ultrathin secondary nanowires are fabricated on nickel foam (NF) through a facile hydrothermal strategy. Thus, the enhancement of electrochemical properties especially the low charge transfer resistance strongly depends on more active sites and porosity of the morphology. Benefiting from the unique structure, the optimized NiCo2O4 electrode delivers a significantly lower charge transfer resistance of 0.32 Ω and a high specific capacitance of 450 F·g−1 at 0.5 A·g−1, as well as a superior cycling stability of 139.6% capacitance retention. The improvement of the electrochemical energy storage property proves the potential of the fabrication of various binary metal oxide electrodes for applications in the electrochemical energy field.
X H Lu, M H Yu, G M Wang, et al.. Flexible solid-state supercapacitors: design, fabrication and applications. Energy & Environmental Science, 2014, 7(7): 2160–2181 https://doi.org/10.1039/c4ee00960f
2
K Yuan, D Lützenkirchen-Hecht, L Li, et al.. Boosting oxygen reduction of single iron active sites via geometric and electronic engineering: nitrogen and phosphorus dual coordination. Journal of the American Chemical Society, 2020, 142(5): 2404–2412 https://doi.org/10.1021/jacs.9b11852
pmid: 31902210
3
P Simon, Y Gogotsi. Capacitive energy storage in nanostructured carbon-electrolyte systems. Accounts of Chemical Research, 2013, 46(5): 1094–1103 https://doi.org/10.1021/ar200306b
pmid: 22670843
4
K Zou, P Cai, C Liu, et al.. A kinetically well-matched full-carbon sodium-ion capacitor. Journal of Materials Chemistry, 2019, 7(22): 13540–13549 https://doi.org/10.1039/C9TA03797G
5
X Yun, S Wu, J Li, et al.. Facile synthesis of crystalline RuSe2 nanoparticles as a novel pseudocapacitive electrode material for supercapacitors. Chemical Communications, 2019, 55(82): 12320–12323 https://doi.org/10.1039/C9CC06023E
pmid: 31556438
6
X Luo, J Wang, M Dooner, et al.. Overview of current development in electrical energy storage technologies and the application potential in power system operation. Applied Energy, 2015, 137: 511–536 https://doi.org/10.1016/j.apenergy.2014.09.081
7
X Zhang, S Li, S A El-Khodary, et al.. Porous α-Fe2O3 nanoparticles encapsulated within reduced graphene oxide as superior anode for lithium-ion battery. Nanotechnology, 2020, 31(14): 145404 https://doi.org/10.1088/1361-6528/ab667d
pmid: 31891928
8
M Q Wang, Z Q Li, C X Wang, et al.. Novel core–shell FeOF/Ni(OH)2 hierarchical nanostructure for all-solid-state flexible supercapacitors with enhanced performance. Advanced Functional Materials, 2017, 27(31): 1701014–1701027 https://doi.org/10.1002/adfm.201701014
9
S A El-Khodary, G M El-Enany, M El-Okr, et al.. Modified iron doped polyaniline/sulfonated carbon nanotubes for all symmetric solid-state supercapacitor. Synthetic Metals, 2017, 233: 41–51 https://doi.org/10.1016/j.synthmet.2017.09.002
10
S B Kale, A C Lokhande, R B Pujari, et al.. Cobalt sulfide thin films for electrocatalytic oxygen evolution reaction and supercapacitor applications. Journal of Colloid and Interface Science, 2018, 532: 491–499 https://doi.org/10.1016/j.jcis.2018.08.012
pmid: 30103132
11
B L Vijayan, S G Krishnan, N K Zain, et al.. Large scale synthesis of binary composite nanowires in the Mn2O3–SnO2 system with improved charge storage capabilities. Chemical Engineering Journal, 2017, 327: 962–972 https://doi.org/10.1016/j.cej.2017.06.171
12
Y Y Chen, Y Wang, X P Shen, et al.. Cyanide-metal framework derived CoMoO4/Co3O4 hollow porous octahedrons as advanced anodes for high performance lithium ion batteries. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(3): 1048–1056 https://doi.org/10.1039/C7TA08868J
13
Y Y Chen, R Cai, Y Yang, et al.. Cyanometallic frameworks derived hierarchical porous Fe2O3/NiO microflowers with excellent lithium-storage property. Journal of Alloys and Compounds, 2017, 698: 469–475 https://doi.org/10.1016/j.jallcom.2016.12.230
14
X H Xia, J P Tu, Y J Mai, et al.. Self-supported hydrothermal synthesized hollow Co3O4 nanowire arrays with high supercapacitor capacitance. Journal of Materials Chemistry, 2011, 21(25): 9319–9325 https://doi.org/10.1039/c1jm10946d
15
G X Zhang, X Xiao, B Li, et al.. Transition metal oxides with one-dimensional/one-dimensional-analogue nanostructures for advanced supercapacitors. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2017, 5(18): 8155–8186 https://doi.org/10.1039/C7TA02454A
16
S K Meher, G R Rao. Ultralayered Co3O4 for high-performance supercapacitor applications. The Journal of Physical Chemistry C, 2011, 115(31): 15646–15654 https://doi.org/10.1021/jp201200e
17
J P Wang, H Zhou, M Z Zhu, et al.. Metal-organic framework derived Co3O4 covered by MoS2 nanosheets for high-performance lithium-ion batteries. Journal of Alloys and Compounds, 2018, 744: 220–227 https://doi.org/10.1016/j.jallcom.2018.02.086
18
X J Zhang, W H Shi, J X Zhu, et al.. Synthesis of porous NiO nanocrystals with controllable surface area and their application as supercapacitor electrodes. Nano Research, 2010, 3(9): 643–652 https://doi.org/10.1007/s12274-010-0024-6
19
C Y Cao, W Guo, Z M Cui, et al.. Microwave-assisted gas/liquid interfacial synthesis of flowerlike NiO hollow nanosphere precursors and their application as supercapacitor electrodes. Journal of Materials Chemistry, 2011, 21(9): 3204–3209 https://doi.org/10.1039/c0jm03749d
20
Z Wu, Y Zhu, X Ji. NiCo2O4-based materials for electrochemical supercapacitors. Journal of Materials Chemistry, 2014, 2(36): 14759–14772 https://doi.org/10.1039/C4TA02390K
21
W Li, F Yang, Z Hu, et al.. Template synthesis of C@NiCo2O4 hollow microsphere as electrode material for supercapacitor. Journal of Alloys and Compounds, 2018, 749: 305–312 https://doi.org/10.1016/j.jallcom.2018.03.046
22
Z Wang, Z Zhu, C Zhang, et al.. Facile synthesis of reduced graphene oxide/NiMn2O4 nanorods hybrid materials for high-performance supercapacitors. Electrochimica Acta, 2017, 230: 438–444 https://doi.org/10.1016/j.electacta.2017.02.023
23
H Wei, J Wang, L Yu, et al.. Facile synthesis of NiMn2O4 nanosheetarrays grown on nickel foam as novel electrode materials for high-performance supercapacitors. Ceramics International, 2016, 42(13): 14963–14969 https://doi.org/10.1016/j.ceramint.2016.06.140
24
G Wei, J He, W Zhang, et al.. Rational design of Co(II) dominant and oxygen vacancy defective CuCo2O4@CQDs hollow spheres for enhanced overall water splitting and supercapacitor performance. Inorganic Chemistry, 2018, 57(12): 7380–7389 https://doi.org/10.1021/acs.inorgchem.8b01020
pmid: 29799201
25
G Y Huang, Y Yang, H Y Sun, et al.. Defective ZnCo2O4 with Zn vacancies: synthesis, property and electrochemical application. Journal of Alloys and Compounds, 2017, 724: 1149–1156 https://doi.org/10.1016/j.jallcom.2017.07.136
26
K Qiu, M Lu, Y Luo, et al.. Engineering hierarchical nanotrees with CuCo2O4 trunks and NiO branches for high-performance supercapacitors. Journal of Materials Chemistry, 2017, 5(12): 5820–5828 https://doi.org/10.1039/C7TA00506G
27
Y Luo, H Zhang, D Guo, et al.. Porous NiCo2O4–reduced graphene oxide (rGO) composite with superior capacitance retention for supercapacitors. Electrochimica Acta, 2014, 132: 332–337 https://doi.org/10.1016/j.electacta.2014.03.179
28
R B Waghmode, A P Torane. Hierarchical 3D NiCo2O4, nanoflowers as electrode materials for high performance supercapacitors. Journal of Materials Science: Materials in Electronics, 2016, 27(6): 6133–6139 https://doi.org/10.1007/s10854-016-4540-3
29
X Qi, W Zheng, G He, et al.. NiCo2O4 hollow microspheres with tunable numbers and thickness of shell for supercapacitors. Chemical Engineering Journal, 2017, 309: 426–434 https://doi.org/10.1016/j.cej.2016.10.060
30
L Li, S Peng, Y Cheah, et al.. Electrospun porous NiCo2O4 nanotubes as advanced electrodes for electrochemical capacitors. Chemistry, 2013, 19(19): 5892–5898 https://doi.org/10.1002/chem.201204153
pmid: 23494864
31
Z Wu, Y Zhu, X Ji. NiCo2O4-based materials for electrochemical supercapacitors. Journal of Materials Chemistry, 2014, 2(36): 14759–14772 https://doi.org/10.1039/C4TA02390K
32
Y Lei, Y Y Wang, W Yang, et al.. Self-assembled hollow urchin-like NiCo2O4 microspheres for aqueous asymmetric supercapacitors. RSC Advances, 2015, 5(10): 7575–7583 https://doi.org/10.1039/C4RA15097J
33
T V Nguyen, L T Son, V V Thuy, et al.. Facile synthesis of Mn-doped NiCo2O4 nanoparticles with enhanced electrochemical performance for a battery-type supercapacitor electrode. Dalton Transactions, 2020, 49(20): 6718–6729 https://doi.org/10.1039/D0DT01177K
pmid: 32369071
34
Q Li, C Lu, C Chen, et al.. Layered NiCo2O4/reduced graphene oxide composite as an advanced electrode for supercapacitor. Energy Storage Materials, 2017, 8: 59–67 https://doi.org/10.1016/j.ensm.2017.04.002
35
K Zou, P Cai, C Liu, et al.. A kinetically well-matched full-carbon sodium-ion capacitor. Journal of Materials Chemistry, 2019, 7(22): 13540–13549 https://doi.org/10.1039/C9TA03797G
36
X F Yang, A Wang, B Qiao, et al.. Single-atom catalysts: a new frontier in heterogeneous catalysis. Accounts of Chemical Research, 2013, 46(8): 1740–1748 https://doi.org/10.1021/ar300361m
pmid: 23815772
37
J Li, S Xiong, Y Liu, et al.. High electrochemical performance of monodisperse NiCo2O4 mesoporous microspheres as an anode material for Li-ion batteries. ACS Applied Materials & Interfaces, 2013, 5(3): 981–988 https://doi.org/10.1021/am3026294
pmid: 23323836
38
H Wang, Y Gong, D Li, et al.. NiCo2O4 bricks as anode materials with high lithium storage property. MRS Advances, 2019, 4(33–34): 1861–1868 https://doi.org/10.1557/adv.2019.169