Beta-cyclodextrin adsorbents to remove water pollutants—a commentary

doi:10.1007/s11705-022-2146-2

Frontiers of Chemical Science and Engineering

2022, Vol. 16

Issue (9): 1407-1423 https://doi.org/10.1007/s11705-022-2146-2

本期目录

Beta-cyclodextrin adsorbents to remove water pollutants—a commentary

Fadina Amran^1,², Muhammad Abbas Ahmad Zaini^1,²(

)

¹. Centre of Lipids Engineering & Applied Research (CLEAR), Ibnu-Sina Institute for Scientific & Industrial Research (ISI-SIR), Universiti Teknologi Malaysia, Johor, Malaysia
². School of Chemical & Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, Johor, Malaysia

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Abstract：

Beta-cyclodextrin-based adsorbent is a promising adsorbent because it has unique characteristics and able to form host-guest complexes with various organic compounds. Adsorption using beta-cyclodextrin-based adsorbent has continuously improved by various preparation strategies and crosslinking agents. This commentary aims to highlight the preparation strategies, properties, and adsorption mechanisms of beta-cyclodextrin-based adsorbents. The adsorbents can be generally classified according to the preparation methods and display high adsorption capacity especially for dyes. Particularly, composite/nanocomposite beta-cyclodextrin-based adsorbents exhibit outstanding adsorption capacity even though the surface area is lower than that of porous and magnetic beta-cyclodextrin-based adsorbents. The beta-cyclodextrin/chitosan functionalized graphene oxide hydrogel with specific surface of 17.6 m²·g^–1 yields an extraordinarily maximum adsorption capacity of 1499 mg·g^–1 methylene blue, while beta-cyclodextrin/chitosan modified with iron(II, III) oxide nanoparticles displays a much greater maximum adsorption capacity at 2780 mg·g^–1. The hydrophobic interaction, functional groups, hydrogen bonding, and electrostatic interaction govern the adsorption to a greater capacity. Although this commentary is not exhaustive, the preparation strategies and illustrated mechanisms provide useful insights into the adsorbent–adsorbate interactions, cost-effective analysis, challenges, and future directions of beta-cyclodextrin-based adsorbents in wastewater treatment.

Key words： beta-cyclodextrin adsorbent adsorption inclusion complex mechanism water pollutant wastewater treatment

收稿日期: 2021-07-28 出版日期: 2022-09-20

Corresponding Author(s): Muhammad Abbas Ahmad Zaini

引用本文:

. [J]. Frontiers of Chemical Science and Engineering, 2022, 16(9): 1407-1423.
Fadina Amran, Muhammad Abbas Ahmad Zaini. Beta-cyclodextrin adsorbents to remove water pollutants—a commentary. Front. Chem. Sci. Eng., 2022, 16(9): 1407-1423.

链接本文:

https://academic.hep.com.cn/fcse/CN/10.1007/s11705-022-2146-2
https://academic.hep.com.cn/fcse/CN/Y2022/V16/I9/1407

Fig.1

Fig.2

Fig.3

Fig.4

Adsorbent	Yield/%	Brunauer–Emmett–Teller surface area/(m²·g⁻¹)	Operating conditions (Temp, time, pH, Conc., dosage)	Model pollutant	Q_m/(mg·g⁻¹)	b/(L·mg⁻¹)	Ref.
Citric acid crosslinked β-CD	59.4	0.1	T = 25 °Ct = 2.33−31.7 hC_o = 1.50−219 mg·L⁻¹Dosage = 1 mg·mL⁻¹	Methylene blueCongo red	5.7612.5	0.4030.278	[5]
Citric acid crosslinked β-CD	56.1	0.1	T = 25 °Ct = 4.17−50 hC_o = 1.6−24.6 mg·L⁻¹pH = 7Dosage = 1 mg·mL⁻¹	Methylene blueReactive orange 16	2.188.78	−	[4]
Citric acid-crosslinked β-CD	66.9	0.81	T = 25 °Ct = 2.83−5 hC_o = 4−1000 mg·L⁻¹pH = 6Dosage = 1 mg·mL⁻¹	Bisphenol AMethylene blueCopper ions	82.924843.7	0.5660.4440.0765	[3]
Citric acid-crosslinked β-CD	30	−	T = 30 °Ct = 1.5 hC_o = 54.9 mg·L⁻¹Dosage = 4 mg·mL⁻¹	Aniline	4.4	−	[30]
Citric acid-crosslinked β-CD	65	−	T = 30 °Ct = 8.16−10.8 hC_o = 5−480 mg·L⁻¹Dosage = 4 mg·mL⁻¹	PhenolMethylene blue	13.8105	−	[23]
Crosslinked β-CD polymer	35	−	T = 25 °Ct = 40 minC_o = 22.8−228 mg·L⁻¹Dosage = 1 mg·mL⁻¹	Bisphenol A	113	0.133	[29]
Amphoteric β-CD-based adsorbent	−	−	T = 25 °Ct = 2−5 hC_o = 25−500 mg·L⁻¹pH = 4−11Dosage = 1 mg·mL⁻¹	Bisphenol AMethylene blueMethyl orange	79.0336166	0.03280.03470.0334	[32]
Crosslinked sawdust-β-CD polymers	72.4	0.11	T = 15 °Ct = 4 hC_o = 20−1200 mg·L⁻¹pH = 7Dosage = 5 mg·mL⁻¹	Aniline	84.0	−	[62]
Crosslinked 1,2,3,4-butanetetracarboxylic dianhydride/β-CD	−	−	T = 25 °Ct = 24 hC_o = 0−114 mg·L⁻¹Dosage = 1 mg·mL⁻¹	Bisphenol A	57.0	−	[35]
Ethylenediaminetetraacetic acid-crosslinked β-CD	−	−	T = 25 °Ct = 23.3 hC_o = 10−500 mg·L⁻¹pH = 6Dosage = 2 mg·mL⁻¹	Copper(II)Cadmium(II)Methylene blueSafranin OCrystal violet	78.912483.859.3114	0.2010.09680.08740.2120.0886	[12]
β-CD-derived polymer networks	64	< 10	T = 25 °Ct = 24 hC_o = 11.4−457 mg·L⁻¹Dosage = 0.8 mg·mL⁻¹	Bisphenol A	388	−	[36]
4,4’-(Hexafluoroisopropene) diphthalic acid-crosslinked β-CD	64	0.56	T = 25 °Ct = 3 hC_o = 20−200 mg·L⁻¹pH = 6Dosage = 1 mg·mL⁻¹	Bisphenol AMethylene blueNeutral red	51.7113107	1.74 × 10⁻⁵2.62 × 10⁻⁴8.16 × 10⁻⁵	[37]
β-CD/ tetrafluoroterephthalonitrile	−	21.1	T = 25 °Ct = 2 hC_o = 25−350 mg·L⁻¹pH = 6.7Dosage = 0.5 mg·mL⁻¹	Bisphenol AChloroxylenolCarbamazepine	164144136	0.0250.0280.013	[38]
Hyper-crosslinked β-CD	88	1209	T = 25 °Ct = 12 hC_o = 5−150 mg·L⁻¹Dosage = 0.25 mg·mL⁻¹	Bisphenol A	278	−	[31]
Porous β-CD polymer	20	263	T = 25 °Ct = 10 minC_o = 22.8 mg·L⁻¹Dosage = 1 mg·mL⁻¹	Bisphenol A	88	0.247	[43]
Ethylenediaminetetraa-cetic acid-crosslinked β-CD polymer grafted onto Fe-Al hydroxides	−	325	T = 30 °Ct = 5 hC_o = 40−180 mg·L⁻¹pH = 8Dosage = 2 mg·mL⁻¹	Methylene blue	81.3	5.38 × 10⁻⁵	[13]
β-CD grafted silica gel	27.2 g	−	T = 30 °Ct = 2 hC_o = 100−4000 mg·L⁻¹pH = 8.5Dosage = 10 mg·mL⁻¹	p-Nitrophenol	57.9	5.67 × 10⁻⁴	[44]
Magnetic molecularly imprinted polymer methacrylic acid-β-CD	−	92.1	T = 25 °Ct = 1 hC_o = 10−100 mg·L⁻¹pH = 8Dosage = 2 mg·mL⁻¹	Bisphenol A	66.2	0.147	[46]
β-CD/chitosan functionalized graphene oxide hydrogel	−	17.6	T = 25 °C t = 4 hC_o = 50−300 mg·L⁻¹ pH = 12Dosage = 0.2 mg·mL⁻¹	Methylene blue	1499	0.035	[16]
Graphene oxide-β-CD nanocomposite	−	−	T = 25 °Ct = 20 minC_o = 100−200 mg·L⁻¹pH = 9Dosage = 0.4 mg·mL⁻¹	Bisphenol A	373	4.25	[28]
Crosslinked chitosan/β-CD composite	−	−	T = 25 °Ct = 10 hC_o = 25−700 mg·L⁻¹pH = 5Dosage = 0.2 mg·mL⁻¹	Methyl orange	392	0.0812	[11]
Graphene/β-CD composite	−	−	T = 25 °Ct = 35 minC_o = 5−1000 mg·L⁻¹Dosage = 1 mg·mL⁻¹	PhenolphthaleinMethylene blueMethyl orangeBasic fuchsin	469580328426	0.065−−−	[7]
β-CD/poly(acrylic acid)/graphene oxide nanocomposite	−	−	T = 25 °Ct = 2.5 hC_o = 5−200 mg·L⁻¹pH = 8Dosage = 0.7 mg·mL⁻¹	Methylene blueSafranine T	262189	0.1340.0523	[47]
Nanosilica-supported poly β-CD	−	−	T = 25 °Ct = 1.33 hC_o = 20−100 mg·L⁻¹pH = 7Dosage = 1 mg·mL⁻¹	Bromophenol blueCrystal violet	41.234.5	1.07 × 10⁻³0.0125	[48]
β-CD-glycine- modified TiO₂ nanoparticles	−	146	T = 25 °Ct = 1 hC_o = 20−100 mg·L⁻¹pH = 5?9Dosage = 1 mg·mL⁻¹	Methylene blueMethyl orangeAcid blue 113Disperse red 1	82.038576.9139	0.1970.0110.2140.533	[8]
β-CD/citric acid/ polydopamine composite	−	6.52	T = 25 °Ct = 12 hC_o = 100−500 mg·L⁻¹pH = 5−5.5Dosage = 1 mg·mL⁻¹	Methylene blueMalachite greenCrystal violetCopper ion	583117447373.6	0.03810.00320.00430.196	[49]
Magnetic β-CD stabilized Fe₃S₄ nanoparticles	−	−	T = 25 °Ct = 24 hC_o = 5−500 mg·L⁻¹pH = 6Dosage = 0.6 mg·mL⁻¹	Lead(II)	256	0.049	[63]
β-CD-chitosan modified Fe₃O₄ nanoparticles	−	−	T = 30 °Ct = 50 minC_o = 2000−5000 mg·L⁻¹pH = 5Dosage = 0.6 mg·mL⁻¹	Methylene blue	2780	−	[14]
Magnetic β-CD/ graphene oxide nanocomposite	−	451	T = 25 °Ct = 50 minC_o = 10−100 mg·L⁻¹pH = 7Dosage = 1 mg·mL⁻¹	Chromium ion	120	−	[9]
Magnetic β-CD- chitosan/graphene oxide	−	402	T = 25 °Ct = 1.33 hC_o = 5−120 mg·L⁻¹Dosage = 0.4 mg^·mL⁻¹	Methylene blue	84.3	−	[10]
Carboxymethyl-β-CD modified Fe₃O₄ nanoparticles	−	111	T = 25 °Ct = 4 hC_o = 50−400 mg·L⁻¹pH = 6Dosage = 12 mg·mL⁻¹	Copper ions	47.2	0.0237	[52]
Carboxymethyl-β-CD conjugated magnetic nanoparticles	−	−	T = 25 °Ct = 2−2.5 hC_o = 100−3000 mg·L⁻¹pH = 12Dosage = 26 mg·mL⁻¹	Methylene blue	278	9.00 × 10⁻³	[53]
Carboxymethyl-β-CD modified Fe₃O₄ nanoparticles	60	−	T = 25 °C t = 4 hC_o = 50−400 mg·L⁻¹pH = 5.5Dosage = 12 mg·mL⁻¹	LeadCadmiumNickel	64.527.713.2	0.4170.2140.043	[6]
Magnetic β-CD-graphene oxide nanocomposites	−	−	T = 45 °Ct = 2 hC_o = 50−700 mg·L⁻¹pH = 7Dosage = 0.25 mg·mL⁻¹	Malachite green	990	0.0099	[15]
Ammonium β-CD-conjugatedmagnetic nanoparticles	−	72.3	T = 40 °Ct = 2.5−3.33 hC_o = 5−250 mg·L⁻¹pH = 6.8Dosage = 0.6 mg·mL⁻¹	Congo redChromium(VI)	877196	3.00 × 10⁻⁵5.1 × 10⁻³	[54]
Magnetic copper-based metal-organic framework	−	250	T = 25 °Ct = 2 hC_o = 0.5−100 mg·L⁻¹Dosage = 5 mg·mL⁻¹	ThiamethoxamImidacloparidAcetamipridNitenpyramDinotefuranClothianidin	2.883.112.962.561.772.88	−	[51]

Tab.1

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