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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

Postal Subscription Code 80-969

2018 Impact Factor: 2.809

Front Chem Eng Chin    2009, Vol. 3 Issue (1) : 112-118    https://doi.org/10.1007/s11705-009-0149-x
RESEARCH ARTICLE
A novel composite coating mesh film for oil-water separation
Futao QIN, Zhijia YU(), Xinhui FANG, Xinghua LIU, Xiangyu SUN
School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China
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Abstract

Polytetrafluoroethylene-polyphenylene sulfide composite coating mesh film was successfully prepared by a simple layered transitional spray-plasticizing method on a stainless steel mesh. It shows super-hydrophobic and super-oleophilic properties. The contact angle of this mesh film is 156.3° for water, and close to 0° for diesel oil and kerosene. The contact angle hysteresis of water on the mesh film is 4.3°. The adhesive force between the film and substrate is grade 0, the flexibility is 1 mm and the pencil hardness is 4H. An oil-water separation test was carried out for oil-contaminated water in a six-stage super-hydrophobic film separator. The oil removal rate can reach about 99%.

Keywords super-hydrophobic      super-oleophilic      composite coating      mesh film      separation of oil and water     
Corresponding Author(s): YU Zhijia,Email:yuzhijia@dl.cn   
Issue Date: 05 March 2009
 Cite this article:   
Futao QIN,Zhijia YU,Xinhui FANG, et al. A novel composite coating mesh film for oil-water separation[J]. Front Chem Eng Chin, 2009, 3(1): 112-118.
 URL:  
https://academic.hep.com.cn/fcse/EN/10.1007/s11705-009-0149-x
https://academic.hep.com.cn/fcse/EN/Y2009/V3/I1/112
Fig.1  1 oily feed water tank; 2 pump; 3 flow meter; 4 oily feed water inlet; 5 oil outlet; 6 water outlet; 7 oil tank; 8 water tank
Flow chart of oil-water separation
Fig.2  1 oily feed water inlet; 2 mesh film; 3 water outlet; 4 oil outlet
Sketch of one-stage film separator
Fig.3  Relationship between pore diameters and the CA of water on the corresponding mesh film
Fig.4  (a) Digital photograph and (b) optical image of water droplet on the mesh film
Fig.5  (a)-(f)Processes of kerosene passing through the mesh film easily
Fig.6  (a) Firstly, a drop of water is dripped on the mesh film; (b)-(f) then some drops of kerosene are dripped on the water drop on the mesh film
test itemsPTFEPTFE-PPStest method
adhesive forcegrade 5grade 0GB/T 9286-1998
flexility1 mm1 mmGB/T 1731-93
pencil hardness4B4HGB/T 6739-1996
Tab.1  Feasibility test of PTFE-PPS composite coating mesh films
concentrationperformancehydrophobicityoleophilicity
H2SO498%??
HCl30%??
HNO365%??
HF40%?
CH3COOH36%?
NH3·H2O25%??
NaOH50%?
Acetone-?
Kerosene-?
Diesel oil-?
Atmosphere-?
Tab.2  Corrosion resistance test results of mesh films (being immersed in different solution for 60 days)
Fig.7  Oil removal rate vs. the number of separation stage for different content of oil in feed
Fig.8  SEM images of the prepared mesh film
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