Emulsified asphalt is the primary material for preventive maintenance and cold-mix paving, but its low cohesive strength and poor mechanical properties limit its wide application, even with polymer modification. In this study, Styrene-Butadiene Rubber (SBR) emulsified asphalt was modified with nano-cellulose materials, namely nano paper-cellulose (NPC) and wood-derived nano-cellulose (WDC), to improve its properties. A novel preparation method of nano-cellulose solution was developed, including blending, ultrasonic stirring, and centrifugal treatment. Four types of nano-cellulose solution (0.5% NPC, 0.5%, 1.0%, and 1.5% WDC by weight of water) were selected. The microscopy analysis indicated that 0.5% WDC emulsion had a smaller particle size than 1.5% WDC emulsion. The rheology test indicated that WDC modified residue improved rutting resistance with the increased solution dosage due to the cross-linking effect, but its creep-and-recovery performance was worse than that of SBR emulsion residue. The NPC modified binder had a higher rutting factor than WDC modified binder at the same dosage after short-term aging. In addition, 1.0% WDC could be regarded as the optimal dosage in terms of fatigue and low-temperature performance. Furthermore, Fourier Transform Infrared Spectroscopy (FTIR) results showed that 0.5% NPC modified residue performed better in long-term aging resistance compared with 0.5%WDC modified asphalt.
X D Hou, F P Xiao, R Guo, Q Xiang, T Wang, J Y Wang. Application of spectrophotometry on detecting asphalt content of emulsified asphalt. Journal of Cleaner Production, 2019, 215: 626–633 https://doi.org/10.1016/j.jclepro.2019.01.102
2
C A WangY L WuM Y GuoM C Chen. Development and applications of bitumen emulsion and its emulsifiers. Guangzhou Chemistry, 2006, 31(1): 54−60 (in Chinese)
3
Y Y Liu, Z Y Zhang, L J Tan, Y Xu, C H Wang, P F Liu, H Y Yu, M Oeser. Laboratory evaluation of emulsified asphalt reinforced with glass fiber treated with different methods. Journal of Cleaner Production, 2020, 274: 123116 https://doi.org/10.1016/j.jclepro.2020.123116
4
X Guan. Research of performance for nano-ZnO/SBR modified asphalt mixture. Technology of Highway and Transport, 2021, 37(3): 28−33 (in Chinese)
5
R M Islam, S Arafat, N M Wasiuddin. Quantification of reduction in hydraulic conductivity and skid resistance caused by fog seal in low-volume roads. Transportation Research Record: Journal of the Transportation Research Board, 2017, 2657(1): 99–108 https://doi.org/10.3141/2657-11
6
L Xu, Z F Zhao, X R Li, J Yuan, Q Y Zhou, F P Xiao. Cracking investigation on fog seal technology with waterborne acrylate and polyurethane as a clean modification approach. Journal of Cleaner Production, 2021, 329: 129751 https://doi.org/10.1016/j.jclepro.2021.129751
7
H L Zhang, M M Su, S F Zhao, Y P Zhang, Z P Zhang. High and low temperature properties of nano-particles/polymer modified asphalt. Construction & Building Materials, 2016, 114: 323–332 https://doi.org/10.1016/j.conbuildmat.2016.03.118
8
C Q Yan, Q Lv, A A Zhang, C F Ai, W D Huang, D Y Ren. Modeling the modulus of bitumen/SBS composite at different temperatures based on kinetic models. Composites Science and Technology, 2022, 218: 109146 https://doi.org/10.1016/j.compscitech.2021.109146
9
J Yang, S Tighe. A review of advances of nanotechnology in asphalt mixtures. Procedia: Social and Behavioral Sciences, 2013, 96: 1269–1276 https://doi.org/10.1016/j.sbspro.2013.08.144
10
L Sun, X T Xin, H Y Wang, W J Gu. Microscopic mechanismvof modified asphalt by multi-dimensional and multi-scale nanomaterial. Journal of the Chinese Ceramic Society, 2012, 40(10): 1437–1447
11
R Y Li, F P Xiao, S Amirkhanian, Z P You, J Huang. Developments of nano materials and technologies on asphalt materials—A review. Construction & Building Materials, 2017, 143: 633–648 https://doi.org/10.1016/j.conbuildmat.2017.03.158
12
S J He, Y Q Wang, M M Xi, J Lin, Y Xue, L Q Zhang. Prevention of oxide aging acceleration by nano-dispersed clay in styrene-butadiene rubber matrix. Polymer Degradation & Stability, 2013, 98(9): 1773–1779 https://doi.org/10.1016/j.polymdegradstab.2013.05.012
13
C Z Zhu, H L Zhang, G Q Xu, C J Shi. Aging rheological characteristics of SBR modified asphalt with multi-dimensional nanomaterials. Construction & Building Materials, 2017, 151: 388–393 https://doi.org/10.1016/j.conbuildmat.2017.06.121
14
H L Zhang, C Z Zhu, J Y Yu, C J Shi, D M Zhang. Influence of surface modification on physical and ultraviolet aging resistance of bitumen containing inorganic nanoparticles. Construction & Building Materials, 2015, 98: 735–740 https://doi.org/10.1016/j.conbuildmat.2015.08.138
15
B HuangQ L LuL R Tang. Research progress of nanocellulose manufacture and application. Journal of Forestry Engineering, 2016, 1(5): 1−9 (in Chinese)
16
W R YaoQ H Xu. Research development of nano-cellulose preparation. Paper and Paper Making, 2014, 33(11): 49−55 (in Chinese)
17
M J Khattak, A Khattab, H R Rizvi, P F Zhang. The impact of carbon nano-fiber modification on asphalt binder rheology. Construction & Building Materials, 2012, 30: 257–264 https://doi.org/10.1016/j.conbuildmat.2011.12.022
18
M J Khattak, A Khattab, H R Rizvi. Characterization of carbon nano-fiber modified hot mix asphalt mixtures. Construction & Building Materials, 2013, 40: 738–745 https://doi.org/10.1016/j.conbuildmat.2012.11.034
19
R Ghabchi, M P P Castro. Effect of laboratory-produced cellulose nanofiber as an additive on performance of asphalt binders and mixes. Construction & Building Materials, 2021, 286: 122922 https://doi.org/10.1016/j.conbuildmat.2021.122922
20
J Jin, Y C Gao, Y R Wu, R Li, R H Liu, H Wei, G P Qian, J L Zheng. Performance evaluation of surface-organic grafting on the palygorskite nanofiber for the modification of asphalt. Construction & Building Materials, 2021, 268: 121072 https://doi.org/10.1016/j.conbuildmat.2020.121072
21
M J Khattak, A Khattab, P F Zhang, H R Rizvi, T Pesacreta. Microstructure and fracture morphology of carbon nano-fiber modified asphalt and hot mix asphalt mixtures. Materials and Structures, 2013, 46(12): 2045–2057 https://doi.org/10.1617/s11527-013-0035-3
22
Q L Yang, X L Li, L Zhang, Y Qian, Y Z Qi, H S Kouhestani, X M Shi, X C Gui, D W Wang, J Zhong. Performance evaluation of bitumen with a homogeneous dispersion of carbon nanotubes. Carbon, 2020, 158: 465–471 https://doi.org/10.1016/j.carbon.2019.11.013
23
J Li, S L Yao, F P Xiao, S N Amirkhanian. Surface modification of ground tire rubber particles by cold plasma to improve compatibility in rubberised asphalt. International Journal of Pavement Engineering, 2022, 23(3): 651–662
24
Z C Liu. Reason for aggregation of nanoparticles in nano-materials and solutions. Value Engineering, 2017, 36(13): 157−158 (in Chinese)
25
A Jamshidi, M R M Hasan, H Yao, Z P You, M O Hamzah. Characterization of the rate of change of rheological properties of nano-modified asphalt. Construction & Building Materials, 2015, 98: 437–446 https://doi.org/10.1016/j.conbuildmat.2015.08.069
26
A Khadivar, A Kavussi. Rheological characteristics of SBR and NR polymer modified bitumen emulsions at average pavement temperatures. Construction & Building Materials, 2013, 47: 1099–1105 https://doi.org/10.1016/j.conbuildmat.2013.05.093
27
E20-2011 JTG. Standard Test Methods of Bitumen and Bituminous Mixtures for Highway Engineering. Beijing: Ministry of Transport of the People’s Republic of China, 2011 (in Chinese)
28
F40-2004 JTG. Technical Specification for Construction of Highway Asphalt Pavement. Beijing: Ministry of Transport of the People’s Republic of China, 2004 (in Chinese)
29
T Saito, A Isogai. Ion-exchange behavior of carboxylate groups in fibrous cellulose oxidized by the TEMPO-mediated system. Carbohydrate Polymers, 2005, 61(2): 183–190 https://doi.org/10.1016/j.carbpol.2005.04.009
30
A P Mathew, K Oksman, Z Karim, P Liu, S A Khan, N Naseri. Process scale up and characterization of wood cellulose nanocrystals hydrolysed using bioethanol pilot plant. Industrial Crops and Products, 2014, 58: 212–219 https://doi.org/10.1016/j.indcrop.2014.04.035
31
P L Bragd, H van Bekkum, A C Besemer. TEMPO-mediated oxidation of polysaccharides: survey of methods and applications. Topics in Catalysis, 2004, 27(1): 49–66 https://doi.org/10.1023/B:TOCA.0000013540.69309.46
32
S L Dai, Y Wang, J Y Zhang, Y W Zhao, F P Xiao, D P Liu, T R Wang, J Huang. Wood-derived nanopaper dielectrics for organic synaptic transistors. ACS Applied Materials & Interfaces, 2018, 10(46): 39983–39991 https://doi.org/10.1021/acsami.8b15063
33
T-315 AASHTO. Standard Method of Test for Determining the Rheological Properties of Asphalt Binder Using a Dynamic Shear Rheometer (DSR). Washington, D.C.: American Association of State Highway and Transportation Officials (AASHTO), 2019
34
M Elwardany, J P Planche, G King. Universal and practical approach to evaluate asphalt binder resistance to thermally-induced surface damage. Construction & Building Materials, 2020, 255: 119331 https://doi.org/10.1016/j.conbuildmat.2020.119331
35
R M Anderson, G N King, D I Hanson, P B Blankenship. Evaluation of the relationship between asphalt binder properties and non-load related cracking. Electronic Journal of the Association of Asphalt Paving Technologists, 2011, 80: 615–664
36
X D Hou, S T Lv, Z Chen, F P Xiao. Applications of Fourier transform infrared spectroscopy technologies on asphalt materials. Measurement, 2018, 121: 304–316 https://doi.org/10.1016/j.measurement.2018.03.001
37
A N Amirkhanian, F P Xiao, S N Amirkhanian. Characterization of unaged asphalt binder modified with carbon nano particles. International Journal of Pavement Research and Technology, 2011, 4(5): 281–286
38
S Q Wang, C Wei, Y Y Gong, J Lv, C B Yu, J H Yu. Cellulose nanofiber-assisted dispersion of cellulose nanocrystals@polyaniline in water and its conductive films. RSC Advances, 2016, 6(12): 10168–10174 https://doi.org/10.1039/C5RA19346J
39
L O Souza, M Cordazzo, L M S Souza, G Tonoli, F A Silva, V Mechtcherine. Investigation of dispersion methodologies of microcrystalline and nano-fibrillated cellulose on cement pastes. Cement and Concrete Composites, 2022, 126: 104351
40
H TianM L ZengC F WuY XiaY F Zhu. Effect of glass fiber and plant fiber on high temperature performance of unaged and aged asphalt mortar. Highway Engineering, 2008, 33(4): 37−41 (in Chinese)
41
B N Yuan, M H Guo, Z H Huang, N Naik, Q Hu, Z H Guo. A UV-shielding and hydrophobic graphitic carbon nitride nanosheets/cellulose nanofibril (gCNNS/CNF) transparent coating on wood surface for weathering resistance. Progress in Organic Coatings, 2021, 159: 106440 https://doi.org/10.1016/j.porgcoat.2021.106440
42
H L Cheng, L J Sun, Y H Wang, X Y Chen. Effects of actual loading waveforms on the fatigue behaviours of asphalt mixtures. International Journal of Fatigue, 2021, 151: 106386 https://doi.org/10.1016/j.ijfatigue.2021.106386
43
M P P Castro. Effects of cellulose nano-fiber as an additive on performance of asphalt binders and mixes. Thesis for the Master’s Degree. Vermillion, SD: South Dakota State University, 2020
44
X D Hou, F P Xiao, J Y Wang, S Amirkhanian. Identification of asphalt aging characterization by spectrophotometry technique. Fuel, 2018, 226: 230–239 https://doi.org/10.1016/j.fuel.2018.04.030
45
H Y Zhang, G Xu, X H Chen, R Wang, K R Shen. Effect of long-term laboratory aging on rheological properties and cracking resistance of polymer-modified asphalt binders at intermediate and low temperature range. Construction & Building Materials, 2019, 226: 767–777 https://doi.org/10.1016/j.conbuildmat.2019.07.206
46
J Y Wang, T Wang, X D Hou, F P Xiao. Modelling of rheological and chemical properties of asphalt binder considering SARA fraction. Fuel, 2019, 238: 320–330 https://doi.org/10.1016/j.fuel.2018.10.126
47
S Chen, H Xu, X Y He, Y Su, B Zhang, Q Liu. Oil-grinded recycled kapok fiber as a bio-packing for eco-friendly modified asphalt and its aging resistance behavior. Construction & Building Materials, 2022, 320: 126293 https://doi.org/10.1016/j.conbuildmat.2021.126293