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Frontiers of Environmental Science & Engineering

ISSN 2095-2201

ISSN 2095-221X(Online)

CN 10-1013/X

Postal Subscription Code 80-973

2018 Impact Factor: 3.883

Front. Environ. Sci. Eng.    2023, Vol. 17 Issue (8) : 98    https://doi.org/10.1007/s11783-023-1698-9
RESEARCH ARTICLE
Water quality prediction of copper-molybdenum mining-beneficiation wastewater based on the PSO-SVR model
Xiaohua Fu1, Qingxing Zheng1,2, Guomin Jiang3, Kallol Roy4, Lei Huang5, Chang Liu2, Kun Li6,7, Honglei Chen1, Xinyu Song1,2, Jianyu Chen2, Zhenxing Wang2()
1. Ecological Environment Management and Assessment Center, Central South University of Forestry and Technology, Changsha 410004, China
2. State Environmental Protection Key Laboratory of Water Environmental Simulation and Pollution Control, South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
3. Chinese Non-Ferrous Industrial Engineering Center of Pollution Control Technology & Equipment, Science Environment Protection Co., Ltd., Changsha 410036, China
4. Institute of Computer Science, University of Tartu, Tartu 51009, Estonia
5. School of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China
6. A.B Freeman School of Business, Tulane University, New Orleans, LA 70118, USA
7. Guangzhou Huacai Environmental Protection Technology Co., Ltd., Guangzhou 511480, China
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Abstract

● Data acquisition and pre-processing for wastewater treatment were summarized.

● A PSO-SVR model for predicting CODeff in wastewater was proposed.

● The CODeff prediction performances of the three models in the paper were compared.

● The CODeff prediction effects of different models in other studies were discussed.

The mining-beneficiation wastewater treatment is highly complex and nonlinear. Various factors like influent quality, flow rate, pH and chemical dose, tend to restrict the effluent effectiveness of mining-beneficiation wastewater treatment. Chemical oxygen demand (COD) is a crucial indicator to measure the quality of mining-beneficiation wastewater. Predicting COD concentration accurately of mining-beneficiation wastewater after treatment is essential for achieving stable and compliant discharge. This reduces environmental risk and significantly improves the discharge quality of wastewater. This paper presents a novel AI algorithm PSO-SVR, to predict water quality. Hyperparameter optimization of our proposed model PSO-SVR, uses particle swarm optimization to improve support vector regression for COD prediction. The generalization capacity tested on out-of-distribution (OOD) data for our PSO-SVR model is strong, with the following performance metrics of root means square error (RMSE) is 1.51, mean absolute error (MAE) is 1.26, and the coefficient of determination (R2) is 0.85. We compare the performance of PSO-SVR model with back propagation neural network (BPNN) and radial basis function neural network (RBFNN) and shows it edges over in terms of the performance metrics of RMSE, MAE and R2, and is the best model for COD prediction of mining-beneficiation wastewater. This is because of the less overfitting tendency of PSO-SVR compared with neural network architectures. Our proposed PSO-SVR model is optimum for the prediction of COD in copper-molybdenum mining-beneficiation wastewater treatment. In addition, PSO-SVR can be used to predict COD on a wide variety of wastewater through the process of transfer learning.

Keywords Chemical oxygen demand      Mining-beneficiation wastewater treatment      Particle swarm optimization      Support vector regression      Artificial neural network     
Corresponding Author(s): Zhenxing Wang   
Issue Date: 13 March 2023
 Cite this article:   
Xiaohua Fu,Qingxing Zheng,Guomin Jiang, et al. Water quality prediction of copper-molybdenum mining-beneficiation wastewater based on the PSO-SVR model[J]. Front. Environ. Sci. Eng., 2023, 17(8): 98.
 URL:  
https://academic.hep.com.cn/fese/EN/10.1007/s11783-023-1698-9
https://academic.hep.com.cn/fese/EN/Y2023/V17/I8/98
Fig.1  Process flow of copper-molybdenum mining-beneficiation wastewater treatment.
Water quality indexUnitMaximumMinimumAverageStandard deviationRelative standard deviation
CODinfmg/L1619.0000182.2000619.8353139.79880.2255
Q#4acidm3/h1835.00000.0000772.4429386.47390.5003
Q#4alkm3/h1629.83330.0000618.9781187.41610.3028
Q#1acidm3/h1591.50000.0000724.7367291.91310.4028
Q#1alkm3/h5994.08330.0000633.8186322.22140.5084
CODsmg/L74.750013.500033.514110.24970.3058
CODnmg/L108.000010.100032.896310.14060.3083
ORP#5mV599.5000101.8000370.238677.78860.2101
ORP#2mV708.8000110.2000387.952073.80820.1903
pH#510.41001.43004.69201.28140.2731
pH#28.90002.16004.32931.14180.2637
Oxidantuct/h4.65002.00003.87310.37180.0960
CODeffmg/L74.200016.800030.58727.14880.2337
Tab.1  Data analysis of key water quality indicator variables in mining-beneficiation wastewater treatment
Fig.2  Flow of SVR prediction model based on PSO algorithm.
Fig.3  Prediction results of CODeff based on PSO-SVR model. (a) PSO-SVR model fitting simulation results. (b) PSO-SVR model prediction error distribution. (c) Scatter plot between measured and predicted values of CODeff in PSO-SVR model.
ModelRMSEMAER2
BPNN2.802.210.50
RBFNN2.361.820.64
PSO-SVR1.521.260.85
Tab.2  Comparison of prediction accuracy of different models
Fig.4  Prediction results of CODeff of each model. (a) The simulation results of each model fitting. (b) Prediction error distribution of each model. (c) Scatter plot between measured and predicted values of CODeff in each model.
Research objectPrediction algorithmModel accuracyCommentReferences
RMSEMAER2
Papermaking wastewaterCSWLSTM2.682.050.83The CSWLSTM model had the best performance for COD prediction.Wan et al. (2022)
SWLSTM5.354.050.33
CLSTM3.792.910.67
CGRU3.182.320.77
Papermaking wastewaterPLS4.550.59Compared with other models, DKELM has improved prediction performance and higher fitting performance.Liu et al. (2020)
ELM4.370.63
DELM4.360.69
KELM3.680.68
DKELM3.500.76
Papermaking wastewaterBPNN4.160.61The COD prediction effect of GA-DBN was the best, but there was still much room for improvement in prediction accuracy.Niu et al. (2020)
DBN4.000.63
GA-DBN3.970.65
Papermaking wastewaterDBN3.830.79VIP-DBN improved the problem of insufficient COD prediction accuracy of papermaking wastewater.Zhang et al. (2021)
VIP-DBN3.080.88
Domestic wastewaterSDAE5.944.80SDAE had the tremendous potential for COD prediction in 5 prediction models.Shi and Xu (2018)
Thermal power plant wastewaterANN59.480.95Compared with M5, ANN significantly improved the prediction effect of COD.Asami et al. (2021)
M5 model tree63.390.90
Sewage treatment plants wastewaterABR9.767.98The comprehensive comparison showed that the GBR model had the best performance in predicting COD.Sharafati et al. (2020)
GBR9.657.84
RFR8.1310.11
Sewage treatment plants wastewaterANN0.0950.0220.55The COD prediction performance of the GBM algorithm was slightly better than the remaining models.Bagherzadeh et al. (2021)
RF0.0950.0190.55
GBM0.0920.0170.58
Copper-molybdenum mining-beneficiation wastewaterBPNN2.802.210.50PSO-SVR model showed the best water quality prediction effect.This paper
RBFNN2.361.820.64
PSO-SVR1.521.260.85
Tab.3  Summary of different studies on COD prediction of wastewater treatment effluent
Data expansion factorData setTest setPenalty coefficient CKernel function parameter gRMSEMAER2
2 times239412019.61530.49781.110.800.91
4 times47882403.60690.69290.680.540.97
6 times71823606.62710.78120.620.490.98
Tab.4  Optimal parameter settings and prediction accuracy comparison of PSO-SVR model for each augmented data
Fig.5  Prediction results of CODeff from PSO-SVR model with different expansion multiple data. (a) Prediction effect of PSO-SVR model after data expansion by 2 times. (b) Prediction error distribution of PSO-SVR model after data augmentation by 2 times. (c) Prediction effect of PSO-SVR model after data expansion by 4 times. (d) Prediction error distribution of PSO-SVR model after data augmentation by 4 times. (e) Prediction effect of PSO-SVR model after data expansion by 6 times. (f) Prediction error distribution of PSO-SVR model after data augmentation by 6 times. (g) Proportion of absolute errors in the prediction of data models with different expansion multiples in each numerical interval.
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