Surface-enhanced Raman scattering (SERS) based on surface plasmon resonance coupling techniques

doi:10.1007/s11458-011-0258-1

Front Chem Chin

2011, Vol. 6

Issue (4) : 341-354 https://doi.org/10.1007/s11458-011-0258-1

REVIEW ARTICLE

Surface-enhanced Raman scattering (SERS) based on surface plasmon resonance coupling techniques

Shuping XU, Yu LIU, Haibo LI, Weiqing XU(

)

State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China

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Abstract

Surface plasmon resonance (SPR) can provide a remarkably enhanced electromagetic field around metal surface. It is one of the enhancement models for explaining surface-enhanced Raman scattering (SERS) phonomenon. With the development of SERS theories and techniques, more and more studies referred to the configurations of the optical devices for coupling the excitation and radiation of SERS, including the prism-coupling, waveguide-coupling, and grating-coupling modes. In this review, we will summarize the recent experimental improvements on the surface plasmon-coupled SERS.

Keywords surface-enhanced Raman scattering (SERS) electromagnetic field surface plasmon resonance (SPR) metal film grating

Corresponding Author(s): XU Weiqing,Email:xuwq@jlu.edu.cn

Issue Date: 05 December 2011

Cite this article:

Weiqing XU,Shuping XU,Yu LIU, et al. Surface-enhanced Raman scattering (SERS) based on surface plasmon resonance coupling techniques[J]. Front Chem Chin, 2011, 6(4): 341-354.

URL:

https://academic.hep.com.cn/fcc/EN/10.1007/s11458-011-0258-1
https://academic.hep.com.cn/fcc/EN/Y2011/V6/I4/341

Fig.1 Interaction of a plane wave in a stratified medium system

Fig.2 The four possible ways to measure Raman scattering using a Kretschmann prism. Reprinted with permission from Ref. []. Copyright? 1988 American Chemical Society

Fig.3 (a) ATR-SPR/SERS optical setup with gold nanoparticle enhancement; (b) Photograph of ATR-SPR/SERS device. Reprinted with permission from Ref. []. Copyright? 2004 SPIE

Fig.5 The schematic diagram of SERS spectroscopies based on (a) propagating SP excitation, (b) localized and propagating SP co-enhancement, and (c) long-range SP excitation

Fig.6 (a) The incident angle-dependent SERS spectra of 4-ATP. The integration time of all SERS spectra was 10 s and the laser power was 8 mW. (b) The SERS peak intensities of the 4-ATP at 1435 (○), 1141 (□), and 1077 cm (◇) are plotted with the incident angles. The SPR curve was recorded as the interval of 0.02°. Reprinted with permission from Ref. []. Copyright? 2010 American Institute of Physics

Fig.7 The schematic diagram of the SP-enhanced SERS based on (a) the evanescent field excitation and (b) bright field excitation. (c) The SERS spectra excited via the evanescent field and bright field. The incident angle was 44°.

Fig.8 (a) Curve A and A-1 are the SPR curve and SERS intensity profile of 4-Mpy on a vacuum-deposited silver film. Curve B and B-1 are the SPR curve and SERS intensity profile of 4-Mpy under the LSP-PSP co-enhancement. (b) The strongest SERS spectra of 4- Mpy on a silver film and a sandwich structure excited under the resonance condition. Reprinted with permission from Ref. []. Copyright? 2011 Royal Society of Chemistry

Fig.9 (a) A comparison of the angular reflectivity scans recorded on a normal SPR configuration and a LRSPR configuration. The angle-dependent SP field-enhanced SERS intensities under a SPR configuration (○) and a LRSPR configuration (◇) were also shown. (b) The SERS spectra excited by the LRSPs at the resonance angles of 65.4° (top curve) and the SPs at the resonance angles of 72° (bottom curve). Reprinted with permission from Ref. []. Copyright? 2011 American Chemical Society

Fig.10 Schematic light scattering configuration in ATR-SPP resonance with the weierstrass prism. Reprinted with permission from Ref. []. Copyright ?1995 American Chemical Society

Fig.11 Schematics of the optical setup for combined SPR-SERS in a backscattering configuration. Reprinted with permission from Ref. []. Copyright ?2011 American Chemical Society

Fig.12 The design of the directional SERS based on back coupled radiation mode

Fig.13 Optical input scheme for TIR excitation of the localized plasmon at the nanoparticle array/air interface. Reprinted with permission from Ref. []. Copyright ?2005 American Chemical Society

Fig.14 Scheme of the remote SERS measurement using a quasi-one-dimensional ribbon dielectric waveguide, where A and B stand for the point that laser radiates on the edge of ribbon belt and collection point of SERS, and the red and brown arrows stands for the incident and scattering and collection SERS signal, respectively. Reprinted with permission from Ref. []. Copyright ?2011 Springer Science+ Business Media

Fig.15 Schematic diagram of an SERS-active optical fiber. Reprinted with permission from Ref. []. Copyright ?2008 American Chemical Society

Fig.16 Schematic of the Raman probe with a D-shaped (or side-polished) fiber coated with SERS substrate on the flat surface. Reprinted with permission from Ref. []. Copyright ?2005 American Institute of Physics

Fig.17 Configuration of SERS-active light waveguide applied to the SERS detection of a sample in a small volume of low refractive index liquid. Reprinted with permission from Ref. []. Copyright ?2004 Optical Society of America

Fig.18 (a) Schematic of the experimental setup. (b) SEM image taken from the side surface of the silica core. Reprinted with permission from Ref. []. Copyright ?2008 Optical Society of America

Fig.19 (a) A proposed wo-dimensional SERS grating structure and its spectral properties; (b) Absorption spectra for various periods from 426 to 546 nm with a 24 nm increment; (c) absorption peak positions versus different periods for LSPs (circles) and SPPs (squares), with corresponding maximum local || at resonance wavelength of SPPs (triangles). The silver film thickness was 40 nm, the bump height was 100 nm and the environment is water. Reprinted with permission from Ref. []. Copyright ?2010 Optical Society of America

Fig.20 (a) An AFM image of biharmonic metal surface with the grating components of 500 and 250 nm. First periodicity was designed to excite the SPs. Second one generated backscattering for PSPs with a photonic band gap. (b) Resonance absorption spectra of biharmonic metal gratings with different grating strengths; (c) Corresponding SERS spectra for each resonance condition. Reprinted with permission from Ref. []. Copyright ?2008 Optical Society of America

Fig.21 Schematic metal nanostructured plasmonic crystals (b) schematic SERS process; light is coupled into a plasmon, which then interacts with and is Raman scattered by a molecule on the surface, and the outgoing plasmon is then scattered back into a photon. Emitted far-field Raman images deduced from the measured plasmonic nanovoid extinction for (a) propagating and (b) localized plasmons. Reprinted with permission from Ref. []. Copyright ?2005 American Chemical Society

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