CO<sub>2</sub> adsorption performance of ZIF-7 and its endurance in flue gas components

doi:10.1007/s11783-013-0507-2

Front Envir Sci Eng

2014, Vol. 8

Issue (2) : 162-168 https://doi.org/10.1007/s11783-013-0507-2

RESEARCH ARTICLE

CO₂ adsorption performance of ZIF-7 and its endurance in flue gas components

Jiangkun XIE, Naiqiang YAN(

), Fei LIU, Zan QU, Shijian YANG, Ping LIU

School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

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Abstract

Porous ZIF-7 with the sodalite (SOD) cage structure (ZIF, Zeolitic imidazolate framework) were synthesized by the solvothermal method. Synthesized material was characterized by powder X-ray diffraction (PXRD), thermal gravity (TG), scanning electron microscopy (SEM) and N₂ adsorption analysis. ZIF-8 with the SOD structure and a little larger pore window was synthesized in a similar way and was characterized for comparisons. Thermal stability and structural stability of ZIF-7 were tested through PXRD analysis, and the capability of the material for CO₂ capture from simulated flue gas was investigated through physical adsorption method. The results showed that CO₂ adsorption capacity on ZIF-7 was about 48 mL·g^-1 while the capacity on ZIF-8 was about 18 mg·g^-1 (at 12°C and 0.98 P/P₀ relative pressure). Furthermore, the impact of flue gas components on adsorption capacity of ZIF-7 and the selectivity of CO₂ against N₂ on ZIF-7 was also investigated in this work.

Keywords ZIF-7 structural stability CO₂ capture thermal stability

Corresponding Author(s): YAN Naiqiang,Email:nqyan@sjtu.edu.cn

Issue Date: 01 April 2014

Cite this article:

Jiangkun XIE,Shijian YANG,Ping LIU, et al. CO₂ adsorption performance of ZIF-7 and its endurance in flue gas components[J]. Front Envir Sci Eng, 2014, 8(2): 162-168.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-013-0507-2
https://academic.hep.com.cn/fese/EN/Y2014/V8/I2/162

Fig.1 PXRD patterns of ZIF-7 (a) and ZIF-8 (b)

Fig.2 SEM images of ZIF-7 (a) and ZIF-8 (b)

Fig.3 TG curves of ZIF-7 and ZIF-8

Fig.4 XRD patterns of ZIF-7 before and after treatment in moist air at room temperature for 1, 3 and 5 d

Fig.5 XRD patterns of ZIF-7 before and after treatment in SO/N mixture at room temperature for 1, 3 and 5 d

Fig.6 XRD patterns of ZIF-7 before and after treatment in NO/N mixture at room temperature for 1, 3 and 5 d

Fig.7 XRD patterns of ZIF-7 before and after treatment in moist air/NO/SO mixture at room temperature for 5 d

Fig.8 Adsorption and desorption curve of N (a) and CO (b) on ZIF-7 and ZIF-8 at 12°C

Fig.9 Adsorption and desorption curves of CO on ZIF-7 after treatment in moist air (a), SO (b) and NO (c) at 12°C for 5 d

Fig.10 CO and N concentration in gaseous effluent passing through ZIF-7 packed bed at room temperature
(The abscissa 0 denotes the initial gaseous mixture, abscissa 1-7 denote the 1-7th gaseous effluent)

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