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Frontiers of Physics

ISSN 2095-0462

ISSN 2095-0470(Online)

CN 11-5994/O4

邮发代号 80-965

2019 Impact Factor: 2.502

Frontiers of Physics  2023, Vol. 18 Issue (5): 53604   https://doi.org/10.1007/s11467-023-1290-6
  本期目录
Defect repairing in two-dimensional transition metal dichalcogenides
Shiyan Zeng, Fang Li, Chao Tan, Lei Yang, Zegao Wang()
College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China
 全文: PDF(10203 KB)   HTML
Abstract

Atomically thin two-dimensional (2D) transition metal dichalcogenides (TMDCs) have stimulated enormous research interest due to rich phase structure, high theoretical carrier mobility and layer-dependent bandgap. In view of the close correlation between defects and properties in 2D TMDCs, more attentions have been paid on the defect engineering in recent years, however the mechanism is still unclear. Herein, we review the critical progress of defect engineering and provide an extensive way to modulate the properties depressed by defects. To insight into the defect engineering, we firstly introduce two common kinds of defects during the growth progress of TMDCs and the possible distribution of energy levels those defects could induce. Then, various methods to improve point defects and grain boundaries during the period of growth are discussed intensively, with the assistance of which more large-area TMDCs films can be obtained. Considering the defects in TMDCs are inevitable regardless of concentration, we also highlight strategies to heal the defects after growth. Through dry methods or wet methods, the chalcogen vacancies can be repaired and thus, the performance of electronic device would be significantly enhanced. Finally, we propose the challenges and prospective for defect engineering in 2D TMDCs materials to support the optimization of device and lead them to wide applied fields.

Key wordsdefect    repairing    two-dimensional transition metal    dichalcogenides
收稿日期: 2023-02-13      出版日期: 2023-05-31
Corresponding Author(s): Zegao Wang   
 引用本文:   
. [J]. Frontiers of Physics, 2023, 18(5): 53604.
Shiyan Zeng, Fang Li, Chao Tan, Lei Yang, Zegao Wang. Defect repairing in two-dimensional transition metal dichalcogenides. Front. Phys. , 2023, 18(5): 53604.
 链接本文:  
https://academic.hep.com.cn/fop/CN/10.1007/s11467-023-1290-6
https://academic.hep.com.cn/fop/CN/Y2023/V18/I5/53604
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Defect typeRepair stagePropertiesRepairing methodRefs.
Sulfur vacanciesGrowth processN-type dopingIntroducing NaX[66]
Lower mobilityOxygen-assisted CVD[71]
Post-treatmentLower on/off current ratioN2, O2, H2 plasma treatment[100-102]
Annealing[105]
Weaker PL intensityTFSI treatment[110]
PSS treatment[119]
MPS treatment[120]
Selenium vacanciesGrowth processN-type dopingIntroducing other metallic oxide powder[70]
Post-treatmentWeaker PL intensityOxygen passivizationAnnealing[138][139]
HBr treatment[140]
Lower mobilityMPc treatment[135]
Grain boundariesGrowth processHigher domain density Small sizeSpace confinement effect[72]
Double-tube system with one-side sealed inner tube[73]
Lower mobility Lower on/off currentTwo-stage (induction and growth stage) CVD method[74]
Selection and pretreatment of the substrate and source[79-81]
Introducing catalysts and additives[88-99]
Post-treatment?
Tab.1  
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