Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH· generation

doi:10.1007/s11783-014-0694-5

Front. Environ. Sci. Eng.

2015, Vol. 9

Issue (4) : 591-595 https://doi.org/10.1007/s11783-014-0694-5

RESEARCH ARTICLE

Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH· generation

Hong SUN,Min SUN,Yaobin ZHANG(

),Xie QUAN

Key Laboratory of Industrial Ecology and Environmental Engineering (Dalian University of Technology), Ministry of Education, School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China

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Abstract

Catalytic ozonation of Reactive Red X-3B in aqueous solution had been carried out in an ozone oxidation reactor where Mn-Fe-ceramic honeycomb was used as the catalysts. The presence of Mn-Fe-ceramic honeycomb catalyst could obviously improve the decoloration efficiency of Reactive Red X-3B and the utilization efficiency of ozone compared to the results from non-catalytic ozonation. Adsorption of Reactive Red X-3B had no obviously influence on the degradation efficiency. Addition of tert-butanol significantly decreased the degradation efficiency, indicating that the degradation of Reactive Red X-3B followed the mechanism of hydroxyl radical (OH·) oxidation. The operating variables such as reaction pressure and ozone supply had a positive influence on the degradation efficiency, mainly attributing to facilitate the ozone decomposition and OH· formation.

Keywords catalytic ozonation reactive red X-3B ceramic honeycomb hydroxyl radical (OH·)

Corresponding Author(s): Yaobin ZHANG

Online First Date: 23 April 2014 Issue Date: 25 June 2015

Cite this article:

Xie QUAN,Yaobin ZHANG,Hong SUN, et al. Catalytic ozonation of reactive red X-3B in aqueous solution under low pressure: decolorization and OH· generation[J]. Front. Environ. Sci. Eng., 2015, 9(4): 591-595.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-014-0694-5
https://academic.hep.com.cn/fese/EN/Y2015/V9/I4/591

Fig.1 Schematic diagram of catalytic ozonation reaction setup

1. Oxygen, 2. Dryer, 3. Ozone generator, 4. Gas flowmeter, 5.Import valve, 6.Sampling position, 7. Heater, 8. Temperature control system, 9. Catalysts, 10.Pump, 11. Manometer, 12. Outlet pressure valve, 13. Safety valve, 14. KI solution

Fig.2 Comparison of the decolorization efficiency of X-3B with and without catalysts. (supply of ozone: 1.0 g·h^-1; imposed pressure: 0.02 MPa)

Fig.3 Influence of tert-butanol on the ozonation with and without the catalysts (supply of ozone: 1.0 g·h^-1; imposed pressure: 0.02 MPa)

Fig.4 Comparison of the decolorization under the different pressure (in the presence of the catalysts)

Tab.1 Influence of pressure on flow rate of ozone

Fig.5 Influence of tert-butanol on the ozonation under the different pressure (in the presence of the catalysts)

Tab.2 Peseudo-first order and R² under different pressures

Fig.6 Comparison of the degradation efficiency of X-3B in the different ozone generation rates (pressure: 0.02 Mpa, in the presence of catalysts)

Fig.7 Influence of tert-butanol on the ozonation in the different ozone generation rates (pressure 0.02 MPa, in the presence of catalysts)

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