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Frontiers of Structural and Civil Engineering

ISSN 2095-2430

ISSN 2095-2449(Online)

CN 10-1023/X

邮发代号 80-968

2019 Impact Factor: 1.68

Frontiers of Structural and Civil Engineering  2022, Vol. 16 Issue (11): 1474-1485   https://doi.org/10.1007/s11709-022-0869-2
  本期目录
Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano paper-cellulose
Yunge WEI, Jiayu WANG(), Ruoyu LI, Ling XU, Feipeng XIAO
Key Laboratory of Road and Traffic Engineering of Ministry of Education, Tongji University, Shanghai 200092, China
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Abstract

Emulsified asphalt is the primary material for preventive maintenance and cold-mix paving, but its low cohesive strength and poor mechanical properties limit its wide application, even with polymer modification. In this study, Styrene-Butadiene Rubber (SBR) emulsified asphalt was modified with nano-cellulose materials, namely nano paper-cellulose (NPC) and wood-derived nano-cellulose (WDC), to improve its properties. A novel preparation method of nano-cellulose solution was developed, including blending, ultrasonic stirring, and centrifugal treatment. Four types of nano-cellulose solution (0.5% NPC, 0.5%, 1.0%, and 1.5% WDC by weight of water) were selected. The microscopy analysis indicated that 0.5% WDC emulsion had a smaller particle size than 1.5% WDC emulsion. The rheology test indicated that WDC modified residue improved rutting resistance with the increased solution dosage due to the cross-linking effect, but its creep-and-recovery performance was worse than that of SBR emulsion residue. The NPC modified binder had a higher rutting factor than WDC modified binder at the same dosage after short-term aging. In addition, 1.0% WDC could be regarded as the optimal dosage in terms of fatigue and low-temperature performance. Furthermore, Fourier Transform Infrared Spectroscopy (FTIR) results showed that 0.5% NPC modified residue performed better in long-term aging resistance compared with 0.5%WDC modified asphalt.

Key wordsnano-cellulose    emulsified asphalt binder    dispersion    rheological properties    Fourier transform infrared spectroscopy
收稿日期: 2021-10-24      出版日期: 2023-01-03
Corresponding Author(s): Jiayu WANG   
 引用本文:   
. [J]. Frontiers of Structural and Civil Engineering, 2022, 16(11): 1474-1485.
Yunge WEI, Jiayu WANG, Ruoyu LI, Ling XU, Feipeng XIAO. Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano paper-cellulose. Front. Struct. Civ. Eng., 2022, 16(11): 1474-1485.
 链接本文:  
https://academic.hep.com.cn/fsce/CN/10.1007/s11709-022-0869-2
https://academic.hep.com.cn/fsce/CN/Y2022/V16/I11/1474
emulsion propertiesunitmeasured valuesrequirementmethod
SBR ISBR II
demulsification rateslowquickT 0658
particle chargecationic (+)cationic (+)T 0653
surplus on sieve (1.18 mm)%0.060.06≤0.1T 0652
engler viscosity (25 °C)1317.62?30T 0622
storage stability (5 d)%1.10.20≤5T 0655
residue by distillation residue%5962.5≥50T 0651
softening point°C58.157.5T 0606
penetration (25 °C)0.1mm58.86245–150T 0604
ductility (15 °C)cm4242≥40T 0605
Tab.1  
Fig.1  
Fig.2  
emulsion typeaverage particle size (μm)maximum particle size (μm)5 μm> 10 μm
0.5% WDC emulsion1.362.12100%
1.5% WDC emulsion2.615.2890%
Tab.2  
Fig.3  
Fig.4  
Fig.5  
Fig.6  
Fig.7  
Fig.8  
temperature (°C)0.5% NPC0.5% WDC1% WDC1.5% WDC
unagedRTFOunagedRTFOunagedRTFOunagedRTFO
58YYYYNYYY
64YYYYNYYY
70YYYYNYYY
Tab.3  
Fig.9  
asphalt type–6 °C–12 °C–18 °C
stiffness (MPa)m-valuestiffness (MPa)m-valuestiffness (MPa)m-value
SBR I89.10.388205.00.3164360.237
0.5% NPC82.90.392141.00.3343050.287
0.5% WDC73.10.396175.00.3453270.275
1.0% WDC42.60.41795.80.3772340.322
1.5% WDC65.50.404122.00.3622960.307
Tab.4  
Fig.10  
Fig.11  
Fig.12  
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