. School of Energy Resource, China University of Geosciences (Beijing), Beijing 100083, China . Coal Reservoir Laboratory of National Engineering Research Center of Coalbed Methane Development and Utilization, Beijing 100083, China . Beijing Key Laboratory of Unconventional Natural Gas Geological Evaluation and Development Engineering, Beijing 100083, China . China Petroleum Exploration and Development Research Institute, Langfang 065000, China
An improved evaluation method for estimating gas content during the inversion process of deep-burial coal was established based on the on-site natural desorption curves. The accuracy of the US Bureau of Mines (USBM), Polynomial fitting, Amoco, and the improved evaluation methods in the predicting of lost gas volume in deep seams in the Mabidong Block of the Qinshui Basin were then compared. Furthermore, the calculation errors of these different methods in simulating lost gas content based on coring time were compared. A newly established nonlinear equation was developed to estimate the minimum error value, by controlling the lost time within 16 min, the related errors can be reduced. The improved evaluation was shown to accurately and rapidly predict the gas content in deep seams. The results show that the deep coal bed methane accumulation is influenced by various factors, including geological structure, hydrodynamic conditions, roof lithology, and coalification. Reverse faults and weak groundwater runoff can hinder the escape of methane, and these factors should be considered in the future exploration and development of coalbed methane.
Online First Date: 23 July 2024Issue Date: 29 September 2024
Cite this article:
Haiqi LI,Shida CHEN,Dazhen TANG, et al. Gas content evaluation in deep coal seam with an improved method and its geological controls[J]. Front. Earth Sci.,
2024, 18(3): 623-636.
Fig.1 Geological background of the Qinshui Basin (modified from (Cai et al., 2014)). (a) Location of the basin. (b) Location of the Mabidong study area. (c) Composite stratigraphic columns in the Mabidong block.
Well Name
Number of samples collected
Number of gas content test samples
Industrial analysis and determination sample number
3#
15#
6
6
7
12
6-3-1, 6-15-1
16X
1
2
3
16X-3-1, 16X-15-1
27
6
4
10
27-3-1, 27-15-1
57
5
4
9
57-3-1, 57-15-1
58
7
4
11
58-3-1, 58-15-1
59
6
2
8
59-3-1, 59-15-1
66
5
5
10
66-3-1, 66-15-1
67
5
4
9
67-3-1, 67-15-1
69
4
3
7
69-3-1, 69-15-1
72
5
3
8
72-3-1, 72-15-1
2
7
3
10
2-3-1, 2-15-1
Tab.1 Sample collection and testing information table
Fig.2 Natural desorption device (AQSIQ , 2008): 1. thermostat power supply, 2. thermostatic device, 3. desorption tank, 4. tank cover, 5. air valve, 6. pressure gauge, 7. quick connector, 8. exhaust pipe, 9. conical bottle, 10. air valve, 11. drain pipe. 12. measuring cylinder, 13. meter bases and stands.
Fig.3 Lost gas estimation at different time zeros.
Calculation standard
Lost gas content/cm3
6-3-1
6-3-2
6-3-3
6-3-4
6-3-5
6-3-6
T1-1
860.68
694.53
720.39
339.57
491.6
1701.47
T1-2
1445.99
1296.25
4336.5
806.41
982.29
3256.28
T2-1
500.62
442.3
421.8
162.43
166.13
410.04
T2-2
831.19
762.06
2203.69
398.07
405.3
1034.87
Tab.2 Estimation of lost gas content under different calculation standards
Fig.4 Calculation of lost gas content by (a) polynomial fitting method, (b) Amoco method.
Fig.5 Gas content evaluation by the improved evaluation.
Fig.6 6-3-1 Sample isothermal adsorption test.
Fig.7 Relationship between desorption rate and the square root of desorption time for coal samples with different buried depths.
Fig.8 Extrapolation calculation of lost gas for simulating different lost time.
Fig.9 Lost gas error of different curve fitting methods.
Fig.10 Comparison of lost gas content calculated using different methods.
Fig.11 Total gas content by different estimation methods.
Fig.12 Correlation between Ro, max and gas content.
Fig.13 Effect of (a) moisture, (b) ash yield, (c) volatile matter, and (d) gross calorific to the gas content.
Fig.14 Relationship of (a) burial depth and (b) coal thickness with gas content.
Fig.15 Groundwater dynamic zoning map in the study area.
Fig.16 The control of lithology and tectonics on gas content in the study area. Relationship between roof and floor lithology and gas content: (a) 3#, (b) 15,. (c) Control of tectonics.
1
AQSIQ S A C (2008). Method of Determining Coalbed Gas Content: GB/T 19559–2008. Bejing: China Standard Press
2
C, Bertard B, Bruyet J Gunther (1970). Determination of desorbable gas concentration of coal (direct method).Int J Rock Mech Min Sci Geomech Abstr, 7(1): 43–65 https://doi.org/10.1016/0148-9062(70)90027-6
3
A M M, Bustin R M Bustin (2016). Total gas-in-place, gas composition and reservoir properties of coal of the Mannville coal measures, Central Alberta.Int J Coal Geol, 153: 127–143 https://doi.org/10.1016/j.coal.2015.11.011
4
C I, Butland T A Moore (2008). Secondary biogenic coal seam gas reservoirs in New Zealand: a preliminary assessment of gas contents.Int J Coal Geol, 76(1−2): 151–165 https://doi.org/10.1016/j.coal.2008.05.017
5
Y, Cai D, Liu Y, Yao J, Li Y Qiu (2011). Geological controls on prediction of coalbed methane of No. 3 coal seam in Southern Qinshui Basin, north China.Int J Coal Geol, 88(2−3): 101–112 https://doi.org/10.1016/j.coal.2011.08.009
6
Y, Cai D, Liu K, Zhang D, Elsworth Y, Yao D Tang (2014). Preliminary evaluation of gas content of the No. 2 coal seam in the Yanchuannan area, southeast Ordos Basin, China.J Petrol Sci Eng, 122: 675–689 https://doi.org/10.1016/j.petrol.2014.09.010
7
L, Cao Y, Yao C, Cui Q Sun (2020). Characteristics of in-situ stress and its controls on coalbed methane development in the southeastern Qinshui Basin, north China.Energy Geosci, 1(1−2): 69–80 https://doi.org/10.1016/j.engeos.2020.05.003
8
S, Chen S, Tao W, Tian D, Tang B, Zhang P Liu (2021). Hydrogeological control on the accumulation and production of coalbed methane in the Anze Block, southern Qinshui Basin, China.J Petrol Sci Eng, 198: 108138 https://doi.org/10.1016/j.petrol.2020.108138
9
X, Chen L, Li Y, Yuan H Li (2020). Effect and mechanism of geological structures on coal seam gas occurrence in Changping minefield.Energy Sci Eng, 8(1): 104–115 https://doi.org/10.1002/ese3.512
10
L D, Connell Z, Pan M Camilleri (2019). The variation in produced gas composition from mixed gas coal seam reservoirs.Int J Coal Geol, 201: 62–75 https://doi.org/10.1016/j.coal.2018.11.011
11
L, Dai H, Lei X, Cheng R Li (2023). Prediction of coal seam gas content based on the correlation between gas basic parameters and coal quality indexes.Front Energy Res, 10: 1096539 https://doi.org/10.3389/fenrg.2022.1096539
12
W, Dang J C, Zhang X, Tang X L, Wei Z M, Li C H, Wang Q, Chen C Liu (2018). Investigation of gas content of organic-rich shale: a case study from Lower Permian shale in southern north China Basin, central China.Geosci Front, 9(2): 559–575 https://doi.org/10.1016/j.gsf.2017.05.009
13
Z, Deng H, Wang Z, Jiang F, Tian R, Ding S, Hou W, Li Y, Li J, Zhu L, Li X Wang (2023). Interpretation method for lost gas in deep coalbed and its application.Processes (Basel), 11(1): 200 https://doi.org/10.3390/pr11010200
H, Fu D, Tang H, Xu T, Xu B, Chen P, Hu Z, Yin P, Wu G He (2016). Geological characteristics and CBM exploration potential evaluation: a case study in the middle of the southern Junggar Basin, NW China.J Nat Gas Sci Eng, 30: 557–570 https://doi.org/10.1016/j.jngse.2016.02.024
16
X, Fu Y, Qin G G, Wang V Rudolph (2009). Evaluation of gas content of coalbed methane reservoirs with the aid of geophysical logging technology.Fuel, 88(11): 2269–2277 https://doi.org/10.1016/j.fuel.2009.06.003
17
T, Gentzis D, Schoderbek S Pollock (2006). Evaluating the coalbed methane potential of the Gething coals in NE British Columbia, Canada: an example from the Highhat area, Peace River coalfield.Int J Coal Geol, 68(3−4): 135–150 https://doi.org/10.1016/j.coal.2006.02.001
18
S D, Golding C J, Boreham J S Esterle (2013). Stable isotope geochemistry of coal bed and shale gas and related production waters: a review.Int J Coal Geol, 120: 24–40 https://doi.org/10.1016/j.coal.2013.09.001
19
S Hemmings-Sykes (2012). The Influence of Faulting on Hydrocarbon Migration in the Kupe Area, South Taranaki Basin, New Zealand. Dissertation for Master’s Degree. Wellington: Victoria University of Wellington
20
X, Hou S, Liu Y, Zhu Y Yang (2020). Evaluation of gas contents for a multi-seam deep coalbed methane reservoir and their geological controls: in situ direct method versus indirect method.Fuel, 265: 116917 https://doi.org/10.1016/j.fuel.2019.116917
21
K, Jin Y, Cheng L, Wang J, Dong P, Guo F, An L Jiang (2015). The effect of sedimentary redbeds on coalbed methane occurrence in the Xutuan and Zhaoji Coal Mines, Huaibei Coalfield, China.Int J Coal Geol, 137: 111–123 https://doi.org/10.1016/j.coal.2014.11.009
S, Kędzior M J, Kotarba Z Pękała (2013). Geology, spatial distribution of methane content and origin of coalbed gases in Upper Carboniferous (Upper Mississippian and Pennsylvanian) strata in the south-eastern part of the Upper Silesian Coal Basin, Poland.Int J Coal Geol, 105: 24–35 https://doi.org/10.1016/j.coal.2012.11.007
24
E C P, Kinnon S D, Golding C J, Boreham K A, Baublys J S Esterle (2010). Stable isotope and water quality analysis of coal bed methane production waters and gases from the Bowen Basin, Australia.Int J Coal Geol, 82(3−4): 219–231 https://doi.org/10.1016/j.coal.2009.10.014
25
F N Kissell, C M McCulloch, C H Elder (1973). The direct method of determining methane content of coalbeds for ventilation design. US Department of Interior, Bureau of Mines
26
H, Lei L, Dai J, Cao R, Li B Wang (2023). Experimental study on rapid determination method of coal seam gas content by indirect method.Processes (Basel), 11(3): 925 https://doi.org/10.3390/pr11030925
27
Q, Li X, Pang L, Tang G, Chen X, Shao N Jia (2018a). Occurrence features and gas content analysis of marine and continental shales: a comparative study of Longmaxi Formation and Yanchang Formation.J Nat Gas Sci Eng, 56: 504–522 https://doi.org/10.1016/j.jngse.2018.06.019
28
S, Li D, Tang Z, Pan H, Xu S, Tao Y, Liu P Ren (2018b). Geological conditions of deep coalbed methane in the eastern margin of the Ordos Basin, China: implications for coalbed methane development.J Nat Gas Sci Eng, 53: 394–402 https://doi.org/10.1016/j.jngse.2018.03.016
29
W, Li X, Li S, Zhao J, Li S, Lu Y, Liu S, Huang Z, Wang J Wang (2022). Evaluation on carbon isotope fractionation and gas-in-place content based on pressure-holding coring technique.Fuel, 315: 123243 https://doi.org/10.1016/j.fuel.2022.123243
30
X, Lin C, Liu Z Wang (2023). The influencing factors of gas adsorption behaviors in shale gas reservoirs.Front Earth Sci (Lausanne), 10: 1021983 https://doi.org/10.3389/feart.2022.1021983
31
S, Liu S Harpalani (2013). Permeability prediction of coalbed methane reservoirs during primary depletion.Int J Coal Geol, 113: 1–10 https://doi.org/10.1016/j.coal.2013.03.010
32
X, Luo X, Zhang L, Zhang G Huang (2017). Visualization of Chinese CBM research: a scientometrics review.Sustainability (Basel), 9(6): 980 https://doi.org/10.3390/su9060980
33
M J Mavor, L B Owen, T J Pratt (1990). Measurement and evaluation of coal sorption isotherm data. ln: SPE Annual Technical Conference and Exhibition 10.2118/20728-MS
34
R S Metcalfe, D Yee, J P Seidle, R Puri (1991). Review of research efforts in coalbed methane recovery. In: SPE Asia-Pacific Conference
35
F, Miao D, Wu X, Liu X, Xiao W, Zhai Y Geng (2022). Methane adsorption on shale under in situ conditions: gas-in-place estimation considering in situ stress.Fuel, 308: 121991 https://doi.org/10.1016/j.fuel.2021.121991
36
C, Ou C, Li D, Zhi L, Xue S Yang (2018). Coupling accumulation model with gas-bearing features to evaluate low-rank coalbed methane resource potential in the southern Junggar Basin, China.AAPG Bull, 102(1): 153–174 https://doi.org/10.1306/03231715171
37
Y, Qin T A, Moore J, Shen Z, Yang Y, Shen G Wang (2018). Resources and geology of coalbed methane in China: a review.Int Geol Rev, 60(5−6): 777–812 https://doi.org/10.1080/00206814.2017.1408034
38
A Saghafi (2017). Discussion on determination of gas content of coal and uncertainties of measurement.Int J Min Sci Technol, 27(5): 741–748 https://doi.org/10.1016/j.ijmst.2017.07.024
E, Shtepani L A, Noll L W, Elrod P M Jacobs (2010). A new regression-based method for accurate measurement of coal and shale gas content.SPE Reservoir Eval Eng, 13(2): 359–364 https://doi.org/10.2118/115405-PA
J, Teng Y, Yao D, Liu Y Cai (2015). Evaluation of coal texture distributions in the southern Qinshui Basin, north China: investigation by a multiple geophysical logging method.Int J Coal Geol, 140: 9–22 https://doi.org/10.1016/j.coal.2014.12.014
43
N B, Waechter G L, Hampton J C Shipps (2004). Overview of coal and shale gas measurement: field and laboratory procedures.ln: International Coalbed Methane Symposium: University of Alabama, Tuscaloosa: Alabama
44
D, Wang Y, Cheng L, Yuan C, Wang L Wang (2023). Implications of geological conditions on gas contents: a case study in the Pingdingshan Coalfield.Energy Fuels, 37(9): 6465–6478 https://doi.org/10.1021/acs.energyfuels.2c04374
45
G, Wang Y, Qin Y, Xie J, Shen B, Wang L, Du J Guo (2018a). The spatial distribution of CBM systems under the control of structure and sedimentation: the Gujiao Block as an example.J Geol Soc India, 92(6): 721–731 https://doi.org/10.1007/s12594-018-1095-3
46
L, Wang L B, Cheng Y P, Cheng S, Liu P K, Guo K, Jin H Jiang (2015). A new method for accurate and rapid measurement of underground coal seam gas content.J Nat Gas Sci Eng, 26: 1388–1398 https://doi.org/10.1016/j.jngse.2015.08.020
47
Y, Wang D, Liu Y, Cai Y, Yao Y Zhou (2018b). Evaluation of structured coal evolution and distribution by geophysical logging methods in the Gujiao Block, northwest Qinshui Basin, China.J Nat Gas Sci Eng, 51: 210–222 https://doi.org/10.1016/j.jngse.2018.01.022
48
P D, Warwick F C Jr, Breland P C Hackley (2008). Biogenic origin of coalbed gas in the northern Gulf of Mexico Coastal Plain, USA.Int J Coal Geol, 76(1−2): 119–137 https://doi.org/10.1016/j.coal.2008.05.009
C, Yang F, Qiu F, Xiao S, Chen Y Fang (2023). CBM gas content prediction model based on the ensemble tree algorithm with Bayesian hyper-parameter optimization method: a case study of Zhengzhuang Block, southern Qinshui Basin, north China.Processes (Basel), 11(2): 527 https://doi.org/10.3390/pr11020527
51
Y, Yang S Liu (2019). Estimation and modeling of pressure-dependent gas diffusion coefficient for coal: a fractal theory-based approach.Fuel, 253: 588–606 https://doi.org/10.1016/j.fuel.2019.05.009
52
S, Zhao S, Lu J, Wu W, Li Y, Liu J, Li J, Zhang Z, Xia S Huang (2023). Comparison and verification of gas-bearing parameter evaluation methods for deep shale based on the pressure coring technique.Energy Fuels, 37(3): 2066–2077 https://doi.org/10.1021/acs.energyfuels.2c03840
53
W, Zhao Y, Cheng Z, Pan K, Wang S Liu (2019). Gas diffusion in coal particles: a review of mathematical models and their applications.Fuel, 252: 77–100 https://doi.org/10.1016/j.fuel.2019.04.065
54
C J, Zhu B Q Lin (2015). Effect of igneous intrusions and normal faults on coalbed methane storage and migration in coal seams near the outcrop.Nat Hazards, 77(1): 17–38 https://doi.org/10.1007/s11069-014-1577-6