1. Engineering Research Center of Coal-based Ecological Carbon Sequestration Technology of the Ministry of Education, Shanxi Datong University, Datong 037009, China 2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
In situ carbon-coated Co3Se4/CoSe2 (CoxSey) nanoparticles (NPs) attached on three-dimensional (3D) reduced graphene oxide (rGO) sheets were skillfully developed in this work, which involved the environment-friendly hydrothermal method, freeze drying, and selenide calcination. Within the structure, the glucose-derived carbon layer exhibited significantly homogeneous dispersion under an argon environment. This structure not only has enhanced stability, but also can effectively mitigate the volume swell of CoxSey particles. The resulted Co3Se4/CoSe2@C/rGO (CSe@C/rGO) exhibited a specific surface area (SSA) of 240.9 m2·g−1, offering more electrochemically active sites for the storage of energy related to lithium ions. The rGO matrix held exceptional flexibility and functional structural rigidity, facilitating the swift ion intercalation and ensuring the high conductivity and recyclability of the structure. When applied to anodes designed for lithium-ion batteries (LIBs), this material demonstrated distinguished rate and ultra-high reversible capacity (872.98 mA·h·g−1 at 0.5 A·g−1). Meanwhile, its capacity retention reached 119.5% after 500 cycles at 2 A·g−1, with a coulombic efficiency of 100%. This work potentially paves the way for generating fast and powerful metal selenide anodes and initiating LIBs with good performance.
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J Q, Liu Z T, Ding Q M, Zhou et al.. 3D porous biomass derived carbon composite modified with (Ni, Co)Se particles for high-performance supercapacitors.Batteries & Supercaps, 2023, 6(11): e202300362 https://doi.org/10.1002/batt.202300362
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H B, Kong C, Lv Y S, Wu et al.. Integration of cobalt selenide nanocrystals with interlayer expanded 3D Se/N Co-doped carbon networks for superior sodium-ion storage.Journal of Energy Chemistry, 2021, 55: 169–175 https://doi.org/10.1016/j.jechem.2020.06.066
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Y Q, Wu X P, Jia H, Zhang et al.. Construction of double-shell Ni3Se4@Co3Se4 microsphere for hybrid Zn-based supercapacitor with superior rate and energy density.Journal of Energy Storage, 2023, 62: 106855 https://doi.org/10.1016/j.est.2023.106855
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L, Sun Y, Liu M, Yan et al.. ZIFs derived multiphase CoSe2 nanoboxes induced and fixed on CoAl-LDH nanoflowers for high-performance hybrid supercapacitor.Chemical Engineering Science, 2022, 252: 117241 https://doi.org/10.1016/j.ces.2021.117241
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W, Zhao W J, Feng J Z, Chen et al.. Polar Co3Se4 nitrogen-doped porous carbon derived from ZIF-67 for use as a sulfur substrates in high-performance lithium–sulfur batteries.Journal of Alloys and Compounds, 2022, 923: 166435 https://doi.org/10.1016/j.jallcom.2022.166435
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H, Liu S, Xiong L, Hou et al.. Reducing graphene oxide carbon skeleton supported p–n heterostructure of bimetallic sulfide CoS–MoS2 nanorods for high-performance lithium storage.Journal of Colloid and Interface Science, 2023, 630: 623–633 https://doi.org/10.1016/j.jcis.2022.09.067
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