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Analysis of TiO2 for microelectronic applications: effect of deposition methods on their electrical properties
Davinder RATHEE, Sandeep K ARYA, Mukesh KUMAR
Frontiers of Optoelectronics in China. 2011, 4 (4): 349-358.
https://doi.org/10.1007/s12200-011-0188-z
Metal oxide semiconductor (MOS) device down-scaling is a powerful driving force for the evolution of microelectronics. The downsizing rate of metal oxide semiconductor field effect transistors (MOSFETs) is really marvelous. Silicon dioxide (SiO2) has served as a perfect gate dielectric for the last four decades. Due to physical limitations, leakage current, high interface trap charge it now needs to be replaced with higher permittivity dielectric material. Keeping the motivation for the search of high-k materials, extensive studies have been carried out on several metal oxides, such as ZrO2, Ta2O5, TiO2, Al2O3 and HfO2 for the replacement of SiO2. The high dielectric constant (k) of titanium dioxide (TiO2) will open multifaceted prospects for the use of this material in microelectronic devices. In this paper, a comparative study of various deposition methods for fabrication of thin TiO2 films has been presented. This work uses a combination of simulation results, experimental data and critical analysis of published data. Further, an experiment using sol-gel method has been carried out to deposit thin films of TiO2. It has been characterized and compared with the earlier reported fabrication methods. The X-ray diffraction analyses and Raman spectra indicate the presence of anatase TiO2 phase in the film. The dielectric constant as calculated using capacitance-voltage (C-V) analysis was found to be 23. The refractive index of the film was 2.43. The TiO2 films studied for microelectronic applications and present acceptable properties such as low leakage current density of 1.0×10-5 A/cm at 1 V and band gap of 3.6 eV. The leakage current has been found to be dominant by the Schottky emission at lower electric field, while Flower-Nordheim (F-N) tunneling occurs at higher biasing voltages.
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Application of Poly (3, 4-ethylenedioxythiophene): polystyrenesulfonate counter electrode in polymer heterojunction dye-sensitized solar cells
Gentian YUE, Jihuai WU, Jianming LIN, Miaoliang HUANG, Ying YAO, Leqing FAN, Yaoming XIAO
Frontiers of Optoelectronics in China. 2011, 4 (4): 369-377.
https://doi.org/10.1007/s12200-011-0181-6
A Poly (3, 4-ethylenedioxythiophene): polystyrenesulfonate (PEDOT:PSS)/carbon conductive paste was prepared and coated on a conducting FTO glass to construct counter electrode for polymer heterojunction dye-sensitized solar cells (DSSCs). The surface morphology, conductivity, sheet resistance, redox properties and photoelectric properties of carbon electrode were observed respectively by scanning electron microscopy, four-probe tester and CHI660D electrochemical measurement system. The experimental results showed that DSSCs had the best photoelectric properties for PEDOT:PSS/carbon counter electrode annealing at 80°C in vacuum conditions. Using [6, 6]-phenyl-C61-butyric acid methyl ester (PCBM)/poly (3-hexylthiophene) (P3HT) heterojunction to replace I3-/I- redox electrolyte, the overall energy conversion efficiency of the DSSCs with barrier layer reached 4.11% under irradiation of a simulated solar light with a intensity of 100 mW·cm-1 (AM 1.5), which is higher 20% than that of the DSSCs with Pt counter electrode (3.42%). The excellent photoelectric properties, simple preparation procedure and low cost allow the PEDOT:PSS/carbon electrode to be a credible alternative used in DSSCs.
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Synthesis and optical properties of europium pentafluoropropionate 1,10-phenanthroline complex and its silica glass
Jiangbo SHE, Dongdong LI
Frontiers of Optoelectronics in China. 2011, 4 (4): 382-386.
https://doi.org/10.1007/s12200-011-0179-0
Europium pentafluoropropionate 1,10-phenanthroline complex, Eu(C2F5COO)3·Phen (Phen= 1,10-phenanthroline), were synthesized and characterized by elemental analysis, Fourier transform infrared spectroscopy (FT-IR), photoluminescence (PL) spectroscopy and thermogravimetric analysis (TA). At the same time, its silica glass was synthesized by in situ processes. The excitation spectra of the complex demonstrate that the energy collected by “antenna ligands” was transferred to Eu3+ ions efficiently. The room-temperature PL spectra of the complexes are composed of the typical Eu3+ ions red emission, due to transitions between 5D0→7FJ(J = 0→4). The decomposition temperature of the complex was 290°C, which indicates the host complex is quite stable to heat. Then the affection of anneal temperatures on PL properties of SiO2 glass were studied. The PL intensity of the SiO2 glass annealed at 160°C was higher than other annealed temperatures for 24 h in air.
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Modelling of beam propagation and its applications for underwater imaging
Yuzhang CHEN, Kecheng YANG, Xiaohui ZHANG, Min XIA, Wei LI
Frontiers of Optoelectronics in China. 2011, 4 (4): 398-406.
https://doi.org/10.1007/s12200-011-0219-9
In order to process underwater imaging to the best possible level, an imaging model based on beam propagation was established. The presented model included not only the laser beam propagation affected by absorption and scattering, but also the effects of underwater turbulence and the diffraction limit of sensors. By this model approximately quantified optical transfer functions (OTFs) were studied. Thus, under this framework, the approaches of image enhancement, restoration and super-resolution reconstruction (SRR) can be extended by incorporating underwater optical properties based on OTF or point spread function (PSF) of the imaging system. Experimental results proved that the imaging range and the image quality can be effectively enhanced, which are critical in underwater imaging or detecting.
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Nearly zero-dispersion, low confinement loss, and small effective mode area index-guiding PCF at 1.55 μm wavelength
Saeed OLYAEE, Fahimeh TAGHIPOUR, Mahdieh IZADPANAH
Frontiers of Optoelectronics in China. 2011, 4 (4): 420-425.
https://doi.org/10.1007/s12200-011-0172-7
In this paper, a new simple structure of index-guiding photonic crystal fiber (PCF) is designed and presented. In this PCF, dispersion, confinement loss, and effective mode area characteristics are investigated in the second communication window (1.55 μm). Since 1.55 μm wavelength is widely used in optical communication systems, we try to optimize the PCF characteristics in this wavelength by designing an index-guiding PCF and three versions of optimized PCF. The results show that the dispersion is obtained very close to zero around 4.6×10-4 ps/(nm·km). Also, the confinement loss is 2.303×10-6 dB/km and effective mode area is as small as 2.6 μm2.
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Identification and replacement of defective pixel based on Matlab for IR sensor
Minghui YANG, Sihai CHEN, Xin WU, Wen FU, Zhangli HUANG
Frontiers of Optoelectronics in China. 2011, 4 (4): 434-437.
https://doi.org/10.1007/s12200-011-0177-2
Infrared focal plane arrays (IRFPAs) usually contain many defective pixels. These defective pixels have to be corrected because those can significantly impair the performance of infrared image of IRFPAs. As is known to all, infrared image acquisition and analysis based on Matlab can be helpful to identify and correct defective pixels. In this paper, we proposed a novel method to identify and correct defective pixels. In the phase of identification, the defective pixels could be identified by the algorithms combined with median filtering algorithm and improved standard deviation algorithm. In the phase of correction, proportion-spatial defective pixel replacement (PSDPR) algorithm was introduced to replace the defective pixels, and this method reduced the difficulty of replacement originating from the clustering phenomenon of defective pixels. In addition, an experiment of verification was done, and showed the proposed scheme worked effectively.
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Investigation of aqueous acetone solution with THz pulse spectroscopy
Jinxin BIAN, Yiming ZHU, Xiaoxuan JIA, Lin CHEN, Yan PENG, Yongcai YANG, Songlin ZHUANG
Frontiers of Optoelectronics in China. 2011, 4 (4): 444-447.
https://doi.org/10.1007/s12200-011-0175-4
The absorption spectra from 0.2 to 1.7 THz of five water-acetone mixtures, whose concentrations are 0%, 25%, 50%, 75%, and 100%, has been investigated by THz time-domain spectroscopy (THz-TDS). The result indicates that of acetone solutions with different concentrations have different absorption for THz radiation, which is analyzed and attributed to the variation of the hydrogen bond. Furthermore, we also find the absorption of the water-acetone mixture almost linearly increases with the increase of water concentration in the THz range.
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