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Microcellular injection molding process for producing lightweight thermoplastic polyurethane with customizable properties |
Thomas ELLINGHAM1,2, Hrishikesh KHARBAS1,2, Mihai MANITIU3, Guenter SCHOLZ3, Lih-Sheng TURNG1,2() |
1. Department of Mechanical Engineering, University of Wisconsin-Madison, Madison, WI 53706, USA 2. Wisconsin Institute for Discovery, University of Wisconsin-Madison, Madison, WI 53715, USA 3. BASF Corporation, Wyandotte, MI 48192, USA |
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Abstract A three-stage molding process involving microcellular injection molding with core retraction and an “out-of-mold” expansion was developed to manufacture thermoplastic polyurethane into lightweight foams of varying local densities, microstructures, and mechanical properties in the same microcellular injection molded part. Two stages of cavity expansion through sequential core retractions and a third expansion in a separate mold at an elevated temperature were carried out. The densities varied from 0.25 to 0.42 g/cm3 (77% to 62% weight reduction). The mechanical properties varied as well. Cyclic compressive strengths and hysteresis loss ratios, together with the microstructures, were characterized and reported.
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Keywords
thermoplastic polyurethane
microcellular injection molding
cavity expansion
compressive strength
hysteresis loss ratio
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Corresponding Author(s):
Lih-Sheng TURNG
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Just Accepted Date: 12 December 2017
Online First Date: 09 January 2018
Issue Date: 23 January 2018
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1 |
Colton J S, Suh N P. The nucleation of microcellular thermoplastic foam with additives: Part I: Theoretical considerations. Polymer Engineering and Science, 1987, 27(7): 485–492
https://doi.org/10.1002/pen.760270702
|
2 |
Ames K A. Elastomers for shoe applications. Rubber Chemistry and Technology, 2004, 77(3): 413–475
https://doi.org/10.5254/1.3547832
|
3 |
Colton J S, Suh N P. Nucleation of microcellular foam: Theory and practice. Polymer Engineering and Science, 1987, 27(7): 500–503
https://doi.org/10.1002/pen.760270704
|
4 |
Lakes R S. Viscoelastic Materials. Cambridge: Cambridge University Press, 2009, 359–360
https://doi.org/10.1017/CBO9780511626722
|
5 |
Engels H W, Pirkl H G, Albers R, et al. Polyurethanes: Versatile materials and sustainable problem solvers for today’s challenges. Angewandte Chemie International Edition, 2013, 52(36): 9422–9441
https://doi.org/10.1002/anie.201302766
|
6 |
Okamoto K T. Microcellular Processing. Cincinnati: Hanser Publication, 2003
|
7 |
Anson M, Ko J M, Lam E S S. Advances in Building Technology. Amsterdam: Elsevier, 2002
|
8 |
Xu J. Microcellular Injection Molding. Hoboken: Wiley, 2011
|
9 |
Kharbas H A. Developments in microcellular injection molding technology. Dissertation for the Doctoral Degree. Madison: University of Wisconsin-Madison, 2003
|
10 |
Sun X, Turng L S. Novel injection molding foaming approaches using gas-laden pellets with N2, CO2, and N2 + CO2 as the blowing agents. Polymer Engineering and Science, 2014, 54(4): 899–913
https://doi.org/10.1002/pen.23630
|
11 |
Shaayegan V, Mark L H, Park C B, et al. Identification of cell-nucleation mechanism in foam injection molding with gas-counter pressure via mold visualization. American Institute of Chemical Engineers, 2016, 62(11): 4035–4046
https://doi.org/10.1002/aic.15433
|
12 |
Rizvi S J, Alaei M, Yadav A, et al. Quantitative analysis of cell distribution in injection molded microcellular foam. Journal of Cellular Plastics, 2014, 50(3): 199–219
https://doi.org/10.1177/0021955X14524081
|
13 |
Moon Y, Cha S W, Seo J. Bubble nucleation and growth in microcellular injection molding processes. Polymer-Plastics Technology and Engineering, 2008, 47(4): 420–426
https://doi.org/10.1080/03602550801898321
|
14 |
Nellis G, Klein S. Heat Transfer. Cambridge: Cambridge University Press, 2009, 137
|
15 |
Sun X, Turng L. Foam injection molding using nitrogen and carbon dioxide as co-blowing agents. Society of Plastics Engineers: Plastics Research Online, 2013, 2–4
https://doi.org/10.2417/spepro.005005
|
16 |
Sun X, Kharbas H, Peng J, et al. A novel method of producing lightweight microcellular injection molded parts with improved ductility and toughness. Polymer, 2015, 56: 102–110
https://doi.org/10.1016/j.polymer.2014.09.066
|
17 |
Sun X, Kharbas H, Turng L S. Fabrication of highly expanded thermoplastic polyurethane foams using microcellular injection molding and gas-laden pellets. Polymer Engineering and Science, 2015, 55(11): 2643–2652
https://doi.org/10.1002/pen.24157
|
18 |
Kharbas H A. Manufacturing highly expanded thermoplastic polyurethane foams using novel injection molding foaming technologies. Dissertation for the Doctoral Degree. Madison: University of Wisconsin-Madison, 2016
|
19 |
Qi H J J, Boyce M C C. Stress-strain behavior of thermoplastic polyurethanes. Mechanics of Materials, 2005, 37(8): 817–839
https://doi.org/10.1016/j.mechmat.2004.08.001
|
20 |
Gong L, Kyriakides S, Triantafyllidis N. On the stability of Kelvin cell foams under compressive loads. Journal of the Mechanics and Physics of Solids, 2005, 53(4): 771–794
https://doi.org/10.1016/j.jmps.2004.10.007
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