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Frontiers of Structural and Civil Engineering

ISSN 2095-2430

ISSN 2095-2449(Online)

CN 10-1023/X

邮发代号 80-968

2019 Impact Factor: 1.68

Frontiers of Structural and Civil Engineering  2023, Vol. 17 Issue (8): 1264-1280   https://doi.org/10.1007/s11709-023-0921-x
  本期目录
Analyzing the characterization of pore structures and permeability of diesel contaminated clays under different aging conditions
Yeyang CHUN1, Dong ZHOU1(), Zonghui LIU1(), Chenhui LIU1, Tenglong LIANG2, Dongpo SU1, Zheng HUANG1
1. Key Laboratory of Disaster Prevention and Structural Safety of Ministry of Education, School of Civil Engineering and Architecture, Guangxi University, Nanning 530004, China
2. College of Civil Engineering and Architecture, Guangxi University for Nationalities, Nanning 530006, China
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Abstract

In this study, mercury intrusion porosimetry (MIP) and X-ray micro-computed tomography (XRμCT) were used to characterize the pore structures and investigate the permeability characteristics of clay after aging and contamination with diesel. The results of the MIP tests showed that aging leads to reductions in porosity and average diameter, as well as an increase in tortuosity. The XRμCT analysis yielded consistent results; it showed that aging renders pores more spherical and isotropic and pore surfaces smoother. This weakens the pore connectivity. Micromorphological analysis revealed that aging led to the rearrangement of soil particles, tighter interparticle overlapping, and a reduction in pore space. The combination of MIP and XRμCT provided a comprehensive and reliable characterization of the soil pore structure. An increased diesel content increased the porosity and average diameter and reduced the tortuosity of the pores. Mechanistic analysis showed that aging weakens interparticle cohesion; this causes large agglomerates to break down into smaller agglomerates, resulting in a tighter arrangement and a subsequent reduction in porosity. An increase in diesel content increases the number of large agglomerates and pore spaces between agglomerates, resulting in increased porosity. Both aging and diesel content can weaken the permeation characteristics of soil.

Key wordsMIP    XRμCT    aging    diesel content    pore structure    permeability characteristics
收稿日期: 2022-06-19      出版日期: 2023-11-16
Corresponding Author(s): Dong ZHOU,Zonghui LIU   
 引用本文:   
. [J]. Frontiers of Structural and Civil Engineering, 2023, 17(8): 1264-1280.
Yeyang CHUN, Dong ZHOU, Zonghui LIU, Chenhui LIU, Tenglong LIANG, Dongpo SU, Zheng HUANG. Analyzing the characterization of pore structures and permeability of diesel contaminated clays under different aging conditions. Front. Struct. Civ. Eng., 2023, 17(8): 1264-1280.
 链接本文:  
https://academic.hep.com.cn/fsce/CN/10.1007/s11709-023-0921-x
https://academic.hep.com.cn/fsce/CN/Y2023/V17/I8/1264
property value
specific gravity 2.73
moisture content (%) 19.43
ρ (g·cm−3) 1.755
plastic limit (%) 23.52
liquid limit (%) 47.07
clay content (vol.%) 20.46
silt content (vol.%) 36.32
sand content (vol.%) 43.22
Tab.1  
factor level
aging time 7, 14, 30, 60, 90 d
diesel content 0.0 wt.%, 3.0 wt.%, 5.0 wt.%, 7.0 wt.%
moisture content 20%
dry density 1.4 g·cm−3
Tab.2  
Fig.1  
Fig.2  
Fig.3  
Fig.4  
Fig.5  
aging time (d) value/voxel
7 450
30 400
90 450
Tab.3  
Fig.6  
Fig.7  
Fig.8  
pore structure parameter source type III of squares degrees of freedom means squared F p-value
apparent porosity aging time 119.177 4 29.794 69.529 < 0.001
diesel content 47.389 3 15.796 36.863 < 0.001
aging time × diesel content 16.651 12 1.388 3.238 0.003
error 17.141 40 0.429
corrected total 200.358 59
average diameter aging time 7404.647 4 1851.162 157.993 < 0.001
diesel content 8017.655 3 2672.552 228.097 < 0.001
aging time × diesel content 537.902 12 44.825 3.826 0.001
error 468.670 40 11.717
corrected total 16428.874 59
tortuosity aging time 0.311 4 0.078 64.079 < 0.001
diesel content 0.184 3 0.061 50.525 < 0.001
aging time × diesel content 0.040 12 0.003 2.713 0.009
error 0.049 40 0.001
corrected total 0.584 59
Tab.4  
pore structure parameter (nm) source type III of squares degrees of freedom means squared F p-value
5–20 aging time 9.787 4 2.447 110.524 < 0.001
diesel content 47.401 3 15.800 713.711 < 0.001
aging time × diesel content 1.843 12 0.154 6.938 < 0.001
error 0.886 40 0.022
corrected total 59.917
20–100 aging time 0.275 4 0.069 0.716 0.586
diesel content 26.821 3 8.940 93.221 < 0.001
aging time × diesel content 0.963 12 0.080 0.837 0.613
error 3.836 40 0.096
corrected total 31.896
Tab.5  
pore structure parameter (nm) source type III of squares degrees of freedom means squared F p-value
100–5000 aging time 1.612 4 0.403 9.788 < 0.001
diesel content 19.508 3 6.503 157.886 < 0.001
aging time × diesel content 1.877 12 0.156 3.797 0.001
error 1.647 40 0.041
corrected total 24.644
> 5000 aging time 73.398 4 18.349 100.706 < 0.001
diesel content 190.392 3 63.464 348.302 < 0.001
aging time × diesel content 20.565 12 1.714 9.405 < 0.001
error 7.288 40 0.182
corrected total 291.643
Tab.6  
soil parameter apparent porosity average diameter tortuosity
apparent porosity
average diameter 0.95a)
tortuosity −0.82a) −0.86a)
porosity (> 5000 nm) 0.88 a) 0.94 a) −0.83a)
porosity (100–5000 nm) 0.26 0.45 b) −0.22
porosity (20–100 nm) −0.26 −0.45b) 0.54b)
porosity (5–20 nm) 0.02 −0.23 0.16
Tab.7  
aging time (d) soil parameter
true porosity average diameter shape factor degree of anisotropy fractal dimension Euler number tortuosity pore−throat ratio
7 19.13 ± 0.26aA 16.76 ± 0.10aA 1.47 ± 0.03aA 0.49 ± 0.01aA 2.73 ± 0.02aA −0.17 ± 0.01cC 1.72 ± 0.03cC 8.97 ± 0.61aA
30 15.42 ± 0.35bB 14.45 ± 0.11bB 1.12 ± 0.01bB 0.48 ± 0.01bB 2.69 ± 0.01bB −0.14 ± 0.01bB 1.92 ± 0.05bB 4.51 ± 0.47bB
90 13.25 ± 0.47cC 12.66 ± 0.25cC 1.01 ± 0.01cC 0.47 ± 0.01cC 2.66 ± 0.01cC −0.11 ± 0.01aA 2.75 ± 0.01aA 3.89 ± 0.32bB
Tab.8  
Fig.9  
Fig.10  
Fig.11  
Fig.12  
Fig.13  
Fig.14  
Fig.15  
Fig.16  
soil parameter permeability coefficient (aging time) permeability coefficient (diesel content)
apparent porosity 0.97a) −0.71b)
average diameter 0.95a) −0.83a)
tortuosity −0.86a) 0.94a)
porosity (> 5000 µm) 0.98a) −0.94a)
porosity (100–5000 µm) −0.67b) −0.93a)
porosity (20–100 µm) 0.03 0.92a)
porosity (5–20 µm) 0.96a) 0.94a)
Tab.9  
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