Sensitivity analysis of the deterioration of concrete strength in marine environment to multiple corrosive ions
Jinwei YAO1,2, Jiankang CHEN2()
1. Zhejiang Business Technology Institute, Ningbo 315012, China 2. Key Laboratory of Impact and Safety Engineering, Ministry of Education, School of Mechanical Engineering and Mechanics, Ningbo University, Ningbo 315211, China
The corrosion degradation behavior of concrete materials plays a crucial role in the change of its mechanical properties under multi-ion interaction in the marine environment. In this study, the variation in the macro-physical and mechanical properties of concrete with corrosion time is investigated, and the source of micro-corrosion products under different salt solutions in seawater are analyzed. Regardless of the continuous hydration effect of concrete, the damage effects of various corrosive ions (Cl–, , and Mg2+, etc.) on the tensile and compressive strength of concrete are discussed based on measurement in different salt solutions. The sensitivity analysis method for concrete strength is used to quantitatively analyze the sensitivity of concrete strength to the effects of each ion in a multi-salt solution without considering the influence of continued hydration. The quantitative results indicate that the addition of Cl– can weaken the corrosion effect of by about 20%, while the addition of Mg2+ or Mg2+ and Cl– can strengthen it by 10%–20% during a 600-d corrosion process.
5–16 mm continuous gradation cumulative sieve residue (%)
2.36
45.3
97.00
95–100
4.75
460.5
92.47
85–100
9.50
425.7
46.42
30–60
16.0
38.5
3.85
0–10
19.0
0
0
0
Tab.3
type
water-cement ratio (w/c)
cement
water
sand
gravel
Ⅰ
0.33
22
7
21
50
Ⅱ
0.50
14
7
29
50
Tab.4
symbol
NaCl
Na2SO4
MgSO4
water
Q
0
0
0
100
L
10
0
0
90
S
0
5
0
95
M
0
0
5
95
SL
10
5
0
85
ML
10
0
5
85
Tab.5
Fig.2
Fig.3
Fig.4
normalized strength value
5% MgSO4 + 10% NaCl
5% Na2SO4 + 10% NaCl
5% MgSO4
5% Na2SO4
10% NaCl
water
B2
–2.821 × 10–6
–1.836 × 10–6
–2.356 × 10–6
–2.588 × 10–6
–1.649 × 10–6
–1.360 × 10–6
B1
1.331 × 10–3
1.436 × 10–3
1.460 × 10–3
1.581 × 10–3
1.3348 × 10–3
1.167 × 10–3
R2
0.862
0.968
0.788
0.989
0.952
0.938
Tab.6
normalized strength value
5% MgSO4 + 10% NaCl
5% Na2SO4 + 10% NaCl
5% MgSO4
5% Na2SO4
10% NaCl
water
B2
–2.054 × 10–6
–2.560 × 10–6
–2.234 × 10–6
–3.066 × 10–6
–1.901 × 10–6
–0.981 × 10–6
B1
1.113 × 10–3
1.932 × 10–3
1.370 × 10–3
1.862 × 10–3
1.532 × 10–3
0.925 × 10–3
R2
0.848
0.977
0.974
0.887
0.971
0.978
Tab.7
normalized strength value
5% MgSO4 + 10% NaCl
5% Na2SO4 + 10% NaCl
5% MgSO4
5% Na2SO4
10% NaCl
water
B2
–4.041 × 10–6
–3.869 × 10–6
–5.254 × 10–6
–5.083 × 10–6
–2.794 × 10–6
–2.764 × 10–6
B1
2.590 × 10–3
2.922 × 10–3
3.286 × 10–3
3.340 × 10–3
2.130 × 10–3
2.136 × 10–3
R2
0.937
0.965
0.911
0.658
0.846
0.840
Tab.8
normalized strength value
5% MgSO4 + 10% NaCl
5% Na2SO4 + 10% NaCl
5% MgSO4
5% Na2SO4
10% NaCl
water
B2
–3.017 × 10–6
–4.482 × 10–6
–2.400 × 10–6
–4.486 × 10–6
–1.778 × 10–6
–1.628 × 10–6
B1
1.719 × 10–3
2.905 × 10–3
1.435 × 10–3
2.546 × 10–3
1.443 × 10–3
1.324 × 10–3
R2
0.833
0.933
0.973
0.938
0.836
0.891
Tab.9
Fig.5
w/c
ML
SL
M
S
L
0.50
110
560
290
335
600
0.33
175
>600
355
450
>600
Tab.10
w/c
ML
SL
M
S
L
0.50
110
205
220
235
–
0.33
130
350
45
270
–
Tab.11
Fig.6
Fig.7
Fig.8
Fig.9
Fig.10
Fig.11
Fig.12
Fig.13
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