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Frontiers of Environmental Science & Engineering

ISSN 2095-2201

ISSN 2095-221X(Online)

CN 10-1013/X

Postal Subscription Code 80-973

2018 Impact Factor: 3.883

Front. Environ. Sci. Eng.    2021, Vol. 15 Issue (6) : 111    https://doi.org/10.1007/s11783-021-1400-z
RESEARCH ARTICLE
Performance evaluation on the pollution control against wet weather overflow based on on-site coagulation/flocculation in terminal drainage pipes
Zongqun Chen1, Wei Jin1(), Hailong Yin1, Mengqi Han1, Zuxin Xu1,2
1. College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
2. Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
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Abstract

• A way for overflow control based on on-site coagulation/flocculation was proposed.

• Coagulant and flocculant dose were optimized based on pollutant removal performance.

• Settling time of 5 min is enough in a proper transmission distance.

• Fast removal of particulate pollutants could be achieved under varied flow.

The pollution caused by wet weather overflow in urban drainage systems is a main factor causing blackening an odorization of urban rivers. The conventional overflow treatment based on coagulation/flocculation in terminal drainage systems requires relatively large space and long retention time demand that makes it not applicable in crowded urban drainage systems or under heavy rains. On-site coagulation/flocculation in terminal drainage pipes was proposed in this study which was aimed to transfer the coagulation/flocculation process to the inside of pipes at the terminal drainage system to save space and reduce the retention time of the coagulation/flocculation process. The optimized dose of chemicals was studied first which was 80 mg/L of coagulant and 0.8 mg/L of flocculant. Settling for only 5 min can remove most of the pollutants at 406.5 m of transmission distance. In addition, the relation of wet weather overflow rate and concentration of pollution load on the on-site coagulation/flocculation process was investigated, which indicated that high removal of pollutant was gained at a large range of flow velocity and pollutant concentration. Finally, the study confirmed electric neutralization, bridging, and net capture as the major mechanisms in this process, and further optimization was proposed. The proposed process can reduce much turbidity, chemical oxygen demand, and total phosphorous, but hardly remove soluble ammonia and organics. This work provides scientific guidance to address wet weather overflow in terminal drainage pipes.

Keywords Wet weather overflow      On-site coagulation/flocculation      Fast removal of particulate pollutants     
Corresponding Author(s): Wei Jin   
Issue Date: 11 February 2021
 Cite this article:   
Zongqun Chen,Wei Jin,Hailong Yin, et al. Performance evaluation on the pollution control against wet weather overflow based on on-site coagulation/flocculation in terminal drainage pipes[J]. Front. Environ. Sci. Eng., 2021, 15(6): 111.
 URL:  
https://academic.hep.com.cn/fese/EN/10.1007/s11783-021-1400-z
https://academic.hep.com.cn/fese/EN/Y2021/V15/I6/111
Fig.1  The concept diagram of on-site coagulation/flocculation treatment of wet weather overflow in terminal drainage pipes.
Fig.2  Removals of turbidity, TCOD, TP and NH4+-N in simulated wastewater at different dosage of coagulant and flocculant (The mass ratio of PAS and APAM was 100:1. SS, turbidity, TCOD, TP and NH4+-N concentrations of original simulated water were 372.5 mg/L, 126.6 NTU, 334.0 mg/L, 3.28 mg/L and 13.43 mg/L).
Fig.3  The removal rates of turbidity (a), TCOD (b) and TP (c) with different reaction time (axis X) and settling time (axis Y) (flow velocity= 1.13 m/s; orange, green, blue, red and yellow dots refer to removal rates of pollutants at 2 min, 4 min, 6 min, 8 min and 10 min of reaction time respectively. SS, turbidity, TCOD, SCOD, TP and NH4+-N of the original simulated water were 436–487 mg/L, 170.2–199.5 NTU, 321.0–369.0 mg/L, 118.0–133.0 mg/L, 3.97–4.30 mg/L and 12.96–14.31 mg/L; and pH was 7.22–7.53).
Fig.4  The changes of turbidity (a), TCOD (b), TP (c), and NH4+-N (d) before and after reaction at different flow velocities and corresponding removal rates (The initial concentration of SS, turbidity, TCOD, SCOD, TP and NH4+-N were in the range of 456–497 mg/L, 165.8–186.3 NTU, 377.0–440.0 mg/L, 136.0–142.0 mg/L, 2.73–3.42 mg/L and 10.40–11.63 mg/L, and pH was at 7.44–7.65).
Fig.5  The changes of turbidity (a), TCOD (b), and TP (c) before and after reaction at different pollutant concentrations and the corresponding removal rates (SS, turbidity, TCOD, SCOD, TP and NH4+-N of the initial simulated water were in the range of 210.0–1618.0 mg/L, 95.7–701 NTU, 229.0–1035.0 mg/L, 136.0–151.0 mg/L, 3.10–5.88 mg/L and 10.61–11.50 mg/L, and the pH was at 7.44–7.75).
Fig.6  (a) Changes of zeta potential and pH, and (b) removal rates of turbidity, TCOD and TP at different PAS dosages (the mass ratio of PAS and APAM was 100:1).
Fig.7  Volume equivalent D50 and average particle diameter after adding different doses of APAM. (a)–(e) are the flocs formed with dose of APAM of SS0–2 mg/L (PAS was 100 mg/L).
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