Please wait a minute...
Frontiers of Materials Science

ISSN 2095-025X

ISSN 2095-0268(Online)

CN 11-5985/TB

邮发代号 80-974

2019 Impact Factor: 1.747

Frontiers of Materials Science  2020, Vol. 14 Issue (4): 450-458   https://doi.org/10.1007/s11706-020-0528-2
  本期目录
Feather-like NiCo2O4 self-assemble from porous nanowires as binder-free electrodes for low charge transfer resistance
Dandan HAN1(), Jinhe WEI1, Shanshan WANG1, Yifan PAN1, Junli XUE1, Yen WEI2()
1. College of Chemistry and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China
2. Department of Chemistry and the Tsinghua Center for Frontier Polymer Research, Tsinghua University, Beijing 100084, China
 全文: PDF(2834 KB)   HTML
Abstract

The unique feather-like arrays composing of ultrathin secondary nanowires are fabricated on nickel foam (NF) through a facile hydrothermal strategy. Thus, the enhancement of electrochemical properties especially the low charge transfer resistance strongly depends on more active sites and porosity of the morphology. Benefiting from the unique structure, the optimized NiCo2O4 electrode delivers a significantly lower charge transfer resistance of 0.32 Ω and a high specific capacitance of 450 F·g−1 at 0.5 A·g−1, as well as a superior cycling stability of 139.6% capacitance retention. The improvement of the electrochemical energy storage property proves the potential of the fabrication of various binary metal oxide electrodes for applications in the electrochemical energy field.

Key wordsfeather-like NiCo2O4    binder-free electrode    charge transfer resistance    supercapacitor
收稿日期: 2020-07-27      出版日期: 2020-12-09
Corresponding Author(s): Dandan HAN,Yen WEI   
 引用本文:   
. [J]. Frontiers of Materials Science, 2020, 14(4): 450-458.
Dandan HAN, Jinhe WEI, Shanshan WANG, Yifan PAN, Junli XUE, Yen WEI. Feather-like NiCo2O4 self-assemble from porous nanowires as binder-free electrodes for low charge transfer resistance. Front. Mater. Sci., 2020, 14(4): 450-458.
 链接本文:  
https://academic.hep.com.cn/foms/CN/10.1007/s11706-020-0528-2
https://academic.hep.com.cn/foms/CN/Y2020/V14/I4/450
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
  
  
  
1 X H Lu, M H Yu, G M Wang, et al.. Flexible solid-state supercapacitors: design, fabrication and applications. Energy & Environmental Science, 2014, 7(7): 2160–2181
https://doi.org/10.1039/c4ee00960f
2 K Yuan, D Lützenkirchen-Hecht, L Li, et al.. Boosting oxygen reduction of single iron active sites via geometric and electronic engineering: nitrogen and phosphorus dual coordination. Journal of the American Chemical Society, 2020, 142(5): 2404–2412
https://doi.org/10.1021/jacs.9b11852 pmid: 31902210
3 P Simon, Y Gogotsi. Capacitive energy storage in nanostructured carbon-electrolyte systems. Accounts of Chemical Research, 2013, 46(5): 1094–1103
https://doi.org/10.1021/ar200306b pmid: 22670843
4 K Zou, P Cai, C Liu, et al.. A kinetically well-matched full-carbon sodium-ion capacitor. Journal of Materials Chemistry, 2019, 7(22): 13540–13549
https://doi.org/10.1039/C9TA03797G
5 X Yun, S Wu, J Li, et al.. Facile synthesis of crystalline RuSe2 nanoparticles as a novel pseudocapacitive electrode material for supercapacitors. Chemical Communications, 2019, 55(82): 12320–12323
https://doi.org/10.1039/C9CC06023E pmid: 31556438
6 X Luo, J Wang, M Dooner, et al.. Overview of current development in electrical energy storage technologies and the application potential in power system operation. Applied Energy, 2015, 137: 511–536
https://doi.org/10.1016/j.apenergy.2014.09.081
7 X Zhang, S Li, S A El-Khodary, et al.. Porous α-Fe2O3 nanoparticles encapsulated within reduced graphene oxide as superior anode for lithium-ion battery. Nanotechnology, 2020, 31(14): 145404
https://doi.org/10.1088/1361-6528/ab667d pmid: 31891928
8 M Q Wang, Z Q Li, C X Wang, et al.. Novel core–shell FeOF/Ni(OH)2 hierarchical nanostructure for all-solid-state flexible supercapacitors with enhanced performance. Advanced Functional Materials, 2017, 27(31): 1701014–1701027
https://doi.org/10.1002/adfm.201701014
9 S A El-Khodary, G M El-Enany, M El-Okr, et al.. Modified iron doped polyaniline/sulfonated carbon nanotubes for all symmetric solid-state supercapacitor. Synthetic Metals, 2017, 233: 41–51
https://doi.org/10.1016/j.synthmet.2017.09.002
10 S B Kale, A C Lokhande, R B Pujari, et al.. Cobalt sulfide thin films for electrocatalytic oxygen evolution reaction and supercapacitor applications. Journal of Colloid and Interface Science, 2018, 532: 491–499
https://doi.org/10.1016/j.jcis.2018.08.012 pmid: 30103132
11 B L Vijayan, S G Krishnan, N K Zain, et al.. Large scale synthesis of binary composite nanowires in the Mn2O3–SnO2 system with improved charge storage capabilities. Chemical Engineering Journal, 2017, 327: 962–972
https://doi.org/10.1016/j.cej.2017.06.171
12 Y Y Chen, Y Wang, X P Shen, et al.. Cyanide-metal framework derived CoMoO4/Co3O4 hollow porous octahedrons as advanced anodes for high performance lithium ion batteries. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(3): 1048–1056
https://doi.org/10.1039/C7TA08868J
13 Y Y Chen, R Cai, Y Yang, et al.. Cyanometallic frameworks derived hierarchical porous Fe2O3/NiO microflowers with excellent lithium-storage property. Journal of Alloys and Compounds, 2017, 698: 469–475
https://doi.org/10.1016/j.jallcom.2016.12.230
14 X H Xia, J P Tu, Y J Mai, et al.. Self-supported hydrothermal synthesized hollow Co3O4 nanowire arrays with high supercapacitor capacitance. Journal of Materials Chemistry, 2011, 21(25): 9319–9325
https://doi.org/10.1039/c1jm10946d
15 G X Zhang, X Xiao, B Li, et al.. Transition metal oxides with one-dimensional/one-dimensional-analogue nanostructures for advanced supercapacitors. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2017, 5(18): 8155–8186
https://doi.org/10.1039/C7TA02454A
16 S K Meher, G R Rao. Ultralayered Co3O4 for high-performance supercapacitor applications. The Journal of Physical Chemistry C, 2011, 115(31): 15646–15654
https://doi.org/10.1021/jp201200e
17 J P Wang, H Zhou, M Z Zhu, et al.. Metal-organic framework derived Co3O4 covered by MoS2 nanosheets for high-performance lithium-ion batteries. Journal of Alloys and Compounds, 2018, 744: 220–227
https://doi.org/10.1016/j.jallcom.2018.02.086
18 X J Zhang, W H Shi, J X Zhu, et al.. Synthesis of porous NiO nanocrystals with controllable surface area and their application as supercapacitor electrodes. Nano Research, 2010, 3(9): 643–652
https://doi.org/10.1007/s12274-010-0024-6
19 C Y Cao, W Guo, Z M Cui, et al.. Microwave-assisted gas/liquid interfacial synthesis of flowerlike NiO hollow nanosphere precursors and their application as supercapacitor electrodes. Journal of Materials Chemistry, 2011, 21(9): 3204–3209
https://doi.org/10.1039/c0jm03749d
20 Z Wu, Y Zhu, X Ji. NiCo2O4-based materials for electrochemical supercapacitors. Journal of Materials Chemistry, 2014, 2(36): 14759–14772
https://doi.org/10.1039/C4TA02390K
21 W Li, F Yang, Z Hu, et al.. Template synthesis of C@NiCo2O4 hollow microsphere as electrode material for supercapacitor. Journal of Alloys and Compounds, 2018, 749: 305–312
https://doi.org/10.1016/j.jallcom.2018.03.046
22 Z Wang, Z Zhu, C Zhang, et al.. Facile synthesis of reduced graphene oxide/NiMn2O4 nanorods hybrid materials for high-performance supercapacitors. Electrochimica Acta, 2017, 230: 438–444
https://doi.org/10.1016/j.electacta.2017.02.023
23 H Wei, J Wang, L Yu, et al.. Facile synthesis of NiMn2O4 nanosheetarrays grown on nickel foam as novel electrode materials for high-performance supercapacitors. Ceramics International, 2016, 42(13): 14963–14969
https://doi.org/10.1016/j.ceramint.2016.06.140
24 G Wei, J He, W Zhang, et al.. Rational design of Co(II) dominant and oxygen vacancy defective CuCo2O4@CQDs hollow spheres for enhanced overall water splitting and supercapacitor performance. Inorganic Chemistry, 2018, 57(12): 7380–7389
https://doi.org/10.1021/acs.inorgchem.8b01020 pmid: 29799201
25 G Y Huang, Y Yang, H Y Sun, et al.. Defective ZnCo2O4 with Zn vacancies: synthesis, property and electrochemical application. Journal of Alloys and Compounds, 2017, 724: 1149–1156
https://doi.org/10.1016/j.jallcom.2017.07.136
26 K Qiu, M Lu, Y Luo, et al.. Engineering hierarchical nanotrees with CuCo2O4 trunks and NiO branches for high-performance supercapacitors. Journal of Materials Chemistry, 2017, 5(12): 5820–5828
https://doi.org/10.1039/C7TA00506G
27 Y Luo, H Zhang, D Guo, et al.. Porous NiCo2O4–reduced graphene oxide (rGO) composite with superior capacitance retention for supercapacitors. Electrochimica Acta, 2014, 132: 332–337
https://doi.org/10.1016/j.electacta.2014.03.179
28 R B Waghmode, A P Torane. Hierarchical 3D NiCo2O4, nanoflowers as electrode materials for high performance supercapacitors. Journal of Materials Science: Materials in Electronics, 2016, 27(6): 6133–6139
https://doi.org/10.1007/s10854-016-4540-3
29 X Qi, W Zheng, G He, et al.. NiCo2O4 hollow microspheres with tunable numbers and thickness of shell for supercapacitors. Chemical Engineering Journal, 2017, 309: 426–434
https://doi.org/10.1016/j.cej.2016.10.060
30 L Li, S Peng, Y Cheah, et al.. Electrospun porous NiCo2O4 nanotubes as advanced electrodes for electrochemical capacitors. Chemistry, 2013, 19(19): 5892–5898
https://doi.org/10.1002/chem.201204153 pmid: 23494864
31 Z Wu, Y Zhu, X Ji. NiCo2O4-based materials for electrochemical supercapacitors. Journal of Materials Chemistry, 2014, 2(36): 14759–14772
https://doi.org/10.1039/C4TA02390K
32 Y Lei, Y Y Wang, W Yang, et al.. Self-assembled hollow urchin-like NiCo2O4 microspheres for aqueous asymmetric supercapacitors. RSC Advances, 2015, 5(10): 7575–7583
https://doi.org/10.1039/C4RA15097J
33 T V Nguyen, L T Son, V V Thuy, et al.. Facile synthesis of Mn-doped NiCo2O4 nanoparticles with enhanced electrochemical performance for a battery-type supercapacitor electrode. Dalton Transactions, 2020, 49(20): 6718–6729
https://doi.org/10.1039/D0DT01177K pmid: 32369071
34 Q Li, C Lu, C Chen, et al.. Layered NiCo2O4/reduced graphene oxide composite as an advanced electrode for supercapacitor. Energy Storage Materials, 2017, 8: 59–67
https://doi.org/10.1016/j.ensm.2017.04.002
35 K Zou, P Cai, C Liu, et al.. A kinetically well-matched full-carbon sodium-ion capacitor. Journal of Materials Chemistry, 2019, 7(22): 13540–13549
https://doi.org/10.1039/C9TA03797G
36 X F Yang, A Wang, B Qiao, et al.. Single-atom catalysts: a new frontier in heterogeneous catalysis. Accounts of Chemical Research, 2013, 46(8): 1740–1748
https://doi.org/10.1021/ar300361m pmid: 23815772
37 J Li, S Xiong, Y Liu, et al.. High electrochemical performance of monodisperse NiCo2O4 mesoporous microspheres as an anode material for Li-ion batteries. ACS Applied Materials & Interfaces, 2013, 5(3): 981–988
https://doi.org/10.1021/am3026294 pmid: 23323836
38 H Wang, Y Gong, D Li, et al.. NiCo2O4 bricks as anode materials with high lithium storage property. MRS Advances, 2019, 4(33–34): 1861–1868
https://doi.org/10.1557/adv.2019.169
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed